[2-(trimethylsilyl)ethyl]-N,N,-dinitramine | 136398-41-9

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: [2-(trimethylsilyl)ethyl]-N,N,-dinitramine
• 英文别名: N-nitro-N-(2-trimethylsilylethyl)nitramide
• CAS: 136398-41-9
• 化学式: C₅H₁₃N₃O₄Si
• 分子量: 207.261
• InChiKey: GMAULXQGXMCZTC-UHFFFAOYSA-N

物化性质

• 沸点：
  277.4±42.0 °C(Predicted)
• 密度：
  1.153±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.01
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  94.9
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  [2-(trimethylsilyl)ethyl]-N,N,-dinitramine 、 cesium fluoride 以 乙腈 为溶剂， 以50%的产率得到cesium dinitramide
  参考文献：
  名称：

  1,1,3,3-Tetraoxo-1,2,3-triazapropene Anion, a New Oxy Anion of Nitrogen:  The Dinitramide Anion and Its Salts

  摘要：

  We report the synthesis of a completely new, stable class of inorganic salts named the dinitramide salts. These salts are based on a newly discovered nitrogen oxide anion known as the dinitramide anion. The dinitramide anion is a uniquely stable, high oxygen density grouping that can be prepared in many salt combinations including the ammonium or hydrazinium salts. The dinitramide anion has both fundamental scientific interest and practical applications. We describe here the synthesis of dinitramide salts and give a preliminary report on their properties.

  DOI：

  10.1021/ja9709278
• 作为产物：
  描述：

  (2-Isocyanato-ethyl)-trimethyl-silane 在 nitronium tetrafluoborate 、 硝酸 作用下， 以 乙腈 为溶剂， 反应 0.25h， 以25%的产率得到[2-(trimethylsilyl)ethyl]-N,N,-dinitramine
  参考文献：
  名称：

  异氰酸酯直接硝化合成烷基-N,N-二硝胺的新方法

  摘要：

  摘要 已开发出一种将脂肪族异氰酸酯轻松转化为 N,N-二硝胺的方法。脂肪族异氰酸酯用氟硼酸硝铵和硝酸在乙腈中的混合物进行处理，得到公平的产率并简化了现有的合成。

  DOI：

  10.1080/00397919108019779

文献信息

• BOTTARO, JEFFREY C.;PENWELL, PAUL E.;SCHMITT, ROBERT J., SYNTH. COMMUN., 21,(1991) N, C. 945-949
  作者：BOTTARO, JEFFREY C.、PENWELL, PAUL E.、SCHMITT, ROBERT J.

  DOI：——

  日期：——
• 1,1,3,3-Tetraoxo-1,2,3-triazapropene Anion, a New Oxy Anion of Nitrogen:  The Dinitramide Anion and Its Salts
  作者：Jeffrey C. Bottaro、Paul E. Penwell、Robert J. Schmitt

  DOI：10.1021/ja9709278

  日期：1997.10.1

  We report the synthesis of a completely new, stable class of inorganic salts named the dinitramide salts. These salts are based on a newly discovered nitrogen oxide anion known as the dinitramide anion. The dinitramide anion is a uniquely stable, high oxygen density grouping that can be prepared in many salt combinations including the ammonium or hydrazinium salts. The dinitramide anion has both fundamental scientific interest and practical applications. We describe here the synthesis of dinitramide salts and give a preliminary report on their properties.
• A New Synthesis of Alkyl-N,N-dinitramines by Direct Nitration of Isocyanates
  作者：Jeffrey C. Bottaro、Paul E. Penwell、Robert J. Schmitt

  DOI：10.1080/00397919108019779

  日期：1991.4

  Abstract A facile conversion of aliphatic isocyanates to N,N-dinitramines has been developed. An aliphatic isocyanate is treated with a mixture of nitronium fluoroborate and nitric acid in acetonitrile giving fair yields and simplifing the existing synthesis.

  摘要 已开发出一种将脂肪族异氰酸酯轻松转化为 N,N-二硝胺的方法。脂肪族异氰酸酯用氟硼酸硝铵和硝酸在乙腈中的混合物进行处理，得到公平的产率并简化了现有的合成。