triphenylsilyl bromide | 6990-64-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triphenylsilyl bromide
• 英文别名: Bromtriphenylsilan；Triphenylbromsilan；Bromo(triphenyl)silane
• CAS: 6990-64-3
• 化学式: C₁₈H₁₅BrSi
• 分子量: 339.307
• InChiKey: VSCMNSZBNLOXNR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.05
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  triphenylsilyl bromide 在 水 、 potassium carbonate 作用下， 以 水 为溶剂， 生成 三苯基硅醇
  参考文献：
  名称：

  Ladenburg, A., Chemische Berichte, 1907, vol. 40, p. 2274 - 2279

  摘要：

  DOI：
• 作为产物：
  描述：

  三苯基氯硅烷 在 magnesium bromide 作用下， 以 甲苯 为溶剂， 生成 triphenylsilyl bromide
  参考文献：
  名称：

  Krueerke,U., Chemische Berichte, 1962, vol. 95, p. 174 - 182

  摘要：

  DOI：

文献信息

• Polyhalo-organometallic and -organometalloidal compounds
  作者：F.W.Gordon Fearon、Henry Gilman

  DOI：10.1016/s0022-328x(00)83164-2

  日期：1967.12

  The preparation and some properties of the compounds (C6F5)nSiPh4−n (where n = 1–4) and (C6F5)nPh3−nSiX (where n = 1 or 2 and X = H or Cl) are described. In general, these compounds were obtained by the reaction of a (pentafluorophenyl)-metallic compound with the corresponding chlorosilane. However, compounds of the form (C6F5)nPh3−nSiCl could not be obtained in this manner; they were prepared by the

  （C 6 F 5）n SiPh 4- n（n = 1-4）和（C 6 F 5）n Ph 3- n SiX（n = 1或2且X = H或Cl）被描述。通常，这些化合物是通过（五氟苯基）金属化合物与相应的氯硅烷反应获得的。但是，形式为（C 6 F 5）n Ph 3− n的化合物用这种方法不能得到SiCl。它们是通过氯化相应的有机硅氢化物制备的。
• Metallic Compound and Organic Electroluminescence Device Comprising the Same
  申请人：Suh Dong-Hack

  公开号：US20080207905A1

  公开（公告）日：2008-08-28

  The present invention relates to a light emitting metallic compound of Chemical Formula 1 and an organic electroluminescence device including the compound. In the Chemical Formula 1, M is selected from Ir, Pt, Rh, Re, and Os, m is 2 or 3, n is 0 or 1, the sum of m and n is 3, provided that the sum of m and n is 2 when M is Pt. X is an N or P atom, Y is S, O, or Se, and Z is SiR 5 R 6 , CR 5 R 6 , PR 5 , S, SO 2 , carbonyl, or NR 5 , and L 2 is represented by Chemical Formulae 2, 3, or 4.

  本发明涉及化学式1的发光金属化合物以及包括该化合物的有机电致发光器件。在化学式1中，M从Ir、Pt、Rh、Re和Os中选择，m为2或3，n为0或1，m和n的和为3，当M为Pt时，m和n的和为2。X是N或P原子，Y是S、O或Se，Z是SiR5R6、CR5R6、PR5、S、SO2、羰基或NR5，L2由化学式2、3或4表示。
• SYNTHESIS OF 5-FLUORO-PRGSTAGLANDINS
  作者：Hisao Nakai、Nobuyuki Hamanaka、Hajimu Miyake、Masaki Hayashi

  DOI：10.1246/cl.1979.1499

  日期：1979.12.5

  (5E)- And (5Z)-5-fluoro-prostaglandin(PG)F2α methyl esters 1 and 2 were synthesized via decarboxylative elimination reaction from key intermediate α-fluoro-β-hydroxy ester 7. 5-Fluoro-6-keto-PGE1 methyl ester 3 was also synthesized from the key intermediate 7. These 5-fluoro-PGs 1, 2 and 3 showed interesting biological properties.

  (5E)- 和 (5Z)-5-氟-前列腺素 (PG)F2α 甲酯 1 和 2 通过从关键中间体 α-氟-β-羟基酯 7 的脱羧消除反应合成。5-氟-6-酮- PGE1 甲酯 3 也由关键中间体 7 合成。这些 5-氟-PGs 1、2 和 3 显示出有趣的生物学特性。
• Photolysis of Acylsilanes in Cyclohexane and Other Solvents
  作者：A. G. Brook、J. M. Duff

  DOI：10.1139/v73-051

  日期：1973.2.1

  Whereas photolysis of acylsilanes in carbon tetrachloride has been shown to generate silyl radicals which yield chlorosilanes exclusively, and photolyses in alcohols yield siloxycarbenes which yield "mixed acetal" insertion products, it is shown that photolysis of acylsilanes in non-polar, non-halogenated solvents such as cyclohexane give complex mixtures of products which result primarily from the attack of silyl radicals on the carbonyl oxygen of an acylsilane, followed by conventional disproportionation or recombination reactions. Under some circumstances silyl radicals add to carbon–carbon double bonds. The structures of the products formed and the mechanism of their formation are described.

  在碳四氯化物中，酰硅烷的光解已被证明会产生硅基自由基，其仅生成氯硅烷；而在醇中的光解会产生硅氧卡宾，从而生成“混合缩醛”插入产物。结果表明，在非极性、非卤代溶剂（如环己烷）中，酰硅烷的光解会产生复杂的产物混合物，主要是由硅基自由基对酰硅烷的羰基氧发起攻击，随后进行传统的不均化或重组反应。在某些情况下，硅基自由基会加成到碳-碳双键上。描述了所形成产物的结构和形成机制。
• Preparation and properties of some pentafluorophenyl group IV compounds
  作者：A.J. Oliver、W.A.G. Graham

  DOI：10.1016/s0022-328x(00)87750-5

  日期：1969.9

  The preparation of the compounds C6F5Si(CH3)2X [where X = H, CH3, C6F5, OCH13, N(CH3)2 or NHC6H5] and R3MYC6F5 (where R = CH3 or C6H5, M = Si, Ge, Sn or Pb and Y = O, S or NH) is described and their NMR and IR spectra are discussed.

  化合物C 6 F 5 Si（CH 3）2 X [其中X ＝ H，CH 3，C 6 F 5，OCH 13，N（CH 3）2或NHC 6 H 5 ]和R 3 MYC 6的制备描述了F 5（其中R = CH 3或C 6 H 5，M = Si，Ge，Sn或Pb，Y = O，S或NH），并讨论了它们的NMR和IR光谱。