2,5-Bis-(p-hexyloxyphenyl)-pyrazin | 16877-63-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2,5-Bis-(p-hexyloxyphenyl)-pyrazin
• 英文别名: 2,5-bis(4-hexyloxyphenyl)pyrazine；2,5-Bis(4-hexoxyphenyl)pyrazine；2,5-bis(4-hexoxyphenyl)pyrazine
• CAS: 16877-63-7
• 化学式: C₂₈H₃₆N₂O₂
• 分子量: 432.606
• InChiKey: RBRGUILIJLFCOC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  32
• 可旋转键数：
  14
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  44.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,5-Bis-(p-hexyloxyphenyl)-pyrazin 、 palladium diacetate 以 溶剂黄146 为溶剂， 以72%的产率得到palladium(μ-acetato)-2,5-bis(4-hexyloxyphenyl)pyrazine
  参考文献：
  名称：

  Cyclometallated nitrogen heterocycles

  摘要：

  The cyclometallation of four different classes of nitrogen heterocycle (pyridazine, tetrazines, pyrazines and pyrimidines) by palladium and platinum has been studied. Pyridazines readily form singly and doubly cyclometallated compounds, whilst pyrazines only metallate once. Both tetrazines and pyrimidines readily metallate once and doubly metallated species have been identified in solution. The use of trans-cyclometallating reagents based on benzylamine and Schiff's base ligands was also studied: considerable promise was shown by a benzylamine compound. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.08.038

文献信息

• Cyclometallated nitrogen heterocycles
  作者：Jonathan W. Slater、Jonathan P. Rourke

  DOI：10.1016/j.jorganchem.2003.08.038

  日期：2003.12

  The cyclometallation of four different classes of nitrogen heterocycle (pyridazine, tetrazines, pyrazines and pyrimidines) by palladium and platinum has been studied. Pyridazines readily form singly and doubly cyclometallated compounds, whilst pyrazines only metallate once. Both tetrazines and pyrimidines readily metallate once and doubly metallated species have been identified in solution. The use of trans-cyclometallating reagents based on benzylamine and Schiff's base ligands was also studied: considerable promise was shown by a benzylamine compound. (C) 2003 Elsevier B.V. All rights reserved.