trans-bis(2-aminopyridine)dichloropalladium(II) | 77839-68-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: trans-bis(2-aminopyridine)dichloropalladium(II)
• 英文别名: trans-[PdCl2(2-aminopyridine)2]；Dichloropalladium;pyridin-2-amine
• CAS: 77839-68-0；89577-64-0
• 化学式: C₁₀H₁₂Cl₂N₄Pd
• 分子量: 365.558
• InChiKey: SEQFUVMKDFPQKB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  trans-bis(2-aminopyridine)dichloropalladium(II) 、 saccharin sodium salt 以 乙醇 为溶剂， 反应 3.0h， 以77%的产率得到trans-[Pd(saccharinate)2(2-aminopyridine)2]
  参考文献：
  名称：

  Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with 2-aminopyridine (2-ampy), 2-acetylaminopyridine (2-aampy) and 2-acetylaminopyrimidine (2-aampym) co-ligands: X-ray crystal structures of trans-[Pd(sac)2(ampy)2] and solvatomorphs trans-[Pd(sac)2(2-aampy)2]·S (S=CHCl3, thf)

  摘要：

  Reactions of Na2PdCl4 with two equivalents of 2-aminopyridine (2-ampy), 2-acetylaminopyridine (2-aampy) or 2-acetylaminopyrimidine (2-aampym) afford complexes of the type trans-[PdCl2L2]. Further reaction with two equivalents of sodium saccharinate (Nasac) affords mixed-ligand complexes trans-[Pd(sac)(2)L-2]. X-ray structures of trans-[Pd(sac)(2)(2-ampy)(2)] and two solvatomorphs of trans-[Pd(sac)(2)(2-aampy)(2)].S (S = CHCl3, thf) have been carried out. In all three, the saccharinate ligands coordinate in a monodentate fashion via the endocyclic amido group and all four ligands lie approximately perpendicular to the PdN4 plane. In trans-[Pd(sac)(2)(2-ampy)(2)] the metal ion lies on an inversion centre and consequently the ligands adopt a relative anti/anti-configuration, while in both solvatomorphs of trans-[Pd(sac)(2)(2-aampy)(2)] they adopt a syn/syn-configuration, the latter possibly resulting from intramolecular hydrogen bonding between the amine protons and the carbonyl oxygen. Reactions of trans-[PdCl2L2] with thiosaccharin (tsacH) are dependent upon the nature of the amine. Thus, with trans-[PdCl2(2-ampy)(2)] the desired mixed-ligand complex trans-[Pd(tsac)(2)(2-ampy)(2)] results, however with acetylamine complexes only the known homoleptic complex, [Pd(tsac)(2)], is isolated. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.03.036
• 作为产物：
  描述：

  2-氨基吡啶 、 sodium tetrachloropalladate(II) 以 甲醇 、 乙醚 为溶剂， 反应 72.0h， 生成 trans-bis(2-aminopyridine)dichloropalladium(II)
  参考文献：
  名称：

  高效萃取钯的多孔有机聚合物纳米阱。

  摘要：

  为了抵消铂族元素（PGE）开采对环境的影响，正在探索回收技术。多孔有机聚合物（POPs）由于其选择性和承受苛刻条件的能力而显示出巨大的前景。已经设计并系统地探索了一系列基于吡啶的POP纳米捕集阱，POP-Py，POP- p NH 2 -Py和POP- o NH 2 -Py，以捕获钯（最常用的PGE之一）。所有的POP纳米捕集阱均显示出记录的吸收和快速捕获，其中的氨基对提高性能至关重要。在POP nanotrap再生和选择性进一步测试发现，POP- ö NH 2 -py跑赢POP-p NH 2 -Py。单晶X-射线分析表明，POP- ö NH 2 -py提供更强的复合物相比，POP- p NH 2 -py由于氨基和协调的氯分子之间的分子内氢键。这些结果证明了对吸附剂的轻微修饰如何可以最大化其性能。

  DOI：

  10.1002/anie.202006596

文献信息

• An efficient Pd(II)-(2-aminonicotinaldehyde) complex as complementary catalyst for the Suzuki-Miyaura coupling in water
  作者：Sanjeeva Thunga、Soumya Poshala、Naveenkumar Anugu、Ramaiah Konakanchi、Satheesh Vanaparthi、Hari Prasad Kokatla

  DOI：10.1016/j.tetlet.2019.06.051

  日期：2019.8

  An efficient new Pd(II)-(2-aminonicotinaldehyde)-catalyzed Suzuki-Miyaura coupling of the aryl halides (Br, Cl and I) and organoboronic acids at moderate temperature in water is described. Low catalyst loading, easy accessibility, being an air-stable catalyst, functional group compatibility, and water as the reaction medium are some of the key features of this synthetic method. This protocol is also

  描述了一种高效的新型Pd（II）-（2-氨基烟碱醛）催化的芳基卤化物（Br，Cl和I）与有机硼酸在水中的Suzuki-Miyaura偶联反应。催化剂负载量低，易于获得，作为空气稳定的催化剂，官能团相容性以及水作为反应介质是该合成方法的一些关键特征。该协议也适用于克量表。
• A Porous Organic Polymer Nanotrap for Efficient Extraction of Palladium
  作者：Briana Aguila、Qi Sun、Harper C. Cassady、Chuan Shan、Zhiqiang Liang、Abdullah M. Al‐Enizic、Ayman Nafadyc、Joshua T. Wright、Robert W. Meulenberg、Shengqian Ma

  DOI：10.1002/anie.202006596

  日期：2020.10.26

  To offset the environmental impact of platinum‐group element (PGE) mining, recycling techniques are being explored. Porous organic polymers (POPs) have shown significant promise owing to their selectivity and ability to withstand harsh conditions. A series of pyridine‐based POP nanotraps, POP‐Py, POP‐pNH2‐Py, and POP‐oNH2‐Py, have been designed and systematically explored for the capture of palladium

  为了抵消铂族元素（PGE）开采对环境的影响，正在探索回收技术。多孔有机聚合物（POPs）由于其选择性和承受苛刻条件的能力而显示出巨大的前景。已经设计并系统地探索了一系列基于吡啶的POP纳米捕集阱，POP-Py，POP- p NH 2 -Py和POP- o NH 2 -Py，以捕获钯（最常用的PGE之一）。所有的POP纳米捕集阱均显示出记录的吸收和快速捕获，其中的氨基对提高性能至关重要。在POP nanotrap再生和选择性进一步测试发现，POP- ö NH 2 -py跑赢POP-p NH 2 -Py。单晶X-射线分析表明，POP- ö NH 2 -py提供更强的复合物相比，POP- p NH 2 -py由于氨基和协调的氯分子之间的分子内氢键。这些结果证明了对吸附剂的轻微修饰如何可以最大化其性能。
• Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with 2-aminopyridine (2-ampy), 2-acetylaminopyridine (2-aampy) and 2-acetylaminopyrimidine (2-aampym) co-ligands: X-ray crystal structures of trans-[Pd(sac)2(ampy)2] and solvatomorphs trans-[Pd(sac)2(2-aampy)2]·S (S=CHCl3, thf)
  作者：Subhi A. Al-Jibori、Qusay K.A. Al-Jibori、Harry Schmidt、Kurt Merzweiler、Christoph Wagner、Graeme Hogarth

  DOI：10.1016/j.ica.2013.03.036

  日期：2013.6

  Reactions of Na2PdCl4 with two equivalents of 2-aminopyridine (2-ampy), 2-acetylaminopyridine (2-aampy) or 2-acetylaminopyrimidine (2-aampym) afford complexes of the type trans-[PdCl2L2]. Further reaction with two equivalents of sodium saccharinate (Nasac) affords mixed-ligand complexes trans-[Pd(sac)(2)L-2]. X-ray structures of trans-[Pd(sac)(2)(2-ampy)(2)] and two solvatomorphs of trans-[Pd(sac)(2)(2-aampy)(2)].S (S = CHCl3, thf) have been carried out. In all three, the saccharinate ligands coordinate in a monodentate fashion via the endocyclic amido group and all four ligands lie approximately perpendicular to the PdN4 plane. In trans-[Pd(sac)(2)(2-ampy)(2)] the metal ion lies on an inversion centre and consequently the ligands adopt a relative anti/anti-configuration, while in both solvatomorphs of trans-[Pd(sac)(2)(2-aampy)(2)] they adopt a syn/syn-configuration, the latter possibly resulting from intramolecular hydrogen bonding between the amine protons and the carbonyl oxygen. Reactions of trans-[PdCl2L2] with thiosaccharin (tsacH) are dependent upon the nature of the amine. Thus, with trans-[PdCl2(2-ampy)(2)] the desired mixed-ligand complex trans-[Pd(tsac)(2)(2-ampy)(2)] results, however with acetylamine complexes only the known homoleptic complex, [Pd(tsac)(2)], is isolated. (C) 2013 Elsevier B.V. All rights reserved.