N,N',N''-tris(3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide | 191397-32-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N',N''-tris(3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide
• 英文别名: N~1~,N~3~,N~5~-Tris(3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide；1-N,3-N,5-N-tris(3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide
• CAS: 191397-32-7
• 化学式: C₃₉H₆₉N₃O₃
• 分子量: 627.995
• InChiKey: NKGQYHSBAPGVHX-UHFFFAOYSA-N

物化性质

• 沸点：
  734.1±55.0 °C(Predicted)
• 密度：
  0.953±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12.1
• 重原子数：
  45
• 可旋转键数：
  24
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  87.3
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  (3,7-dimethyloctyl)amine 、 1,3,5-苯三甲酰氯 在 吡啶 、 lithium chloride 作用下， 以 四氢呋喃 为溶剂， 以44%的产率得到N,N',N''-tris(3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide
  参考文献：
  名称：

  1,3,5-苯-和1,3,5-环己烷三甲酰胺的相行为和中间相结构：过渡到各向同性相时对失去顺序的理解。

  摘要：

  超分子化学中最简单，最通用的基元之一是基于1,3,5-苯三甲酰胺。核心结构的变化和侧向取代基结构的细微变化控制着自组装并决定了相行为。本文中，我们提供了一系列包含直链和支链烷基取代基的1,3,5-苯和1,3,5-环己烷甲酰胺的相行为和中间相结构的全面比较。取决于取代基，形成了不同的结晶相，塑性结晶相和液晶相。在相对罕见的柱状向列型（N Ç）相仅在含有线性烷基取代基的环己烷基三酰胺中观察到。在液晶超分子系统中，最基本的兴趣是从介晶态到各向同性态的转变，尤其是如何降低阶数的问题。温度相关的红外光谱和XRD测量表明，各向同性相中仍存在柱状H键结合的聚集体。在清理过渡时，主要失去了侧向顺序，而仍然保留了较短的柱状骨料。对相行为和中间相结构的透彻了解与选择在器件中使用超分子结构或用作原纤纳米材料的加工条件有关。

  DOI：

  10.1002/chem.201103216

文献信息

• Remarkable Viscoelasticity of Organic Solvents Containing Trialkyl-1,3,5-benzenetricarboxamides and Their Intermolecular Hydrogen Bonding
  作者：Kenji Hanabusa、Chiemi Koto、Mutsumi Kimura、Hirofusa Shirai、Akikazu Kakehi

  DOI：10.1246/cl.1997.429

  日期：1997.5

  Remarkable rise of viscosity was observed by adding trialkyl-1,3,5-benzenetricarboxamide into organic solvents; the formation of highly viscoelastic solution was discussed by viscosity measurement, FTIR spectroscopy, and X-ray molecular structure in the crystal.

  在有机溶剂中加入三烷基-1,3,5-苯三甲酰胺后，观察到粘度显著上升；通过粘度测量、傅里叶变换红外光谱和晶体中的 X 射线分子结构，讨论了高粘弹性溶液的形成。
• Solution casting method and polymer film
  申请人：Sugiura Masaru

  公开号：US20050077648A1

  公开（公告）日：2005-04-14

  A solvent in which dichloromethane is mixed with alcohol as a poor solvent is used for preparing a dope. Alcohol is supplied to the dope in a inline pipe to mix with a static mixer, such as a casting dope in which a composition of alcohol is increased. The temperature of the rotary drum is adjusted to −7° C. The casting dope is fed from a casting die to the rotary drum so as to form a casting film whose thickness is 40 μm. Since the content of alcohol is high and a storage modulus of the cooled casting film is at least 150 thousands Pa, the peeling defect does not occur, and the stretch is reduced as far as possible. A gel-like film is dried by a tenter type drying device, and stretched such that the stretch ratio is at most 110%. The produced film is thin and excellent in a surface condition and optical isotropy.

  二氯甲烷与作为劣质溶剂的酒精混合的溶剂用于制备涂料。酒精通过内联管道供应到涂料中，与静态混合器混合，如增加酒精成分的铸造涂料。将浇注料从浇注模具送入旋转滚筒，以形成厚度为 40 μm 的浇注膜。由于酒精含量高，冷却后的浇注膜的储存模量至少为 15 万帕，因此不会出现剥离缺陷，拉伸也尽可能减小。凝胶状薄膜由拉幅机干燥，拉伸率不超过 110%。生产出的薄膜很薄，表面状态和光学各向同性都很好。
• MONO- AND MULTI-LAYER BLOWN FILMS
  申请人：BASF SE

  公开号：EP2026965B1

  公开（公告）日：2010-09-01
• JPH10231465A
  申请人：——

  公开号：JPH10231465A

  公开（公告）日：1998-09-02
• Mono-and multi-layer blown films
  申请人：Stoll Klaus

  公开号：US20090208718A1

  公开（公告）日：2009-08-20

  An extruded air cooled blown film having a) a total thickness of 5 to 500 μm, b) a mono-layer structure or 2 to 9 coextruded layers, c) at least one layer L containing a polymer selected from the group consisting of polypropylene homopolymers, polypropylene random copolymers, hetero-phasic polypropylene block copolymers, or any mixtures thereof, said polymer having a melt flow rate, according to ASTM D-1238, of 0.1 to 10 dg/min at 230° C. and 2.16 kg, said layer L further containing 0.001 to 2%, relative to the weight of the polymer, of a particular nucleating agent, and optionally d) a Modulus according to EN ISO 527 enhanced by at least 10% versus a reference film without the nucleating agent.