benzo[i]benzo[6',7']quinoxalino[2',3':9,10]phenanthro[4,5-abc]phenazine | 1228192-02-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: benzo[i]benzo[6',7']quinoxalino[2',3':9,10]phenanthro[4,5-abc]phenazine
• 英文别名: 3,14,22,33-Tetrazadecacyclo[18.18.2.02,15.04,13.06,11.016,40.021,34.023,32.025,30.035,39]tetraconta-1(39),2,4,6,8,10,12,14,16(40),17,19,21,23,25,27,29,31,33,35,37-icosaene
• CAS: 1228192-02-6
• 化学式: C₃₆H₁₈N₄
• 分子量: 506.566
• InChiKey: KKOKMEKPJIJLJR-UHFFFAOYSA-N

物化性质

• 熔点：
  >300 °C
• 密度：
  1.491±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  40
• 可旋转键数：
  0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,3-二氨基萘 、 芘- 4,5,9,10 -四酮 在 吡啶 作用下， 反应 72.0h， 以40%的产率得到benzo[i]benzo[6',7']quinoxalino[2',3':9,10]phenanthro[4,5-abc]phenazine
  参考文献：
  名称：

  高度稳定的四氮杂十四碳烯和四氮杂八碳烯染料的简便合成

  摘要：

  稳定，可调且色彩鲜艳：据报道，可以直接合成高度稳定的π扩展的四氮杂庚并四氮杂十八碳烯染料。首次还观察到based基氮杂并苯的氧化行为，以及for原子氮杂并具有<11个线性稠合环的第三次还原波。

  DOI：

  10.1002/asia.200900373

文献信息

• Mechanochemical Synthesis, Photophysical Properties, and X-ray Structures of N-Heteroacenes
  作者：Prasit Kumar Sahoo、Chandan Giri、Tuhin Subhra Haldar、Rakesh Puttreddy、Kari Rissanen、Prasenjit Mal

  DOI：10.1002/ejoc.201600005

  日期：2016.3

  chromatographic purifications could be avoided after the solvent-free syntheses. The UV/Vis absorption spectra of the pyrazaacenes show intense absorption bands in the near-IR region. The single-crystal X-ray analyses of selected pyrazaacene derivatives showed pairwise π–π interactions and some C–H···π interactions, which could account for some of the photophysical features of the compounds in the solid

  所描述的机械化学方法是概念验证的一个例子，在该方法中，在无溶剂球磨条件下实现了基于溶液的乏味、收率低且困难的吡氮杂并苯合成；该方法简单、高产、省时、环保。合成的化合物还包括吡氮杂并苯（N-杂并苯），它们是含有芘结构单元的辛苯类似物。该化合物微溶于普通溶剂，无溶剂合成后可避免柱层析纯化。吡氮杂并苯的紫外/可见吸收光谱在近红外区域显示出强烈的吸收带。选定的吡氮杂并苯衍生物的单晶 X 射线分析显示成对的 π-π 相互作用和一些 C-H…π 相互作用，
• ORGANIC THIN FILM TRANSISTOR
  申请人：LG Chem, Ltd.

  公开号：EP1836731B1

  公开（公告）日：2017-10-11
• PYRENE DERIVATIVES AND ORGANIC ELECTRONIC DEVICE USING PYRENE DERIVATIVES
  申请人：LG CHEM, LTD.

  公开号：EP1828343B1

  公开（公告）日：2016-12-07
• Organic thin film transistor
  申请人：Hwang Ho In

  公开号：US20070023749A1

  公开（公告）日：2007-02-01

  The present invention relates to an organic thin film transistor which includes an organic layer comprising an organic compound facilitating the ohmic contact between a semi-conducting layer and electrodes and serving as the semi-conducting layer. The organic thin film transistor according to the present invention has excellent electric contact between the semiconductor layer and the source electrode/drain electrode, and thus can be widely used as components for electric/electronic devices. As a result, as the materials for the source electrode or the drain electrode in the organic thin film transistor, materials which are less expensive and excellent in processibility though they have a low work function as the materials can be used.
• Pyrene derivatives and organic electronic device using pyrene derivatives
  申请人：Lee Hoon Dong

  公开号：US20070069203A1

  公开（公告）日：2007-03-29

  The present invention provides an organic electronic device using the compound of the formula (1) and a pyrene derivative having a new structure.