dihydrocrocipodin | 1271320-89-8

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物 - 环庚三烯酮
• 英文名称: dihydrocrocipodin
• 英文别名: 1-(2-Carboxyethyl)-3,4,6-trihydroxy-5-oxobenzo[7]annulene-8-carboxylic acid；1-(2-carboxyethyl)-3,4,6-trihydroxy-5-oxobenzo[7]annulene-8-carboxylic acid
• CAS: 1271320-89-8
• 化学式: C₁₅H₁₂O₈
• 分子量: 320.255
• InChiKey: AARKDQSYKWCUGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  152
• 氢给体数：
  5
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  没食子酸 、 3,4-二羟基苯基丙酸 在 horseradish peroxidase type I 、 双氧水 作用下， 以 丙酮 为溶剂， 以21%的产率得到dihydrocrocipodin
  参考文献：
  名称：

  Crocipodin, a benzotropolone pigment from the mushroom Leccinum crocipodium (Boletales)

  摘要：

  Crocipodin, an unusual benzotropolone pigment, has been isolated from the fruit bodies of the mushroom Leccinum crocipodium. Its structure was determined by spectroscopic methods, particularly 2D NMR spectroscopy. The structure was confirmed by total synthesis, starting from 4-bromocatechol and gallic acid. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.12.060

文献信息

• [EN] BENZOTROPOLONE DERIVATIVES AS ANTIMICROBIAL AGENTS<br/>[FR] DÉRIVÉS DE BENZOTROPOLONE À TITRE D'AGENTS ANTIMICROBIENS
  申请人：BASF SE

  公开号：WO2011048011A2

  公开（公告）日：2011-04-28

  Disclosed is the use of benzotropolone derivatives of Formula (1) as antimicrobial and/or preserving agents.
• Crocipodin, a benzotropolone pigment from the mushroom Leccinum crocipodium (Boletales)
  作者：Lydia Kerschensteiner、Florian Löbermann、Wolfgang Steglich、Dirk Trauner

  DOI：10.1016/j.tet.2010.12.060

  日期：2011.2

  Crocipodin, an unusual benzotropolone pigment, has been isolated from the fruit bodies of the mushroom Leccinum crocipodium. Its structure was determined by spectroscopic methods, particularly 2D NMR spectroscopy. The structure was confirmed by total synthesis, starting from 4-bromocatechol and gallic acid. (C) 2010 Elsevier Ltd. All rights reserved.