4-Bromo-3-[3-(2-phenylethynyl)phenyl]aniline | 1225389-45-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 4-Bromo-3-[3-(2-phenylethynyl)phenyl]aniline
• 英文别名: 4-bromo-3-[3-(2-phenylethynyl)phenyl]aniline
• CAS: 1225389-45-6
• 化学式: C₂₀H₁₄BrN
• 分子量: 348.242
• InChiKey: HWQWUDFIJRWSCR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-Bromo-3-[3-(2-phenylethynyl)phenyl]aniline 在 亚硝酸特丁酯 、 碘 作用下， 以 苯 为溶剂， 生成 2-bromo-5-iodo-3'-(phenylethynyl)-1,1'-biphenyl
  参考文献：
  名称：

  Synthesis of Large, Stable Colloidal Graphene Quantum Dots with Tunable Size

  摘要：

  We report a solution-chemistry-based approach to large, stable colloidal graphene quantum dots with uniform size and shape. The versatility of solution chemistry allows us to tune the structures of the graphenes and thus their properties.

  DOI：

  10.1021/ja1009376
• 作为产物：
  描述：

  4-溴-3-碘苯胺 、 3-(phenylethynyl)phenylboronic acid 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 生成 4-Bromo-3-[3-(2-phenylethynyl)phenyl]aniline
  参考文献：
  名称：

  Synthesis of Large, Stable Colloidal Graphene Quantum Dots with Tunable Size

  摘要：

  We report a solution-chemistry-based approach to large, stable colloidal graphene quantum dots with uniform size and shape. The versatility of solution chemistry allows us to tune the structures of the graphenes and thus their properties.

  DOI：

  10.1021/ja1009376

文献信息

• SOLUBLE GRAPHENE NANOSTRUCTURES AND ASSEMBLIES THEREFROM
  申请人：Li Liang-shi

  公开号：US20120279570A1

  公开（公告）日：2012-11-08

  Disclosed herein is a method for preparing large soluble graphenes. The method comprises attaching one or more hindering groups to the graphene, which can prevent face-to-face graphene stacking by reducing the effects of inter-graphene attraction. The large graphenes can absorb a wide spectrum of light from UV to near infrared, and are useful in photovoltaic devices and sensitizers in nanocrystalline solar cells.
• US9410040B2
  申请人：——

  公开号：US9410040B2

  公开（公告）日：2016-08-09
• Synthesis of Large, Stable Colloidal Graphene Quantum Dots with Tunable Size
  作者：Xin Yan、Xiao Cui、Liang-shi Li

  DOI：10.1021/ja1009376

  日期：2010.5.5

  We report a solution-chemistry-based approach to large, stable colloidal graphene quantum dots with uniform size and shape. The versatility of solution chemistry allows us to tune the structures of the graphenes and thus their properties.