nickel(II) dibenzyldithiocarbamate | 38542-61-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: nickel(II) dibenzyldithiocarbamate
• 英文别名: Ni(N,N-dibenzyldithiocarbamate)2；Ni(Bz2dtc)2；[Ni(N,N-dibenzyldithiocarbamato)2]；N,N-dibenzylcarbamodithioate;nickel(2+)
• CAS: 38542-61-9
• 化学式: C₃₀H₂₈N₂NiS₄
• 分子量: 603.52
• InChiKey: ZVFKOPAELLPDTR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.04
• 重原子数：
  37
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  72.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4,8,11-四氮杂环十四烷 、 nickel(II) dibenzyldithiocarbamate 以 乙醇 、 氯仿 为溶剂， 以58%的产率得到[Ni(N,N-dibenzyldithiocarbamate)(1,4,8,11-tetraazacyclotetradecane)]ClO4
  参考文献：
  名称：

  Novel octahedral nickel(II) dithiocarbamates with bi- or tetradentate N-donor ligands: X-ray structures of [Ni(Bzppzdtc)(phen)2]ClO4· CHCl3 and [Ni(Bz2dtc)2(cyclam)]

  摘要：

  A series of novel octahedral nickel(II) dithiocarbamate complexes involving bidentate nitrogen-donor ligands (phen = 1, 10-phenanthroline, bpy = 2,2'-bipyridine) or a tetradentate ligand (cyclam = 1,4,8,11-tetraazacycloteradecane) of the composition [Ni(BzMetdtc)(phen)(2)]ClO(4) (1), [Ni(Pe(2)dtc)(phen)(2)]ClO(4) (2), [Ni(Bzppzdtc)(phen)(2)]ClO(4) center dot CHCl(3) (3), [Ni(Bzppzdtc)(phen)(2)](SCN) (4), [Ni(BzMetdtc)(bpy)(2)]ClO(4) center dot 2H(2)O (5), [Ni(Pe(2)dtc)(cyclam)]ClO(4) (6), [Ni(BzMetdtC)(2)(cyclam)] (7), [Ni(Bz(2)dtC)(2)(cyclam)] (8) and [Ni(Bz(2)dtC)(2)(phen)] (9) (BzMetdtc = N,N-benzyl-methyldithiocarbamate(1-) anion, Pe(2)dtc = N,N-dipentyldithiocarbamate(1-) anion, Bz(2)dtc = N,N-dibenzyldithiocarbamate(1-) anion, Bzppzdtc = 4-benzylpiperazinedithiocarbamate(1-) anion), have been synthesized. Spectroscopic (electronic and infrared), magnetic moment and molar conductivity data, and thermal behaviour of the complexes are discussed. Single crystal X-ray analysis of 3 and 8 confirmed a distorted octahedral arrangement in the vicinity of the nickel atom with a N(4)S(2) donor set. They represent the first X-ray structures of such type complexes. The catalytic influence of complexes 2, 3, 6, and 7 on graphite oxidation was studied and discussed. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.09.024
• 作为产物：
  描述：

  以 乙腈 为溶剂， 生成 nickel(II) dibenzyldithiocarbamate
  参考文献：
  名称：

  Eckstein, P.; Hoyer, E., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：

文献信息

• Neutral and Ionic Complexes of C₆₀ with Metal Dibenzyldithiocarbamates. Reversible Dimerization of C₆₀^•^- in Ionic Multicomponent Complex [Cr^I(C₆H₆)₂^•⁺]·(C₆₀^•^-)·0.5[Pd(dbdtc)₂]
  作者：Dmitri V. Konarev、Andrey Yu. Kovalevsky、Akihiro Otsuka、Gunzi Saito、Rimma N. Lyubovskaya

  DOI：10.1021/ic051261i

  日期：2005.12.1

  molecular complexes of C60 with metal(II) dibenzyldithiocarbamates, M(dbdtc)2.C60.0.5(C6H5Cl), where M=Cu(II), Ni(II), Pd(II), and Pt(II) and an ionic multicomponent complex [Cr(I)(C6H6)2*+].(C60*-).0.5[Pd(dbdtc)2] (Cr(C6H6)2: bis(benzene)chromium) were obtained. According to IR, UV-visible-NIR, and EPR spectra, involve neutral components, whereas 5 comprises neutral Pd(dbdtc)2 and C60*- and Cr(I)(C6H6)2*+

  C60与金属（II）二苄基二硫代氨基甲酸酯金属（M（dbdtc）2.C60.0.5（C6H5Cl））的新分子配合物，其中M = Cu（II），Ni（II），Pd（II）和Pt（II）得到离子多组分络合物[Cr（I）（C6H6）2 * +]。（C60 *-）。0.5 [Pd（dbdtc）2]（Cr（C6H6）2：双（苯）铬）。根据IR，UV-可见-NIR和EPR光谱涉及中性成分，而5包含中性Pd（dbdtc）2和C60 *-和Cr（I）（C6H6）2 * +自由基离子。在90 K处的晶体结构揭示了与由Pd（dbdtc）2组成的层交替出现的强烈起皱的富勒烯层。Cr（I）（C6H6）2 * +自由基阳离子排列在各层之间。富勒烯自由基阴离子在层中形成对，富勒烯C ... C接触为3.092（2）A，表明它们在90 K时处于单体状态。该接触实质上比两个碳原子的范德华半径之和短，因此，C60 *-可以
• Synthesis and characterization of Ni(II) complexes with functionalized dithiocarbamates: New single source precursors for nickel sulfide and nickel-iron sulfide nanoparticles
  作者：E. Sathiyaraj、S Thirumaran、Samuele Ciattini、S. Selvanayagam

  DOI：10.1016/j.ica.2019.119162

  日期：2019.12

  supramolecular aggregation. [Ni(dbdtc)2] and [Ni(dbdtc)3][FeCl4] (dbdtc = N,N-dibenzyldithiocarbamate) were used to prepare monometallic sulfide (nickel sulfide), bimetallic sulfide (iron-nickel sulfide) nanoparticles. TEM images of nickel sulfide and iron-nickel sulfide reveal that the particles are oval shape and ultrafine (∼5–10 nm), respectively.

  摘要六个Ni（II）配合物，双（N-苄基-N-取代的苄基二硫代氨基甲酸酯-S，S'）镍（II）（1-3），（N-苄基-N-取代的苄基二硫代氨基甲酸酯-S，S'）（硫氰酸根合-N）（三苯基膦）镍（II）（4-6），[取代的苄基= 4-羟基苄基（1，4），4-甲氧基苄基（2，5），4-氯苄基（3，6）]配合物具有通过元素分析，IR，UV-Vis和NMR（1H和13C）光谱进行合成和表征。与均配复合物相比，杂配复合物的NCS2碳信号的高场移位支持了三苯基膦的反向键合作用。配合物1、4、5和6的结构已经通过单晶X射线衍射获得。在所有配合物中，镍周围的配位几何形状均为扭曲的正方形平面。在4中观察到了分子内Ni⋯HC前部相互作用。各种非共价相互作用，例如CH⋯π（螯合物），CH⋯π和CH⋯X（X = O和Cl）导致超分子聚集。[Ni（dbdtc）2]和[Ni（dbdtc）3] [FeCl4]（dbdtc
• Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4]
  作者：Richard Pastorek、Pavel Štarha、Tomáš Peterek、Zdeněk Trávníček

  DOI：10.1016/j.poly.2011.08.022

  日期：2011.11

  series of fourteen octahedral nickel(IV) dithiocarbamato complexes of the general formula [Ni(ndtc)3]X·yH2O ndtc stands for the appropriate dithiocarbamate anion, X stands for ClO4− (1–8; y = 0) or [FeCl4]− (9–14; y = 0 for 9–12, 1 for 13 and 0.5 for 14} was prepared by the oxidation of the corresponding nickel(II) complexes, i.e. [Ni(ndtc)2], with NOClO4 or FeCl3. The complexes, involving a high-valent

  通式[Ni（n dtc）3 ] X · y H 2 O n dtc的十四个八面体镍（IV）二硫代氨基甲酸酯配合物系列代表适当的二硫代氨基甲酸酯阴离子，X代表ClO 4 -（（1 – 8 ; Ý  = 0）或[的FeCl 4 ] - （9 - 14 ; Ÿ  = 0 9 - 12，1 13和0.5 14}通过用NOClO 4或FeCl 3氧化相应的镍（II）配合物，即[Ni（n dtc）2 ]来制备。通过元素分析（C，H，N，Cl和Ni），UV-Vis和FTIR光谱，热分析以及磁化学和电导率测量，对涉及高价Ni IV S 6核的配合物进行了表征。确定了[Ni（hmi dtc）3 ] [FeCl 4 ]（9）的X射线结构它由共价离散的复合物[Ni（hmi dtc）3 ] +阳离子和[FeCl 4 ] -组成阴离子}，这分别揭示了复杂阳离子和阴离子中八面体和四面体的几何形状略有变形。Ni（
• Eckstein, P.; Hoyer, E., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Eckstein, P.、Hoyer, E.

  DOI：——

  日期：——
• Novel octahedral nickel(II) dithiocarbamates with bi- or tetradentate N-donor ligands: X-ray structures of [Ni(Bzppzdtc)(phen)2]ClO4· CHCl3 and [Ni(Bz2dtc)2(cyclam)]
  作者：Zdeněk Trávníček、Richard Pastorek、Václav Slovák

  DOI：10.1016/j.poly.2007.09.024

  日期：2008.1

  A series of novel octahedral nickel(II) dithiocarbamate complexes involving bidentate nitrogen-donor ligands (phen = 1, 10-phenanthroline, bpy = 2,2'-bipyridine) or a tetradentate ligand (cyclam = 1,4,8,11-tetraazacycloteradecane) of the composition [Ni(BzMetdtc)(phen)(2)]ClO(4) (1), [Ni(Pe(2)dtc)(phen)(2)]ClO(4) (2), [Ni(Bzppzdtc)(phen)(2)]ClO(4) center dot CHCl(3) (3), [Ni(Bzppzdtc)(phen)(2)](SCN) (4), [Ni(BzMetdtc)(bpy)(2)]ClO(4) center dot 2H(2)O (5), [Ni(Pe(2)dtc)(cyclam)]ClO(4) (6), [Ni(BzMetdtC)(2)(cyclam)] (7), [Ni(Bz(2)dtC)(2)(cyclam)] (8) and [Ni(Bz(2)dtC)(2)(phen)] (9) (BzMetdtc = N,N-benzyl-methyldithiocarbamate(1-) anion, Pe(2)dtc = N,N-dipentyldithiocarbamate(1-) anion, Bz(2)dtc = N,N-dibenzyldithiocarbamate(1-) anion, Bzppzdtc = 4-benzylpiperazinedithiocarbamate(1-) anion), have been synthesized. Spectroscopic (electronic and infrared), magnetic moment and molar conductivity data, and thermal behaviour of the complexes are discussed. Single crystal X-ray analysis of 3 and 8 confirmed a distorted octahedral arrangement in the vicinity of the nickel atom with a N(4)S(2) donor set. They represent the first X-ray structures of such type complexes. The catalytic influence of complexes 2, 3, 6, and 7 on graphite oxidation was studied and discussed. (C) 2007 Elsevier Ltd. All rights reserved.