hexadeca-6,10,14-trienoic acid | 4444-12-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: hexadeca-6,10,14-trienoic acid
• 英文别名: Hexadeca-6,10,14-triensaeure；Pentadecatrien-(5.9.13)-carbonsaeure-(1)；Hiragonsaeure；Hiragonic acid；(6E,10E,14E)-hexadeca-6,10,14-trienoic acid
• CAS: 4444-12-6
• 化学式: C₁₆H₂₆O₂
• 分子量: 250.381
• InChiKey: ZKCRKOCVERWCLP-DJWHJZFYSA-N

物化性质

• 沸点：
  333.51°C (rough estimate)
• 密度：
  0.9296

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  hexadeca-6,10,14-trienoic acid 生成 棕榈酸
  参考文献：
  名称：

  Toyama; Tsuchiya, Bulletin of the Chemical Society of Japan, 1929, vol. 4, p. 87

  摘要：

  DOI：
• 作为产物：
  描述：

  hexadeca-6,10,14-trienoic acid methyl ester 生成 hexadeca-6,10,14-trienoic acid
  参考文献：
  名称：

  Toyama; Tsuchiya, Bulletin of the Chemical Society of Japan, 1929, vol. 4, p. 87

  摘要：

  DOI：

文献信息

• [EN] MINIMIZATION OF LIGAND DEGRADATION PRODUCTS, OF REVERSION OF SAME TO USEFUL PHOSPHINE LIGANDS<br/>[FR] MINIMISATION DE PRODUITS DE DEGRADATION DE LIGANDS OU REVERSION DE CES DERNIERS EN LIGANDS PHOSPHINE UTILES
  申请人：UNION CARBIDE CHEM PLASTIC

  公开号：WO2005007602A1

  公开（公告）日：2005-01-27

  A process for the minimization of phosphonium ion ligand degradation products formed during reaction of a polyunsaturated olefin or an unconjugated functionalized olefin in the presence of a transition metal-triorganophosphine ligand complex catalyst to form as a product, by-product, or intermediate product a conjugated functionalized olefin having a carbon-carbon double bond conjugated to an a-electron­withdrawing group, such as, an a,ß-unsaturated aldehyde, ketone, ester, acid, or nitrile. The minimization process involves conducting the reaction under selected conditions of conversion, temperature, pressure, or a combination thereof; and/or by selecting a triorganophosphine ligand with a specified steric and/or electronic property. Further, a process for reversion of phosphonium ion ligand degradation product(s) back to useful triorganophosphine ligand(s), the reversion involving treating a reaction product fluid containing the degradation product(s) with an inert gas, hydrogen, synthesis gas, or a mixture thereof under conditions sufficient to regenerate the triorganophosphine ligand(s).

  一种用于在存在过渡金属-三有机膦配体复合催化剂的情况下，通过反应多不饱和烯烃或非共轭官能化烯烃以形成产品、副产品或中间产物的方法，以最小化磷酮离子配体降解产物的过程，所述产物为具有碳-碳双键与α-电子受体基团共轭的官能化烯烃，如α,β-不饱和醛、酮、酯、酸或腈。最小化过程涉及在选择的转化率、温度、压力或其组合条件下进行反应；和/或通过选择具有特定立体和/或电子性能的三有机膦配体。此外，一种将磷酮离子配体降解产物回复为有用的三有机膦配体的方法，该回复涉及用惰性气体、氢气、合成气或二者的混合物处理含有降解产物的反应产物流体，在足以再生三有机膦配体的条件下进行处理。
• BONE METABOLISM IMPROVING AGENTS
  申请人：The Nisshin OilliO Group, Ltd.

  公开号：EP1380293A9

  公开（公告）日：2009-09-23

  The present invention relates to an improver for bone metabolism comprising one or at least two of chain isoprenoid fatty acid esters and preferably to an improver for bone metabolism whose improving effect is ascribable to the bone absorption-inhibitory action and/or the bone formation-promoting action of the esters.

  本发明涉及一种骨代谢改善剂，包括链异戊二烯脂肪酸酯中的一种或至少两种，并且更倾向于一种骨代谢改善剂，其改善作用归因于酯的抑制骨吸收作用和/或促进骨形成作用。
• Agent for improving bone metabolism
  申请人：The Nisshin Oillio, Ltd.

  公开号：US20040058995A1

  公开（公告）日：2004-03-25

  The present invention relates to an improver for bone metabolism comprising one or at least two of chain isoprenoid fatty acid esters and preferably to an improver for bone metabolism whose improving effect is ascribable to the bone absorption-inhibitory action and/or the bone formation-promoting action of the esters.

  本发明涉及一种骨代谢改善剂，其包括一种或至少两种链状异戊二烯脂肪酸酯，并且更倾向于一种骨代谢改善剂，其改善效果归因于这些酯的抑制骨吸收作用和/或促进骨形成作用。
• Process for the production of fine chemicals
  申请人：Puzio Piotr

  公开号：US20070118916A1

  公开（公告）日：2007-05-24

  The present invention relates to a process for the production of the fine chemical in a microorganism, a plant cell, a plant, a plant tissue or in one or more parts thereof, preferably in plastids. The invention furthermore relates to nucleic acid molecules, polypeptides, nucleic acid constructs, vectors, antibodies, host cells, plant tissue, propagation material, harvested material, plants, microorganisms as well as agricultural compositions and to their use.

  本发明涉及一种在微生物、植物细胞、植物、植物组织或其一部分中生产精细化学品的过程，优选在质体中进行。此外，本发明还涉及核酸分子、多肽、核酸构建物、载体、抗体、宿主细胞、植物组织、繁殖材料、收获材料、植物、微生物以及农业组合物以及它们的用途。
• Isocyanate-carboxyl group-containing fatty compounds for manufacture of cellulosic composites
  申请人：Jim Walter Research Corp.,

  公开号：EP0269869A2

  公开（公告）日：1988-06-08

  A binder/release system for the preparation of molded articles, especially lignocellulosic composites, which utilizes in combination with isocyanate-based binders a fatty material as an internal and/or external release agent, the fatty material being at least one polymerized fatty acid and/or at least one polycarboxyl compound containing a polymeric fatty radical(s).

  一种用于制备模塑制品，特别是木质纤维素复合材料的粘合剂/脱模体系，它与异氰酸酯基粘合剂结合使用，以脂肪材料作为内部和/或外部脱模剂，脂肪材料至少是一种聚合脂肪酸和/或至少一种含有聚合脂肪基的聚羧化合物。