5-[10-(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)-1,10-dihydroxydecylidene]-2,2-dimethyl-1,3-dioxane-4,6-dione | 81393-24-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 5-[10-(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)-1,10-dihydroxydecylidene]-2,2-dimethyl-1,3-dioxane-4,6-dione
• 英文别名: 5-[10-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)-1,10-dihydroxydecylidene]-2,2-dimethyl-1,3-dioxane-4,6-dione
• CAS: 81393-24-0
• 化学式: C₂₂H₃₀O₁₀
• 分子量: 454.474
• InChiKey: XKRYNVAYKURWTL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  32
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  146
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  5-[10-(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)-1,10-dihydroxydecylidene]-2,2-dimethyl-1,3-dioxane-4,6-dione 以 氯苯 、 苯 为溶剂， 反应 21.0h， 生成 (1E)-2-[[(1R)-1-phenylethyl]amino]-12-oxabicyclo[9.2.2]pentadeca-1,11(15)-diene-13,14-dione
  参考文献：
  名称：

  Convenient Synthesis of Chiral Cyclophanes that Can Coordinate to Metals

  摘要：

  Optically pure cyclophanes possessing a 1,3-dicarbonyl moiety were conveniently synthesized from alkanedioyl dichloride in four steps. The intramolecular [4+2]cycloaddition of bis(acylketene)s generated by thermal decomposition of bis(4,6-dioxo-1,3-dioxane) proceeded smoothly, giving cyclophane pyranones in high yields. The compounds possessing 7-10 bridging methylenes were resolved by imine formation with (R)-1-phenylethylamine, followed by basic hydrolysis. These cyclophanes are optically active versions of acetylacetone or salicylaldehyde and formed complexes with metals such as copper and europium. X-ray analysis of the chiral copper complex indicated the pentacoordinated structure of the copper metal with syn configuration of the two bridging chains.

  DOI：

  10.1021/ja983907u
• 作为产物：
  描述：

  丙二酸环(亚)异丙酯 、 癸二酰氯 在 4-二甲氨基吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 20.0h， 以41.5%的产率得到5-[10-(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)-1,10-dihydroxydecylidene]-2,2-dimethyl-1,3-dioxane-4,6-dione
  参考文献：
  名称：

  Cured film-forming composition

  摘要：

  提供的是一种治愈的成膜组合物，由该组合物形成的图像形成底层膜表现出高液体排斥性（亲疏性），即使暴露于低量紫外辐射下，底层膜的亲疏性和液体排斥性也可以轻松改变；以及使用该组合物获得的治愈膜。该治愈成膜树脂组合物的特点是包含：作为组分（A）的具有来自第一单体的结构单元的聚合物，该单体的结构式为（1）；除组分（A）外的另一种聚合物，其相对于聚合物总重量的含氟量低于组分（A），作为组分（B）；作为组分（C）的光酸发生剂；和溶剂。（在公式中，R1表示氢或甲基基团，R2表示能够与R2键合的氧原子一起脱落的含氟基团。）

  公开号：

  US10669376B2

文献信息

• Obaza, Judy; Smith, Francis X., Synthetic Communications, 1982, vol. 12, # 1, p. 19 - 24
  作者：Obaza, Judy、Smith, Francis X.

  DOI：——

  日期：——
• OBAZA, J.;SMITH, F. X., SYNTH. COMMUN., 1982, 12, N 1, 19-23
  作者：OBAZA, J.、SMITH, F. X.

  DOI：——

  日期：——
• CURED FILM-FORMING COMPOSITION
  申请人：NISSAN CHEMICAL CORPORATION

  公开号：US20190085130A1

  公开（公告）日：2019-03-21

  Provided are: a cured film-forming composition whereby a underlayer film for image formation formed from the composition exhibits high liquid repellency (lyophobicity) and lyophilic/liquid-repellent properties of the underlayer film can be easily changed even when exposed to a low amount of ultraviolet radiation; and a cured film obtained using the composition. The cured film-forming resin composition is characterized by containing: a polymer comprising a structural unit derived from a first monomer having the structure of formula (1) as component (A); a polymer other than component (A), which is a polymer in which the content of fluorine relative to the overall weight of the polymer is lower than in component (A), as component (B); a photoacid generator as component (C); and a solvent. (In the formula, R 1 denotes hydrogen or a methyl group, and R 2 denotes a fluorine-containing group able to be detached together with the oxygen atom bonded to R 2 .)
• Convenient Synthesis of Chiral Cyclophanes that Can Coordinate to Metals
  作者：Masayuki Sato、Fumiaki Uehara、Kayo Sato、Masahiko Yamaguchi、Chizuko Kabuto

  DOI：10.1021/ja983907u

  日期：1999.9.1

  Optically pure cyclophanes possessing a 1,3-dicarbonyl moiety were conveniently synthesized from alkanedioyl dichloride in four steps. The intramolecular [4+2]cycloaddition of bis(acylketene)s generated by thermal decomposition of bis(4,6-dioxo-1,3-dioxane) proceeded smoothly, giving cyclophane pyranones in high yields. The compounds possessing 7-10 bridging methylenes were resolved by imine formation with (R)-1-phenylethylamine, followed by basic hydrolysis. These cyclophanes are optically active versions of acetylacetone or salicylaldehyde and formed complexes with metals such as copper and europium. X-ray analysis of the chiral copper complex indicated the pentacoordinated structure of the copper metal with syn configuration of the two bridging chains.
• Cured film-forming composition
  申请人：NISSAN CHEMICAL CORPORATION

  公开号：US10669376B2

  公开（公告）日：2020-06-02

  Provided are: a cured film-forming composition whereby a underlayer film for image formation formed from the composition exhibits high liquid repellency (lyophobicity) and lyophilic/liquid-repellent properties of the underlayer film can be easily changed even when exposed to a low amount of ultraviolet radiation; and a cured film obtained using the composition. The cured film-forming resin composition is characterized by containing: a polymer comprising a structural unit derived from a first monomer having the structure of formula (1) as component (A); a polymer other than component (A), which is a polymer in which the content of fluorine relative to the overall weight of the polymer is lower than in component (A), as component (B); a photoacid generator as component (C); and a solvent. (In the formula, R1 denotes hydrogen or a methyl group, and R2 denotes a fluorine-containing group able to be detached together with the oxygen atom bonded to R2.)

  提供的是一种治愈的成膜组合物，由该组合物形成的图像形成底层膜表现出高液体排斥性（亲疏性），即使暴露于低量紫外辐射下，底层膜的亲疏性和液体排斥性也可以轻松改变；以及使用该组合物获得的治愈膜。该治愈成膜树脂组合物的特点是包含：作为组分（A）的具有来自第一单体的结构单元的聚合物，该单体的结构式为（1）；除组分（A）外的另一种聚合物，其相对于聚合物总重量的含氟量低于组分（A），作为组分（B）；作为组分（C）的光酸发生剂；和溶剂。（在公式中，R1表示氢或甲基基团，R2表示能够与R2键合的氧原子一起脱落的含氟基团。）