4'-acryloyloxybutyl 2,5-dihydroxybenzoate | 1401243-64-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4'-acryloyloxybutyl 2,5-dihydroxybenzoate
• 英文别名: 4-(Acryloyloxy)butyl 2,5-Dihydroxybenzoate；4-prop-2-enoyloxybutyl 2,5-dihydroxybenzoate
• CAS: 1401243-64-8
• 化学式: C₁₄H₁₆O₆
• 分子量: 280.277
• InChiKey: ZLJOIMZFVJERRB-UHFFFAOYSA-N

物化性质

• 沸点：
  459.0±35.0 °C(Predicted)
• 密度：
  1.263±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  93.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  对乙氧基苯甲酸 、 4'-acryloyloxybutyl 2,5-dihydroxybenzoate 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 生成 4''-acryloyloxybutyl 2,5-di(4'-ethyloxybenzoyloxy) benzoate
  参考文献：
  名称：

  Contraction of side-on nematic liquid crystalline elastomers micropillars: Influence of molecular parameters

  摘要：

  We investigated the structure-property relationship of nematic liquid crystalline elastomer (LCE) actuators obtained from a series of nematic side-on monomers. The liquid crystalline acrylate monomers were designed and synthesized with different tail lengths. Combining a soft lithography technique with photo-polymerization/photo-crosslinking of aligned nematic liquid crystalline monomers and crosslinkers, nematic LCE micropillars were obtained, based on the new monomers. Through microscopic observation, influence of some structural parameters on the thermo-mechanical behavior of the micropillars was investigated. The thermo-mechanical behavior of the LCEs showed a close correlation with to the tail length of the monomer and the spacer length of the crosslinker.

  DOI：

  10.1080/15421406.2016.1262710
• 作为产物：
  描述：

  2,5-二羟基苯甲酸 在 potassium hydrogencarbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 4'-acryloyloxybutyl 2,5-dihydroxybenzoate
  参考文献：
  名称：

  Effect of molecular parameters on thermomechanical behavior of side-on nematic liquid crystal elastomers

  摘要：

  We investigated the structure-property relationship of liquid crystal elastomers (LCEs) obtained from a series of nematic side-on monomers. A new synthetic strategy was developed to obtain the acrylate monomers (n-ADBB), which gave us the opportunity to easily modify the spacer lengths of the monomers. Through magnetic field alignment, well-defined LCE micropillars were fabricated from the monomers by a method combining soft lithography and photopolymerization/photocrosslinking of the monomers and a crosslinker. The influence of structural parameters on the thermomechanical deformation of the microstructures was studied through microscopic observations. The study quantitatively revealed the correlation of thermomechanical behavior of the microstructured LCEs with the crosslinking density and length of the flexible spacer linking the mesogenic core to the backbone. With a proper control of the structural parameters, optimized performances such as large reversible contraction, good elasticity and mechanical robustness were demonstrated for this type of LCEs. (c) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2013.07.057

文献信息

• 重合性化合物及び光学異方体
  申请人：ＤＩＣ株式会社

  公开号：JP2016193869A

  公开（公告）日：2016-11-17

  【課題】 本発明が解決しようとする課題は、重合性組成物に添加した際に結晶の析出等が起こらず高い保存安定性を有するような重合性化合物を提供し、当該重合性化合物を含有する重合性組成物を重合して得られる重合物を作製した際に均一なホメオトロピック配向が形成される重合性組成物を提供することである。更に、当該重合性組成物を重合させることで得られるヘイズが少なく、ムラが少ない重合体及び当該重合体を用いた光学異方体を提供することである。【解決手段】 本願発明は一般式（Ｉ）【化１】で表される化合物を提供し、併せて当該化合物を含有する組成物、当該組成物を重合させることにより得られる重合体及び当該重合体を用いた光学異方体等を提供する。【選択図】 なし

  The problem that the present invention aims to solve is to provide a polymerizable compound that, when added to a polymerizable composition, does not cause crystallization or other issues, and has high storage stability. The goal is to provide a polymerizable composition with the polymerizable compound that, when polymerized to obtain a polymer, forms a uniform homeotropic alignment. Furthermore, the invention aims to provide a polymerizable composition that, when polymerized, results in a polymer with low haze and minimal unevenness, as well as optical anisotropic materials using the polymer. The present invention provides a compound represented by the general formula (I) [Chemical 1], a composition containing the compound, a polymer obtained by polymerizing the composition, and optical anisotropic materials using the polymer. [No drawings]
• 重合性化合物、ポリマー、重合性組成物、フィルム、および投映像表示用ハーフミラー
  申请人：富士フイルム株式会社

  公开号：JP2015163596A

  公开（公告）日：2015-09-10

  【課題】新規な重合性化合物及び低複屈折性位相差膜、または反射波長域の選択性の高い反射膜等のフィルムの提供。【解決手段】式（Ｉ）で表される重合性化合物、前記重合性化合物を含む重合性組成物、前記重合性組成物から形成されるフィルム、並びに前記フィルムを含む投映像表示用ハーフミラー。［Ｒ1はアルキル基等；Ａはｍ＋ｎ価の環状基；Ｌ1は単結合等；Ｌ2は−ＣＯＯ−等；Ｚは−ＯＣＯ−等；Ｓｐはアルキレン基又はアルキレンオキシ基等；Ｑは（メタ）アクリロイル基等の重合性基；ｌは０〜２の整数；ｍは１又は２の整数；ｎは１〜３の整数］【選択図】図３

  【问题】提供新的重合性化合物、低複屈折性位相差膜、或具有高选择性反射膜的薄膜。 【解决方案】由式（I）表示的重合性化合物，包括该重合性化合物的重合性组合物，由该重合性组合物形成的薄膜，以及包含该薄膜的半镜面显示器。[其中，R1是烷基等；A是m+n价环状基；L1是单键等；L2是-COO-等；Z是-OOC-等；Sp是烷基或烷氧基等；Q是（甲）丙烯酰基等重合性基；l是0〜2的整数；m是1或2的整数；n是1〜3的整数] 【选图】图3
• POLYMERIZABLE COMPOUND, POLYMER, POLYMERIZABLE COMPOSITION, FILM, AND HALF MIRROR FOR DISPLAYING PROJECTION IMAGE
  申请人：FUJIFILM Corporation

  公开号：US20170009138A1

  公开（公告）日：2017-01-12

  The present invention provides a polymerizable compound denoted by Formula (I): in the formula, Z 1 and Z 2 represent an arylene group, and the like, m represents 1 or 2, n represents an integer of 0 or 1, and when m is 2, n is 0, L 1 , L 2 , L 3 , and L 4 each independently represent a linking group such as —C(═O)O— and —OC(═O)—, T 3 represents -Sp 4 -R 4 , X represents —O—, and the like, r represents 1 to 4, Sp 1 , Sp 2 , Sp 3 , Sp 4 , and Sp 5 each independently represent a single bond or a linking group, R 1 and R 2 each independently represent a polymerizable group, and R 3 , R 4 , and R 5 each independently represent a hydrogen atom, a polymerizable group, or the like; a polymerizable composition containing the polymerizable compound described above; a film formed of the polymerizable composition described above; and a half mirror for displaying a projection image including the film described above.

  本发明提供了一种由式（I）表示的可聚合化合物：在该式中，Z1和Z2表示芳基基团等，m表示1或2，n表示0或1，当m为2时，n为0，L1、L2、L3和L4分别独立地表示链接基，例如—C（═O）O—和—OC（═O）—，T3表示-Sp4-R4，X表示—O—等，r表示1到4，Sp1、Sp2、Sp3、Sp4和Sp5分别独立地表示单键或链接基，R1和R2分别独立地表示可聚合基团，R3、R4和R5分别独立地表示氢原子、可聚合基团等；一种包含上述可聚合化合物的可聚合组合物；一种由上述可聚合组合物形成的薄膜；以及用于显示投影图像的半镜，其中包括上述薄膜。
• Polymerizable compound, polymer, polymerizable composition, film, and half mirror for displaying projection image
  申请人：FUJIFILM Corporation

  公开号：US10012868B2

  公开（公告）日：2018-07-03

  The present invention provides a polymerizable compound denoted by Formula (I): in the formula, Z1 and Z2 represent an arylene group, and the like, m represents 1 or 2, n represents an integer of 0 or 1, and when m is 2, n is 0, L1, L2, L3, and L4 each independently represent a linking group such as —C(═O)O— and —OC(═O)—, T3 represents -Sp4-R4, X represents —O—, and the like, r represents 1 to 4, Sp1, Sp2, Sp3, Sp4, and Sp5 each independently represent a single bond or a linking group, R1 and R2 each independently represent a polymerizable group, and R3, R4, and R5 each independently represent a hydrogen atom, a polymerizable group, or the like; a polymerizable composition containing the polymerizable compound described above; a film formed of the polymerizable composition described above; and a half mirror for displaying a projection image including the film described above.

  本发明提供了一种由式（I）表示的可聚合化合物：式中，Z1和Z2代表芳烯基等，m代表1或2，n代表0或1的整数，当m为2时，n为0，L1、L2、L3和L4各自独立地代表连接基团，如-C(═O)O-和-OC(═O)-，T3代表-Sp4-R4，X代表-O-、和类似物，r 代表 1 至 4，Sp1、Sp2、Sp3、Sp4 和 Sp5 各自独立地代表单键或连接基团，R1 和 R2 各自独立地代表可聚合基团，R3、R4 和 R5 各自独立地代表氢原子、可聚合基团或类似物；含有上述可聚合化合物的可聚合组合物；由上述可聚合组合物形成的薄膜；以及用于显示包括上述薄膜在内的投影图像的半反射镜。
• Polymerizable compound, polymerizable composition, film, and half mirror for displaying projection image
  申请人：FUJIFILM Corporation

  公开号：US10457628B2

  公开（公告）日：2019-10-29

  The present invention provides a new polymerizable compound which is represented by Formula (I). In the formula, R1 indicates an alkyl group or the like, A represents a (m+n)valent cyclic group, L1 indicates a single bond or the like, L2 indicates —COO— or the like, Z indicates —COO— or the like, Sp indicates an alkylene group, an alkyleneoxy group, or the like, Q indicates a polymerizable group such as a (meth)acryloyl groups, 1 indicates an integer of 0 to 2, m indicates an integer of 1 or 2, and n indicates an integer of 1 to 3. The present invention also provides a polymerizable composition which includes the polymerizable compound described above, a film which is formed from the polymerizable composition described above, and a half mirror for displaying a projection image which includes the film described above. Using the polymerization composition described above, it is possible to manufacture films such as a low birefringence retardation film and a reflection film with high reflection wavelength region selectivity.

  本发明提供了一种新的可聚合化合物，由式（I）表示。式中，R1 表示烷基或类似物，A 表示(m+n)价环状基团，L1 表示单键或类似物，L2 表示-COO-或类似物，Z 表示-COO-或类似物，Sp 表示亚烷基、亚烷氧基或类似物，Q 表示可聚合基团，如(甲基)丙烯酰基，1 表示 0 至 2 的整数，m 表示 1 或 2 的整数，n 表示 1 至 3 的整数。本发明还提供了一种可聚合组合物，它包括上述可聚合化合物；一种薄膜，它由上述可聚合组合物形成；以及一种用于显示投影图像的半面镜，它包括上述薄膜。使用上述聚合组合物，可以制造出低双折射延缓膜和高反射波长区域选择性的反射膜等薄膜。