申请人:Yuan Caideng
公开号:US20090111934A1
公开(公告)日:2009-04-30
A novel method for the preparation of an aqueous polyacrylate modified polyurethane dispersion is disclosed. The preparation method includes three main steps:
a) preparation of polyacrylate polymer or copolymer emulsion;
b) preparation of polyurethane prepolymer with carboxylic groups and neutralization treatment to the carboxylic groups; and
c) dispersion and chain-extension of polyurethane prepolymer by adding the polyacrylate emulsion into the polyurethane prepolymer under vigorous agitation, or other mechanical operation.
The aqueous polyacrylate modified polyurethane dispersion has self-crosslinkability when an unsaturated acetoacetoxy compound is used for the preparation of the polyacrylate emulsion.