(+/-)-1-nonene-4-thiol | 1006684-28-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醇
• 英文名称: (+/-)-1-nonene-4-thiol
• 英文别名: Non-1-ene-4-thiol；non-1-ene-4-thiol
• CAS: 1006684-28-1
• 化学式: C₉H₁₈S
• 分子量: 158.308
• InChiKey: UQNRBXXFINLTKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (+/-)-1-nonene-4-thiol 、 正己醛 在 Et₄NF*5HF 作用下， 反应 1.5h， 生成 cis-4-fluoro-2,6-dipentylthiacyclohexane
  参考文献：
  名称：

  离子液体氟化氢盐中的 Prins 环化：4-氟化四氢吡喃、硫代环己烷和哌啶的简便高效合成

  摘要：

  在离子液体氟化氢 (HF) 盐中研究了高烯丙醇与各种醛的 Prins 环化，该盐起到反应介质、催化剂和氟源的作用。该反应以优异的收率和高立体选择性（仅顺式形式）提供了相应的 4-氟化四氢吡喃。当使用在对位具有强给电子基团的苯甲醛时，该体系失去了立体选择性。为了将此方法应用于其他4-氟化杂环化合物的合成，我们还在HF盐中进行了thia-Prins和aza-Prins环化，分别成功地获得了4-氟化硫杂环己烷和哌啶。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

  DOI：

  10.1002/ejoc.200800872
• 作为产物：
  描述：

  (+/-)-S-(1-pentyl-3-butenyl) ethanethioate 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 以76%的产率得到(+/-)-1-nonene-4-thiol
  参考文献：
  名称：

  红灯笼椒（辣椒）的同时蒸馏萃取提取物中的新的挥发性挥发性含硫成分。

  摘要：

  通过同时蒸馏-萃取（SDE，Likens-Nickerson）制备红甜椒（Capsicum annuum）的提取物。除了已知的（3 E）-3-庚-2-酮（1）外，不饱和C9-酮1-壬烯-4-酮（2），（2 E）-2-壬烯-4-酮（3）和（2 E，5 E）-2,5-nonadien-4-one（4），2-甲氧基-3-异丁基吡嗪（5）和庚烷-2-硫醇（6），我们确定了19新硫醇（脂族饱和和不饱和硫醇14-16和22-27，巯基酮12和13，巯基醇17、18和30，二硫醇19和28，甲硫醇20和21 ，以及噻吩-硫醇31）和两个新的二噻吩10和29。它们在结构上均与不饱和C7-和C9-酮1-4相关。使用Affi-Gel 501（对氨基苯酚）富集了游离硫醇-乙酸汞接枝在琼脂糖凝胶上）。

  DOI：

  10.1021/jf072493y

文献信息

• AMPHIPHILIC POLYMER AND PROCESSES OF FORMING THE SAME
  申请人：Janczewski Dominik

  公开号：US20100298504A1

  公开（公告）日：2010-11-25

  Disclosed are an amphiphilic polymer, its synthesis and uses thereof. The polymer has a hydrocarbon backbone with —COOH side groups. It further has first aliphatic moieties with a main chain of about 3 to about 20 carbon atoms and 0 to about 3 heteroatoms, and second aliphatic moieties that have a main chain of about 3 to about 80 carbon atoms and about 2 to about 40 heteroatoms. The second aliphatic moieties have a copolymerisable group. In the synthesis a maleic anhydride polymer of formula (I) where n is an integer from about 10 to about 10000 and R1 is H or methyl, is reacted with a monofunctional compound with an alkyl chain of about 3 to about 20 carbon atoms and 0 to about 2 heteroatoms, and with an at least bifunctional compound with an alkyl chain of about 3 to about 80 carbon atoms and 0 to about 40 heteroatoms. The functional group of the monofunctional compound and one functional group of the at least bifunctional compound can form a linkage with an anhydride. Another functional group of the at least bifunctional compound, which is not allowed to react with the maleic anhydride polymer, is copolymerisable.
• [EN] AMPHIPHILIC POLYMER AND PROCESSES OF FORMING THE SAME<br/>[FR] POLYMÈRE AMPHIPHILE ET SES PROCÉDÉS DE FABRICATION
  申请人：AGENCY SCIENCE TECH & RES

  公开号：WO2009038544A1

  公开（公告）日：2009-03-26

  Disclosed are an amphiphilic polymer, its synthesis and uses thereof. The polymer has a hydrocarbon backbone with -COOH side groups. It further has first aliphatic moieties with a main chain of about 3 to about 20 carbon atoms and 0 to about 3 heteroatoms, and second aliphatic moieties that have a main chain of about 3 to about 80 carbon atoms and about 2 to about 40 heteroatoms. The second aliphatic moieties have a copolymerisable group. In the synthesis a maleic anhydride polymer of formula (I) where n is an integer from about 10 to about 10000 and R1 is H or methyl, is reacted with a monofunctional compound with an alkyl chain of about 3 to about 20 carbon atoms and 0 to about 2 heteroatoms, and with an at least bifunctional compound with an alkyl chain of about 3 to about 80 carbon atoms and 0 to about 40 heteroatoms. The functional group of the monofunctional compound and one functional group of the at least bifunctional compound can form a linkage with an anhydride. Another functional group of the at least bifunctional compound, which is not allowed to react with the maleic anhydride polymer, is copolymerisable.
• New Volatile Sulfur-Containing Constituents in a Simultaneous Distillation−Extraction Extract of Red Bell Peppers (Capsicum annuum)
  作者：Regula Naef、Alain Velluz、Alain Jaquier

  DOI：10.1021/jf072493y

  日期：2008.1.1

  mercapto-alcohols 17, 18, and 30, the dithiols 19 and 28, the methylthio-thiols 20 and 21, and the thiophene-thiol 31) and the two new dithiolanes 10 and 29. All of them are structurally related to the unsaturated C7- and C9-ketones 1- 4. The free thiols were enriched using Affi-Gel 501 ( p-aminophenyl-mercuric acetate grafted on an agarose gel). The new compounds were confirmed by syntheses and were organoleptically

  通过同时蒸馏-萃取（SDE，Likens-Nickerson）制备红甜椒（Capsicum annuum）的提取物。除了已知的（3 E）-3-庚-2-酮（1）外，不饱和C9-酮1-壬烯-4-酮（2），（2 E）-2-壬烯-4-酮（3）和（2 E，5 E）-2,5-nonadien-4-one（4），2-甲氧基-3-异丁基吡嗪（5）和庚烷-2-硫醇（6），我们确定了19新硫醇（脂族饱和和不饱和硫醇14-16和22-27，巯基酮12和13，巯基醇17、18和30，二硫醇19和28，甲硫醇20和21 ，以及噻吩-硫醇31）和两个新的二噻吩10和29。它们在结构上均与不饱和C7-和C9-酮1-4相关。使用Affi-Gel 501（对氨基苯酚）富集了游离硫醇-乙酸汞接枝在琼脂糖凝胶上）。
• Prins Cyclization in Ionic Liquid Hydrogen Fluoride Salts: Facile and Highly Efficient Synthesis of 4-Fluorinated Tetrahydropyrans, Thiacyclohexanes, and Piperidines
  作者：Yuichiro Kishi、Shinsuke Inagi、Toshio Fuchigami

  DOI：10.1002/ejoc.200800872

  日期：——

  Prins cyclization of homoallylic alcohols with various aldehydes was investigated in ionic liquid hydrogen fluoride (HF) salts, which played roles as a reaction medium, a catalyst, and a fluorine source. The reaction afforded the corresponding 4-fluorinated tetrahydropyrans in excellent yields with a high stereoselectivity (cis form exclusively). When benzaldehydes having a strongly electron-donating

  在离子液体氟化氢 (HF) 盐中研究了高烯丙醇与各种醛的 Prins 环化，该盐起到反应介质、催化剂和氟源的作用。该反应以优异的收率和高立体选择性（仅顺式形式）提供了相应的 4-氟化四氢吡喃。当使用在对位具有强给电子基团的苯甲醛时，该体系失去了立体选择性。为了将此方法应用于其他4-氟化杂环化合物的合成，我们还在HF盐中进行了thia-Prins和aza-Prins环化，分别成功地获得了4-氟化硫杂环己烷和哌啶。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)