1-allyloxy-2-phenoxy-ethane | 93066-80-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-allyloxy-2-phenoxy-ethane
• 英文别名: 1-Allyloxy-2-phenoxy-aethan；2-allyloxyethyl phenyl ether；{2-[(Prop-2-en-1-yl)oxy]ethoxy}benzene；2-prop-2-enoxyethoxybenzene
• CAS: 93066-80-9
• 化学式: C₁₁H₁₄O₂
• 分子量: 178.231
• InChiKey: VADSFFHKELMJIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-allyloxy-2-phenoxy-ethane 、 三氯硅烷 在 氯铂酸 氮 、 crude product 、 531 作用下， 反应 4.0h， 以giving 250 g of 3-(2-phenoxyethoxy)propyltrichlorosilane having an acid number of 531的产率得到3-(2-phenoxyethoxy)propyltrichlorosilane
  参考文献：
  名称：

  Iodonium salts and process for the preparation thereof

  摘要：

  本发明涉及一般式A-I.sup.+ --B X.sup.-的碘鎓盐，其中A是以下一般式的基团：##STR1## 其中C是具有6至14个碳原子的一价芳香烃基或含有至少一个氧和/或硫原子且具有5至14个芳香环中原子的一价芳香烃基，D、E和F分别是C的取代基，其中D是以下式子的基团：--(O).sub.x --(R).sub.y --SiR1/3，E是以下式子的基团：--OR.sup.2，F是以下式子的基团：--R.sup.3，a为1、2或3，b为0、1或2，c为0、1或2，x为0或1，y为0或1，R、R.sup.1、R.sup.2和R.sup.3如权利要求1所定义；B是以下式子的基团：##STR2## 其中E和F，如上所定义，可以各自与苯环中的2、3、4、5或6位置结合，d为0、1或2，e为0、1或2，X.sup.-是tosylate阴离子或从CF.sub.3 CO.sub.2.sup.-，BF.sub.4.sup.-，PF.sub.4.sup.-，AsF.sub.6.sup.-，SbF.sub.6.sup.-，ClO.sub.4.sup.-，HSO.sub.4.sup.-和CF.sub.3 SO.sub.3.sup.-的群组中选择的弱亲核或非亲核阴离子Y.sup.-。

  公开号：

  US05468890A1
• 作为产物：
  描述：

  3-溴丙烯 、 alkaline earth salt of/the/ methylsulfuric acid 在 乙醚 、 苯 作用下， 生成 1-allyloxy-2-phenoxy-ethane
  参考文献：
  名称：

  New Compounds. Some New Compounds as Possible Insect Repellents

  摘要：

  DOI：

  10.1021/ja01214a602

文献信息

• Sulfonium salts and process for their preparation
  申请人：Wacker-Chemie GmbH

  公开号：US05466845A1

  公开（公告）日：1995-11-14

  The present invention provides photoactive sulfonium salts which can be employed as photoinitiators for the polymerization of cationically polymerized organic substances and are soluble in these substances.

  本发明提供了一种光活性亚硫酸盐，可用作阳离子聚合有机物的光引发剂，并且可溶于这些物质中。
• REACTIVE AMINE CATALYSTS FOR POLYURETHANE APPLICATIONS
  申请人：Air Products and Chemicals, Inc.

  公开号：US20160347901A1

  公开（公告）日：2016-12-01

  Tertiary amine catalysts having isocyanate reactive groups that are capable of forming thermally stable covalent bonds able to withstand temperatures up to 120° C. are disclosed. These catalyst can be used to produce polyurethane foam having the following desirable characteristics: a) very low chemical emissions over a wide range of environmental conditions and isocyanate indexes (e.g. indexes as low as 65 but higher than 60) while meeting all physical property requirements; b) sufficient hydrolytic stability to maintain the catalyst covalently bound to foam without leaching of tertiary amine catalyst when foam is exposed to water or aqueous solutions even at temperatures higher than ambient (temperature range 25° C. to 90° C.); and c) stable contact interface between the polyurethane polymer and other polymers (for example polycarbonate) with minimal migration of tertiary amine catalyst from polyurethane polymer to other polymers yielding no noticeable polymer deterioration at the point of contact even under conditions of heat and humidity.

  揭示了具有异氰酸酯反应基团的三级胺催化剂，能够形成能够承受高达120°C温度的热稳定共价键。这些催化剂可用于生产具有以下理想特性的聚氨酯泡沫：a) 在各种环境条件和异氰酸酯指数（例如指数低至65但高于60）下，化学排放极低，同时满足所有物理性能要求；b) 具有足够的水解稳定性，使催化剂能够共价结合到泡沫中，即使在高于环境温度的条件下，泡沫暴露在水或水溶液中（温度范围为25°C至90°C）也不会渗漏三级胺催化剂；c) 聚氨酯聚合物与其他聚合物（例如聚碳酸酯）之间的稳定接触界面，使三级胺催化剂从聚氨酯聚合物迁移到其他聚合物的最小，即使在热和湿度条件下，接触点处也不会出现明显的聚合物恶化。
• PROCESS FOR PREPARING RUST INHIBITORS FROM CASHEW NUT SHELL LIQUID
  申请人：Indian Oil Corporation Limited

  公开号：US20030050198A1

  公开（公告）日：2003-03-13

  A process for the preparation of CNSL phenoxy carboxylic acid derivatives for use as an additive in a lubricant composition so as to impart improved rust inhibiting properties, including the steps of (a) partially hydrogenating distilled technical cashew nut shell liquid with palladium or nickel or platinum catalyst; to hydrogenate the olefinic chain; (b) reacting cashew nut shell liquid or partially hydrogenated technical cashew nut shell liquid with halogeno carboxylic acid derivatives to obtain unpolymerized cashew nut shell liquid phenoxy carboxylic acid derivatives, the reaction being carried out at a temperature ranging from 20 to 140° C. A lubricant containing a major proportion of a material selected from the group consisting of an oil of lubricating viscosity and a grease; and remainder an additive including CNSL phenoxy carboxylic acid derivative prepared by the foregoing process.

  一种制备CNSL苯氧基羧酸衍生物的过程，用作润滑剂组成中的添加剂，以赋予改善的防锈性能，包括以下步骤：（a）使用钯、镍或铂催化剂部分加氢蒸馏技术腰果壳液，以加氢烯烃链；（b）将腰果壳液或部分加氢技术腰果壳液与卤代羧酸衍生物反应，以获得未聚合的腰果壳液苯氧基羧酸衍生物，反应在20至140°C的温度范围内进行。润滑剂含有从润滑粘度油和润滑脂组成的主要成分，以及通过上述过程制备的CNSL苯氧基羧酸衍生物为余量的添加剂。
• Low Emissions Polyurethane Foam Made with Isocyanate Reactive Amine Catalyst
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：US20160075817A1

  公开（公告）日：2016-03-17

  Tertiary amine catalysts having isocyanate reactive groups that are capable of forming thermally stable covalent bonds able to withstand temperatures from 120° C. and higher and up to 250° C. are disclosed. These catalyst can be used to produce polyurethane foam having the following desirable characteristics: a) very low chemical emissions over a wide range of environmental conditions and isocyanate indexes (e.g., indexes as low as 65 but higher than 60) ; b) sufficient hydrolytic stability to maintain the catalyst covalently bound to foam without leaching of tertiary amine catalyst when foam is exposed to water or aqueous solutions even at temperatures higher than ambient (temperature range 25° C. to 90° C.); and c) stable contact interface between the polyurethane polymer and other polymers (for example polycarbonate) with minimal migration of tertiary amine catalyst from polyurethane polymer to other polymers yielding no noticeable polymer deterioration at the point of contact even under conditions of heat and humidity.

  本发明揭示了具有异氰酸酯反应基的三级胺催化剂，能够形成热稳定的共价键，能够承受120°C及更高温度，甚至可达250°C。这些催化剂可用于生产聚氨酯泡沫，具有以下理想特性：a）在广泛的环境条件和异氰酸酯指数（例如指数低至65但高于60）下，具有非常低的化学排放；b）具有足够的水解稳定性，以使催化剂共价结合到泡沫中，即使在高于环境温度（25°C至90°C）的水或水溶液中暴露泡沫，也不会出现三级胺催化剂渗出；c）聚氨酯聚合物与其他聚合物（例如聚碳酸酯）之间的稳定接触界面，即使在热和湿度条件下，也只有极少量的三级胺催化剂从聚氨酯聚合物迁移到其他聚合物，不会在接触点处出现明显的聚合物恶化。
• Propynylaminothiazole derivatives
  申请人：SHIONOGI & CO., LTD.

  公开号：EP0111904A2

  公开（公告）日：1984-06-27

  New 2-(2-propynylamino)thiazole and 2-(3-iodo-2-propynylamino)thiazole derivatives having anti-microbial activity which are used as an active ingredient in anti-microbial compositions for medical and agricultural use.

  具有抗微生物活性的新型 2-(2-丙炔基氨基)噻唑和 2-(3-碘-2-丙炔基氨基)噻唑衍生物，可用作医用和农用抗微生物组合物的活性成分。