N1,N3-di(pyridin-4-yl)benzene-1,3-bis(carbothioamide) | 1319189-62-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N1,N3-di(pyridin-4-yl)benzene-1,3-bis(carbothioamide)
• 英文别名: 1-N,3-N-dipyridin-4-ylbenzene-1,3-dicarbothioamide
• CAS: 1319189-62-2
• 化学式: C₁₈H₁₄N₄S₂
• 分子量: 350.468
• InChiKey: FEINALPKRRQMRF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  114
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  fac-[Re(CH3CN)(CO)3(4,4'-di-tert-butyl-2,2'-bipyridine)][PF6] 、 N1,N3-di(pyridin-4-yl)benzene-1,3-bis(carbothioamide) 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  rh（I）羰基具有极性NH识别基序的阴离子感测

  摘要：

  本文介绍了我们对几种带有极化N–H识别基序作为阴离子受体的rh（I）羰基配合物的最新研究结果。已经开发出结构简单且易于合成的包含酰胺型阴离子结合位点和a（I）三羰基吡啶信号传导单元的发光阴离子受体，它们显示出对各种阴离子的出色灵敏度和选择性。此外，已经合成了2，6-吡啶二羰基二氯化物，间苯二甲酰二氯和对苯二甲酰二氯的硫代酰胺和硫脲衍生物。这些配体已被引入双核nu（I）二亚胺三羰基配合物中，并在这些配合物中提供了阴离子识别特性。此外，

  DOI：

  10.1016/j.ica.2012.02.001
• 作为产物：
  描述：

  N,N′-bis-4-pyridinyl-isophthalamide 在 劳森试剂 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 生成 N1,N3-di(pyridin-4-yl)benzene-1,3-bis(carbothioamide)
  参考文献：
  名称：

  Thioamide, urea and thiourea bridged rhenium(I) complexes as luminescent anion receptors

  摘要：

  Thioamides, urea and thiourea derivatives of 2,6-pyridinedicarbonyl dichloride, isophthaloyl dichloride and terephthaloyl dichloride have been synthesized. These ligands have been incorporated in dinuclear rhenium(I) diimine tricarbonyl complexes and the anion recognition properties of these complexes have been studied by luminescence, UV-Vis and (1)H NMR spectroscopic methods. The complexes act as receptors for anions via hydrogen bonding and electrostatic interactions. The anion sensing properties of the complexes are compared to earlier amide-based dinuclear rhenium(I) tricarbonyl complexes. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.065

文献信息

• Anion sensing by rhenium(I) carbonyls with polarized N–H recognition motifs
  作者：Kai-Chi Chang、Shih-Sheng Sun、Alistair J. Lees

  DOI：10.1016/j.ica.2012.02.001

  日期：2012.7

  ligands have been incorporated in dinuclear rhenium(I) diimine tricarbonyl complexes and provide anion recognition properties in these complexes. Furthermore, the related rhenium(I) complex featuring sulfonamide interacting sites that incorporate the highly chromophoric π-conjugated quinoxaline moiety has been prepared, characterized, and its photophysical properties were also studied.

  本文介绍了我们对几种带有极化N–H识别基序作为阴离子受体的rh（I）羰基配合物的最新研究结果。已经开发出结构简单且易于合成的包含酰胺型阴离子结合位点和a（I）三羰基吡啶信号传导单元的发光阴离子受体，它们显示出对各种阴离子的出色灵敏度和选择性。此外，已经合成了2，6-吡啶二羰基二氯化物，间苯二甲酰二氯和对苯二甲酰二氯的硫代酰胺和硫脲衍生物。这些配体已被引入双核nu（I）二亚胺三羰基配合物中，并在这些配合物中提供了阴离子识别特性。此外，
• Thioamide, urea and thiourea bridged rhenium(I) complexes as luminescent anion receptors
  作者：Maurice O. Odago、Amanda E. Hoffman、Russell L. Carpenter、Douglas Chi Tak Tse、Shih-Sheng Sun、Alistair J. Lees

  DOI：10.1016/j.ica.2011.02.065

  日期：2011.8

  Thioamides, urea and thiourea derivatives of 2,6-pyridinedicarbonyl dichloride, isophthaloyl dichloride and terephthaloyl dichloride have been synthesized. These ligands have been incorporated in dinuclear rhenium(I) diimine tricarbonyl complexes and the anion recognition properties of these complexes have been studied by luminescence, UV-Vis and (1)H NMR spectroscopic methods. The complexes act as receptors for anions via hydrogen bonding and electrostatic interactions. The anion sensing properties of the complexes are compared to earlier amide-based dinuclear rhenium(I) tricarbonyl complexes. (C) 2011 Elsevier B. V. All rights reserved.