5,5-dimethyl-2-(2'-phenylphenoxy)-1,3,2-dioxaphosphorinane-2-oxide | 929616-75-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5,5-dimethyl-2-(2'-phenylphenoxy)-1,3,2-dioxaphosphorinane-2-oxide
• 英文别名: 5,5-Dimethyl-2-(2-phenylphenoxy)-1,3,2lambda5-dioxaphosphinane 2-oxide；5,5-dimethyl-2-(2-phenylphenoxy)-1,3,2λ5-dioxaphosphinane 2-oxide
• CAS: 929616-75-1
• 化学式: C₁₇H₁₉O₄P
• 分子量: 318.309
• InChiKey: OUPCDFWTGHUQRO-UHFFFAOYSA-N

物化性质

• 沸点：
  403.5±28.0 °C(Predicted)
• 密度：
  1.23±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  5,5-二甲基-2-氯-1,3,2-二氧磷杂己内酰磷酸酯 、 邻苯基苯酚 在 三乙胺 、 magnesium chloride 作用下， 以 氯苯 为溶剂， 反应 2.0h， 生成 5,5-dimethyl-2-(2'-phenylphenoxy)-1,3,2-dioxaphosphorinane-2-oxide
  参考文献：
  名称：

  PHOSPHORUS COMPOUND, USE THEREOF AND FLAME-RETARDANT POLYESTER FIBER

  摘要：

  公开号：

  EP1925622B1

文献信息

• PHOSPHORIC ACID ESTER PRODUCTION METHOD
  申请人：Ono Yuki

  公开号：US20130072708A1

  公开（公告）日：2013-03-21

  The present invention provides a novel production method which enables obtain a phosphorus compound having both an aromatic substituent and a phosphorinane backbone, without using an expensive hydrogen halide scavenger, without going through a complicated post treatment step or a step of recovering a solvent, and with a favorable yield andpurity. In the present invention, step (1) of allowing phosphorus oxytrihalide to react with a phenol compound or naphthol compound at a molar ratio of 1.1-3.0:1 in the presence of metal halide, and removing unreacted phosphorus oxytrihalide, to produce a mono-substituted phosphorodihalidate; and step (2) of allowing the mono-substituted phosphorodihalidate obtained in the step (1) to react with a diol compound, at a 0.90 to 0.99 molar equivalent based on 1 mole of the halogen atom in the mono-substituted phosphorodihalidate so as to perform a dehydrohalogenation reaction, to obtain a phosphorus compound represented by Formula (V).

  本发明提供了一种新的生产方法，使得可以获得一种同时具有芳基取代基和磷杂环骨架的磷化合物，而无需使用昂贵的氢卤酸清除剂，也无需经过复杂的后处理步骤或回收溶剂的步骤，并且具有良好的产率和纯度。在本发明中，步骤（1）是在金属卤化物的存在下，让磷酸三卤化物与苯酚化合物或萘酚化合物以1.1-3.0:1的摩尔比反应，并去除未反应的磷酸三卤化物，以产生一种单取代磷酸二卤酯；步骤（2）是让步骤（1）中获得的单取代磷酸二卤酯与二元醇化合物以0.90至0.99摩尔当量反应（以单取代磷酸二卤酯中的卤原子为基础，1摩尔），从而进行脱卤化反应，以获得由公式（V）表示的磷化合物。
• PROCESSES FOR PRODUCTION OF CYCLIC ALKYLENE PHOSPHOROHALIDITE AND CYCLIC PHOSPHORIC ACID ESTER
  申请人：Hamada Toshiya

  公开号：US20120264965A1

  公开（公告）日：2012-10-18

  A process for producing a cyclic alkylene phosphorohalidite, which comprises reacting a specific phosphorus trihalide with a specific alkylene glycol compound under conditions where the phosphorus trihalide is present in an excess amount relative to the amount of the alkylene glycol compound in the reaction system to order to obtain the cyclic alkylene phosphorohalidite by reacting the alkylene glycol compound with the phosphorus trihalide; and a process for producing a cyclic phosphoric acid ester by using the obtained cyclic alkylene phosphorohalidite as a raw material.

  一种生产环状烷基磷卤代酸酐的方法，包括在磷三卤化物相对于反应体系中烷基二醇化合物的量处于过量的条件下，将特定的磷三卤化物与特定的烷基二醇化合物反应，以便通过烷基二醇化合物与磷三卤化物的反应获得环状烷基磷卤代酸酐；以及通过使用获得的环状烷基磷卤代酸酐作为原料来生产环状磷酸酯的方法。
• Flame retardant coating agent for vehicle seat, and manufacturing method for flame retardant vehicle seat material
  申请人：NICCA CHEMICAL CO. LTD.

  公开号：US10577509B2

  公开（公告）日：2020-03-03

  Provided is a flame-retardant coating agent for vehicle seats that contains (A) a nitrogen-containing compound, and (C) an aqueous thermoplastic resin. Also provided is a flame-retardant vehicle seat material that does not use a halogen compound or an antimony compound, that exhibits sufficient flame retardancy, and that suppresses the occurrence of marks from hot water.

  本发明提供了一种用于汽车座椅的阻燃涂层剂，它含有 (A) 含氮化合物和 (C) 水性热塑性树脂。还提供了一种不使用卤素化合物或锑化合物的阻燃汽车座椅材料，该材料具有足够的阻燃性，并能抑制热水痕迹的产生。
• PHOSPHORUS COMPOUNDS, USE THEREOF AND FLAME RETARDING POLYESTER FIBERS
  申请人：Kyoda Makoto

  公开号：US20090227713A1

  公开（公告）日：2009-09-10

  A phosphorus compound represented by the formula (I): wherein R 1 and R 2 are, the same or different, a hydrogen atom, a straight or branched-chain alkyl group having 1 to 6 carbon atoms or an aryl group having 6 to 12 carbon atoms which may be optionally substituted for an alkyl group having 1 to 4 carbon atoms, R 3 , R 4 , R 5 , R 6 and R 7 are, the same or different, a hydrogen atom or an aryl group having 6 to 12 carbon atoms which may be optionally substituted for an alkyl group having 1 to 4 carbon atoms, or R 3 and R 4 , R 4 and R 5 , R 5 and R 6 or R 6 and R 7 may form a 6 membered ring with carbon atoms wherein these groups bond a benzene ring provided that R 3 , R 4 , R 5 , R 6 and R 7 are not hydrogen atoms at the same time.
• FLAME RETARDANT COATING AGENT FOR VEHICLE SEAT, AND MANUFACTURING METHOD FOR FLAME RETARDANT VEHICLE SEAT MATERIAL
  申请人：NICCA CHEMICAL CO. LTD.

  公开号：US20160333193A1

  公开（公告）日：2016-11-17

  Provided is a flame-retardant coating agent for vehicle seats that contains (A) a nitrogen-containing compound, and (C) an aqueous thermoplastic resin. Also provided is a flame-retardant vehicle seat material that does not use a halogen compound or an antimony compound, that exhibits sufficient flame retardancy, and that suppresses the occurrence of marks from hot water.