2-acetoxymethyl-acrylic acid | 89533-83-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-acetoxymethyl-acrylic acid
• 英文别名: 2-Acetoxymethyl-acrylsaeure；2-Carboxy-allyl acetate；2-(acetyloxymethyl)prop-2-enoic acid
• CAS: 89533-83-5
• 化学式: C₆H₈O₄
• mdl: MFCD19229028
• 分子量: 144.127
• InChiKey: PASKRLYOVZYATH-UHFFFAOYSA-N

物化性质

• 熔点：
  53 °C
• 沸点：
  286.7±23.0 °C(Predicted)
• 密度：
  1.195±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-acetoxymethyl-acrylic acid 在 甲醇 、 硫酸 作用下， 生成 2-(羟甲基)丙烯酸甲酯
  参考文献：
  名称：

  Jones et al., Journal of the Chemical Society, 1950, p. 236,240

  摘要：

  DOI：
• 作为产物：
  描述：

  乙酸炔丙酯 、 alkaline earth salt of/the/ methylsulfuric acid 在 乙醇 、 溶剂黄146 作用下， 生成 2-acetoxymethyl-acrylic acid
  参考文献：
  名称：

  Jones et al., Journal of the Chemical Society, 1950, p. 236,240

  摘要：

  DOI：

文献信息

• Diazotization of 1-aminocyclopropanecarboxylic acid. Solution chemistry of oxaspiropentanone
  作者：Michael C. Pirrung、William L. Brown

  DOI：10.1021/ja00173a032

  日期：1990.8

  La 1-oxaspiro [2,2] pentan-2-one est un intermediaire dans la diazotation de l'acide 1-aminocyclopropanecarboxylique

  La 1-oxaspiro [2,2] pentan-2-one est un intermediaire dans la diazotation de l'acide 1-aminocyclopropanecarboxylique
• Alicyclic methacrylate having oxygen substituent group on alpha-methyl
  申请人：——

  公开号：US20040176630A1

  公开（公告）日：2004-09-09

  Alicyclic methacrylate compounds having an oxygen substituent group on their &agr;-methyl group, represented by formula (1), are novel wherein R 1 is H or C 1 -C 10 alkyl which may contain a halogen atom, hydroxyl group, ether bond, carbonyl group, carboxyl group or cyano group, and R 2 is a monovalent C 3 -C 20 organic group having an alicyclic structure. Polymers prepared from these alicyclic methacrylate compounds have improved transparency, especially at the exposure wavelength of an excimer laser, and improved dry etching resistance. Resist compositions comprising the polymers are sensitive to high-energy radiation, show a high resolution, allow smooth development, lend themselves to micropatterning, and are thus suitable as micropatterning material for VLSI fabrication. 1

  具有氧取代基的环状甲基丙烯酸酯化合物在其α-甲基基团上，由式（1）表示，其中R1是H或C1-C10烷基，可能包含卤素原子，羟基，醚键，羰基，羧基或氰基，而R2是具有环状结构的一价C3-C20有机基团。从这些环状甲基丙烯酸酯化合物制备的聚合物具有改善的透明度，特别是在准分子激光的曝光波长下，以及改善的干法蚀刻抗性。包含这些聚合物的抗蚀剂组合物对高能辐射敏感，具有高分辨率，允许平滑开发，适用于微图案制作，因此适用于VLSI制造的微图案材料。
• Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
  申请人：McDaniel C. Steven

  公开号：US20100210745A1

  公开（公告）日：2010-08-19

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peotide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文公开了一些聚合材料，如涂层、塑料、层压板、复合材料、弹性体、粘合剂或密封剂；一种表面处理，如纺织品涂层或蜡；一种填料，用于这样的聚合材料或表面处理，其中包括一种酶，如酯酶（例如，脂肪水解酶，硫酸酯水解酶，有机磷化合物降解酶），降解细胞壁和/或细胞膜成分的酶（例如，溶菌酶，裂解转糖基酶），生物杀菌或生物静态肽，以及/或肽酶。本文还公开了通过将酶纳入可通过脂肪水解酶、水解酶和/或脲酶的活性交联材料中来改变材料性能，如使用寿命、柔韧性或刚度的方法。
• a-(UNSATURATED ALKOXYALKYL) ACRYLATE COMPOSITION AND PROCESS FOR PRODUCTION THEREOF
  申请人：Saito Makoto

  公开号：US20120016095A1

  公开（公告）日：2012-01-19

  An α-(unsaturated alkoxyalkyl)acrylate composition is provided which enables an α-(unsaturated alkoxyalkyl)acrylate product to be stored at a high purity for an extended period of time and can fully suppress problems such as coloration and gelation from arising during polymerization, and also a method of preparing α-(unsaturated alkoxyalkyl)acrylate compositions for enabling to obtain industrially α-(unsaturated alkoxyalkyl)acrylates safely in a high purity is also provided. The composition includes an α-(unsaturated alkoxyalkyl)acrylate of a specific structure and an antioxidant, the content of the antioxidant being from 0.03 to 0.5 wt % per 100 wt % of the α-(unsaturated alkoxyalkyl)acrylate.

  提供了一种α-(不饱和烯氧烷基)丙烯酸酯组合物，使α-(不饱和烯氧烷基)丙烯酸酯产品可以在长时间内高纯度地储存，并且可以完全抑制聚合过程中出现的着色和凝胶等问题，同时还提供了一种制备α-(不饱和烯氧烷基)丙烯酸酯组合物的方法，以安全地获得高纯度的工业用α-(不饱和烯氧烷基)丙烯酸酯。该组合物包括具有特定结构的α-(不饱和烯氧烷基)丙烯酸酯和抗氧剂，抗氧剂的含量为α-(不饱和烯氧烷基)丙烯酸酯的100 wt％中的0.03至0.5 wt％。
• Anti-fouling Paints and Coatings
  申请人：Reactive Surfaces LTD

  公开号：US20150191607A1

  公开（公告）日：2015-07-09

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peptide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文披露了聚合材料，例如涂层、塑料、层压材料、复合材料、弹性体、粘合剂或密封剂；表面处理，例如纺织品整理或蜡；填充剂，用于这种聚合材料或表面处理，包括酯酶（例如脂肪水解酶、硫酸酯水解酶、有机磷化合物降解酶）的酶，降解细胞壁和/或细胞膜成分的酶（例如溶菌酶、裂解转葡糖苷酶），生物杀菌或生物稳定肽，和/或肽酶。本文还披露了通过将酶并入能够通过脂肪水解酶、水解酶和/或脲酶的活性进行化学交联的材料中，改变材料性能（例如使用寿命、柔韧性或刚度）的方法。