5-(4'-carboxylphenoxy)isophthalic acid | 60893-67-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(4'-carboxylphenoxy)isophthalic acid
• 英文别名: 5-(4-carboxyphenoxy)isophthalic acid；5-(4′-carboxylphenoxy)isophthalic acid；5-(4-Carboxyphenoxy)isophthalic acid；5-(4-carboxyphenoxy)benzene-1,3-dicarboxylic acid
• CAS: 60893-67-6
• 化学式: C₁₅H₁₀O₇
• 分子量: 302.24
• InChiKey: RMILQYNYQUIGTM-UHFFFAOYSA-N

物化性质

• 沸点：
  595.4±50.0 °C(Predicted)
• 密度：
  1.529±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  121
• 氢给体数：
  3
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  samarium(III) nitrate hexahydrate 、 5-(4'-carboxylphenoxy)isophthalic acid 在 formic acid 作用下， 以 水 为溶剂， 以87%的产率得到[Sm(5-(4-carboxyphenoxy)isophthalic acid(-3H))(H2O)2](n)*H2O
  参考文献：
  名称：

  Syntheses, structures and luminescent properties of a series of 3D lanthanide coordination polymers with tripodal semirigid ligand

  摘要：

  Reactions of the tripodal bridging ligand 5-(4-carboxy-phenoxy)-isophthalic acid (abbreviated as H(3)cpia) with lanthanide salts lead to the formation of a family of different coordination polymers, that is, [Ln(cpia)(H2O)(2)]n, center dot nH(2)O (Ln=Ce (1), Pr (2), Nd (3), Sm (4), Eu (5), Gd (6), Dy (7), Er (8), Tm (9)and Y(10)) in the presence of formic acid or diethylamine, which are characterized by elemental analysis, IR spectrum, thermogravimetric analysis (TGA), XRPD spectrum and single-crystal X-ray diffraction. Compounds 1-10 are isostructural and exhibit three-dimensional microporous frameworks. Furthermore, the photoluminescent properties of 4, 5 and 7 have been studied in detail. (C) 2010 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2010.11.012
• 作为产物：
  描述：

  5-羟基间苯二甲酸二乙酯 在 盐酸 、 potassium carbonate 、 sodium hydroxide 作用下， 以 乙醇 、 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 生成 5-(4'-carboxylphenoxy)isophthalic acid
  参考文献：
  名称：

  Four novel coordination polymers of transition metals built using a semi rigid oxygen donor ligand: Crystal structures, novel topology and emission studies

  摘要：

  Four new coordination polymers namely, [Cd-3(L-1)(2)(DMA)(4)](n) (1), [Mn(HL1)(H2O)(3)](n) (2), [Mn(H2L2)](n) (3) and {[Co-2(HL2)(L-2)]center dot(Et4N)center dot(1.5H(2)O)}(n) (4) have been synthesized with semi-rigid ether bridged tricarboxylic acid ligands H3L1 and H3L2 [H3L1 = 5-(4-carboxy-phenoxy)-isophthalic acid and H3L2 = 5-(2-carboxyphenoxy)-isophthalic acid] with various transition metal ions using hydro(solvo)thermal techniques. All the coordination polymers have been structurally characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and X-ray single crystallography. Single crystal X-ray studies show that these coordination polymers contain homometallic clusters varying from dimeric to trimeric units except 2 which is a linear monomeric. On reacting para-isomer of the ligand H3L1 with metal ions, 2D and 3D supramolecular structures have been obtained while with the ortho-isomer H3L2 dimeric 2D and 3D framework were obtained. Topological analysis reveals that 1 and 3 are binodal (3,6)-connected kgd net, 2 is also a binodal (3,3)-connected honey-comb type hcb net, while 4 shows unprecedented (3,3,6)-connected pkb5 topological trinodal-network. Interestingly, 3 and 4 exhibits unusual coordination modes involving one of carbonyl 0 atom of an acid functional group. Moreover, in 4 ethereal 0 atom is also coordinated to one of the metal center. All complexes show high thermal stability, thus losing coordinated and lattice solvent molecules in the range, similar to 100-200 degrees C. Upon excitation at 325 nm, compounds 1-4 exhibit solid-state luminescences at room temperature. (C) 2012 Elsevier Ltd. All rights reserved,

  DOI：

  10.1016/j.poly.2012.10.045

文献信息

• Series of highly stable Cd(<scp>ii</scp>)-based MOFs as sensitive and selective sensors for detection of nitrofuran antibiotic
  作者：Shanhe Zhou、Lu Lu、Dong Liu、Jun Wang、Hiroshi Sakiyama、Mohd. Muddassir、Alireza Nezamzadeh-Ejhieh、Jianqiang Liu

  DOI：10.1039/d1ce01264a

  日期：——

  The oxygen atom of the MOF ether-bridging group acts as a Lewis base site, improving the connection and allowing the detection of 10 antibiotics through the fluorescence quenching effect.

  MOF醚桥接基团的氧原子作为一个Lewis碱位点，改善了连接并通过荧光猝灭效应实现了对10种抗生素的检测。
• Structures and photocatalytic properties of two new Zn(<scp>ii</scp>) coordination polymers based on semi-rigid V-shaped multicarboxylate ligands
  作者：Shan-He Zhou、Jun Wang、Yi-Wei Liu、Yuyu Zhong、Yan-Chun Sun、Bin Xie、Aiqing Ma、Amita Singh、Mohd. Muddassir、Abhinav Kumar

  DOI：10.1039/d0ra02222e

  日期：——

  Two new metal–organic coordination polymers (CPs), aqua-2,2′-bipyridine-5-(4′-carboxylphenoxy)isophthalatezinc(II) polymer [Zn(HL)(2,2′-bipy)(H2O)]n (1) and tris-4,4′-bipyridine-bis-5-(4′-carboxylphenoxy)isophthalatetrizinc(II) polymer [Zn3(L)2(4,4′-bipy)3]n (2) (H3L = 5-(4′-carboxylphenoxy)isophthalic acid, 4,4′-bipy = 4,4′-bipyridine and 2,2′-bipy = 2,2′-bipyridine), were obtained under hydrothermal

  两种新型金属-有机配位聚合物 (CPs)，aqua-2,2'-bipyridine-5-(4'-carboxylphenoxy)isophthalatezinc( II ) 聚合物 [Zn(HL)(2,2'-bipy)(H 2 O )] n ( 1 ) 和 tris-4,4'-bipyridine-bis-5-(4'-carboxylphenoxy)isophthalatetrizinc( II ) 聚合物 [Zn 3 (L)2(4,4'-bipy) 3 ] n ( 2 ) (H 3L = 5-(4'-羧基苯氧基)间苯二甲酸、4,4'-bipy = 4,4'-联吡啶和 2,2'-bipy = 2,2'-联吡啶)，是在水热条件下获得的，其特征是微量分析、FTIR 光谱和单晶 X 射线衍射。单晶 X 射线衍射表明，在两个 CP 中，配位网络在 Zn( II ) 中心周围表现出不同的拓扑结构和配位模式。CP
• A new mixed ligand based Cd(II) 2D coordination polymer with functional sites: Photoluminescence and photocatalytic properties
  作者：Shu-Lan Cai、Lu Lu、Wei-Ping Wu、Jun Wang、Yan-Chun Sun、Ai-Qing Ma、Amita Singh、Abhinav Kumar

  DOI：10.1016/j.ica.2018.09.066

  日期：2019.1

  5′-tetramethyl-4,4′-bipyrazole (bpz) as co-ligand afforded a new coordination polymer [Cd(L)(Hbpz)]n (1), which was characterized. Compound 1 shows 2D layer network which can work as highly sensitive sensor to detect Fe3+ by the decrease in its luminescence intensity because of the existence of active sites. The photocatalytic activity towards the degradation of methyl violet (MV) in polluted water was explored

  摘要以5-（4-羧苯氧基）间苯二甲酸（H3L）为配体，以3,3'，5,5'-四甲基-4,4'-联吡唑（bpz）为溶剂，对Cd（OAc）2·2H2O进行溶剂热反应。共配体提供了新的配位聚合物[Cd（L）（Hbpz）] n（1），进行了表征。化合物1显示2D层网络，由于存在活性位点，其发光强度降低，可以用作高灵敏度传感器来检测Fe3 +。探索了对污水中甲基紫（MV）降解的光催化活性。另外，已经使用状态密度（DOS）计算解决了1对有机染料的光分解的光催化活性。
• Three Functionalized Zinc(II)/Cobalt(II) Coordination Complexes Demonstrating Fluorescent Sensing Activities towards Fe³⁺ Ions and Photocatalytic Selectivity for Organic Dyes
  作者：Hong-Yan Lin、Jie Chi、Suang Liang、Ming Ji、Guocheng Liu

  DOI：10.1002/zaac.202000057

  日期：2020.6.30

  Three new zinc(II)/cobalt(II) coordination complexes [Zn(HBTB)(L)0.5] (1), [Zn(HCPPA)(L)] (2), and [Co(HCPPA)(L)]·2H2O (3) [H3BTB = 1,3,5‐tri(4‐carboxylphenyl)benzene, H3CPPA = 5‐(4‐carboxyl‐phenoxy)‐isophthalic acid, L = N1,N4‐bis(3‐pyridyl)naphthaldiamide] were solvothermally synthesized. The structural characterization reveals that complex 1 represents a 3D coordination framework with a binodal

  三种新的锌（II）/钴（II）配合物[Zn（HBTB）（L）0.5 ]（1），[Zn（HCPPA）（L）]（2）和[Co（HCPPA）（L）] · 2H 2 O（3）[H 3 BTB = 1,3,5-三（4-羧基苯基）苯，H 3 CPPA = 5-（4-羧基苯氧基）-间苯二甲酸，L = N 1，N 4溶剂热合成-双（3-吡啶基）萘二酰胺]。结构特征表明，复合物1代表具有3,4连接的4.10 2 } 2 4.10 5 } 2的三脚架的3D协调框架。由二维[Zn（HBTB）] n聚合双层和双齿L配体构成的拓扑。配合物2是从双核[Zn 2（HCPPA）2 ]环和[Zn 2（L）2 ]环衍生的一维金属有机链。络合物3具有基于[Co 2（HCPPA）2 ]带状链和双齿L配体的，与3,5连接的4 2 .6} 4 3 .6.8 4 .10 2 }拓扑2D分层体系结构。对于2和3，它们相邻的链或层
• Syntheses, structures and photocatalysis properties of two Cu(II)-based coordination polymers based on flexible tricarboxylate ligand
  作者：Juanjuan Zhao、Xiaoxiong Wang、Peng Dai

  DOI：10.1016/j.molstruc.2021.130220

  日期：2021.7

  performances of the two complexes were explored by the photodegradation of methylene blue (MB) dye under UV light. The chromatography-mass spectrometry (LC-MS) was selected to discuss the catalytic process, revealing the potential photodegradation mechanism of MB. Recycling experiments also indicated that the photocatalyst is reusable and stable. Two new Cu(II)-based coordination polymers (CPs), including

  通过亚甲基蓝（MB）染料在紫外光下的光降解，探索了两种配合物的光催化性能。选择色谱-质谱（LC-MS）讨论了催化过程，揭示了MB潜在的光降解机理。回收实验还表明，该光催化剂是可重复使用且稳定的。两种新的基于Cu（II）的配位聚合物（CP），包括[Cu（HL）（H 2 O）（2,2'-bipy）]（1）和[Cu（HL）（bbi）]（2） （H 3 L ＝ 5-（4′-羧基苯氧基）间苯二甲酸，bbi = 1,1'-（1,4-丁二基）双（咪唑）和2,2'-bipy = 2,2'-联吡啶），具有已成功合成和表征。1个显示了一维阶梯状链，该链通过堆积相互作用和氢键键合相互作用进一步扩展为3D超分子网络。2还具有包含[Cu（bbi）2 Cu]回路的无限链。这些聚合物的光催化性能通过亚甲基蓝（MB）染料在紫外光下的光降解来探索。2具有极好的MB降解能力（50 mL和10 mg L -1）可以在100分钟