(2'-chloro-4'-trifluoromethylphenoxy)-3,4-dinitrobenzene | 71980-08-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2'-chloro-4'-trifluoromethylphenoxy)-3,4-dinitrobenzene
• 英文别名: 3,4-dinitro-2'-chloro-4'-trifluoromethyl-diphenyl ether；1,2-dinitro-4-(2'-chloro-4'-trifluoromethyl phenoxy)-benzene；1-(2-chloro-4-trifluoromethyl-phenoxy)-3,4-dinitrobenzene；Benzene, 2-chloro-1-(3,4-dinitrophenoxy)-4-(trifluoromethyl)-；2-chloro-1-(3,4-dinitrophenoxy)-4-(trifluoromethyl)benzene
• CAS: 71980-08-0
• 化学式: C₁₃H₆ClF₃N₂O₅
• 分子量: 362.649
• InChiKey: IHEOGOJRIWLPMH-UHFFFAOYSA-N

物化性质

• 熔点：
  89-92 °C
• 沸点：
  399.8±42.0 °C(Predicted)
• 密度：
  1.582±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  (2'-chloro-4'-trifluoromethylphenoxy)-3,4-dinitrobenzene 在 吡啶 、 一水合肼 作用下， 生成 Hydrazinecarboxylic acid, 2-(5-(2-chloro-4-(trifluoromethyl)phenoxy)-2-nitrophenyl)-, butyl ester
  参考文献：
  名称：

  DE2944783

  摘要：

  公开号：
• 作为产物：
  描述：

  2-氯-1-(4-硝基苯氧基)-4-三氟甲基苯 生成 (2'-chloro-4'-trifluoromethylphenoxy)-3,4-dinitrobenzene
  参考文献：
  名称：

  YOSHIMOTO, TAKEO;IGARASHI, KEIICHI;FUJITA, TAKASHI;HARAYAMA, TAKEO, NIXON NOYAKU GAKKAJSI, 15,(1990) N, S. 341-352

  摘要：

  DOI：

文献信息

• Diphenyl ether derivatives and herbicides containing same
  申请人：Mitsui Toatsu Chemicals, Inc.

  公开号：US04515628A1

  公开（公告）日：1985-05-07

  Novel diphenyl ether hydrazine derivatives, particularly 2-nitro-5 (nucleus-substituted phenoxy) phenylhydrazine derivatives are provided. They are useful as a selective herbicide having a high herbicidal acitivity and residual efficacy.

  新型二苯醚肼衍生物，特别是2-硝基-5（核取代苯氧基）苯基肼衍生物已提供。它们作为一种具有高除草活性和残留效果的选择性除草剂是有用的。
• Novel phenoxyphenylamino acid derivatives, the production thereof,
  申请人：Ciba-Geigy Corporation

  公开号：US04649212A1

  公开（公告）日：1987-03-10

  The invention relates to novel phenoxyphenylamino acid derivatives of the formula I ##STR1## wherein X is hydrogen, chlorine, fluorine or bromine, R.sup.1 is hydrogen, nitroso, or C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.1 -C.sub.4 alkylcarbonyl or C.sub.2 -C.sub.4 alkenylcarbonyl, each of which is unsubstituted or substituted by one or more halogen atoms, Q is a straight chain or branched aliphatic radical of 1 to 5 carbon atoms ##STR2## in which A', E', G', L' and M' are hydrogen or C.sub.1 -C.sub.4 alkyl, or two adjacent substituents A', E', G', L' and M' together are also a bond between the two carbon atoms to which they are attached; A, E, G, L and M are hydrogen or one or two of A, E, G, L and M are also --OR.sup.2, --SR.sup.3, --COOR.sup.4, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkyl substituted by --OR.sup.5, --SR.sup.6 or --COOR.sup.7, where R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are hydrogen or C.sub.1 -C.sub.4 alkyl; a, b, c and d are 0 or 1; or R.sup.1 and G together are a trimethylene bridge and a, b, c and d are 0; and Z is --COO.sup..crclbar. Me.sup..sym., --COOR.sup.8, --COSR.sup.8, --CONR.sup.9 R.sup.10, --COR.sup.11 or --CN, where Me.sup..sym. is a cation, R.sup.8 is hydrogen, C.sub.1 -C.sub.8 alkyl which is unsubstituted or substituted by halogen, cyano or C.sub.1 -C.sub.4 alkoxy, or is C.sub.2 -C.sub.8 alkenyl or C.sub.3 -C.sub.8 alkynyl, R.sup.9 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.3 -C.sub.6 cycloalkyl, R.sup.10 is hydrogen, amino, hydroxyl, C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkoxy, or is C.sub.2 -C.sub.4 alkynyl, C.sub.1 -C.sub.4 alkoxy or C.sub.3 -C.sub.6 cycloalkylaminocarbonyl and R.sup.11 is hydrogen or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkoxy, with the proviso that, in compounds in which simultaneously R.sup.1 is hydrogen and a, b, c and d are O, (i) G is --OR.sup.2, -- COOR.sup.4 or C.sub.1 -C.sub.4 alkyl which is substituted by --OR.sup.5, --SR.sup.6 or --COOR.sup.7, or (ii) G and G' are both C.sub.1 -C.sub.4 alkyl and also to the preparation of these compounds. The compounds of formula I or compositions containing them may be used for controlling undesirable plant growth and for desiccating and defoliating cotton and potato plants.

  该发明涉及公式I的新型苯氧基苯胺酸衍生物，其中X为氢、氯、氟或溴，R.sup.1为氢、亚硝基或C.sub.1-C.sub.4烷基、C.sub.2-C.sub.4烯基、C.sub.1-C.sub.4烷基羰基或C.sub.2-C.sub.4烯基羰基，每个基未取代或被一个或多个卤素原子取代，Q为1至5个碳原子的直链或支链脂肪基，其中A'、E'、G'、L'和M'为氢或C.sub.1-C.sub.4烷基，或两个相邻的取代基A'、E'、G'、L'和M'也可以是它们连接的两个碳原子之间的键；A、E、G、L和M为氢或A、E、G、L和M中的一个或两个也为--OR.sup.2、--SR.sup.3、--COOR.sup.4、C.sub.1-C.sub.4烷基或被--OR.sup.5、--SR.sup.6或--COOR.sup.7取代的C.sub.1-C.sub.4烷基，其中R.sup.2、R.sup.3、R.sup.4、R.sup.5、R.sup.6和R.sup.7为氢或C.sub.1-C.sub.4烷基；a、b、c和d为0或1；或R.sup.1和G一起为三甲亚甲基桥，a、b、c和d为0；Z为--COO.sup..crclbar. Me.sup..sym.、--COOR.sup.8、--COSR.sup.8、--CONR.sup.9 R.sup.10、--COR.sup.11或--CN，其中Me.sup..sym.为阳离子，R.sup.8为氢、未取代或被卤素、氰基或C.sub.1-C.sub.4烷氧基取代的C.sub.1-C.sub.8烷基，或为C.sub.2-C.sub.8烯基或C.sub.3-C.sub.8炔基，R.sup.9为氢、C.sub.1-C.sub.4烷基或C.sub.3-C.sub.6环烷基，R.sup.10为氢、氨基、羟基、未取代或被C.sub.1-C.sub.4烷氧基取代的C.sub.1-C.sub.4烷基，或为C.sub.2-C.sub.4炔基、C.sub.1-C.sub.4烷氧基或C.sub.3-C.sub.6环烷基氨基羰基，R.sup.11为氢或未取代或被C.sub.1-C.sub.4烷氧基取代的C.sub.1-C.sub.4烷基，但在同时R.sup.1为氢且a、b、c和d为O的化合物中，(i) G为--OR.sup.2、--COOR.sup.4或被--OR.sup.5、--SR.sup.6或--COOR.sup.7取代的C.sub.1-C.sub.4烷基，或(ii) G和G'均为C.sub.1-C.sub.4烷基，以及这些化合物的制备。公式I的化合物或含有它们的组合物可用于控制不良植物生长，以及干燥和除叶棉花和马铃薯植物。
• Herbicidal N-2-(nitro-5-phenoxy-phenyl)-aminoalkylphosphonic acid and
  申请人：Ciba-Geigy Corporation

  公开号：US04618358A1

  公开（公告）日：1986-10-21

  The present invention relates to (2-nitro-5-aryloxyphenylamino)alkylphosphonic, -alkylphosphinic and -alkylphosphonous acid derivatives of the general formula I ##STR1## wherein X is halogen, CF.sub.3, NO.sub.2, CN, CONH.sub.2 or CSNH.sub.2, Y is nitrogen or --CH.dbd., R is hydrogen, C.sub.1 -C.sub.4 alkyl or aralkyl containing 1 to 4 carbon atoms in the alkyl moiety, R.sub.1 is C.sub.1 -C.sub.4 alkyl, R.sub.2 is C.sub.1 -C.sub.4 alkyl, phenyl or --PO(OR.sub.6).sub.2, R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.4 is hydrogen, C.sub.1 -C.sub.4 alkyl or a cation, R.sub.5 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, hydroxyl or an --O-cation group, R.sub.6 is hydrogen or C.sub.1 -C.sub.4 alkyl, m is a value from 0 to 3, n is 0 or 1, p is a value from 0 to 3, and q is 0 or 1, with the proviso that R.sub.1 and R.sub.3 taken together may also be an unsubstituted or substituted C.sub.1 -C.sub.3 alkylene chain and at least one of the symbols n, p and q is a value different from 0. These compounds have useful herbicidal properties.

  本发明涉及通式I的(2-硝基-5-芳氧基苯基氨基)烷基膦酸、烷基膦酸和烷基膦酸衍生物，其中X为卤素、CF.sub.3、NO.sub.2、CN、CONH.sub.2或CSNH.sub.2，Y为氮或--CH.dbd.，R为氢、含有1至4个碳原子的C.sub.1-C.sub.4烷基或芳基烷基，R.sub.1为C.sub.1-C.sub.4烷基，R.sub.2为C.sub.1-C.sub.4烷基、苯基或--PO(OR.sub.6).sub.2，R.sub.3为氢或C.sub.1-C.sub.4烷基，R.sub.4为氢、C.sub.1-C.sub.4烷基或阳离子，R.sub.5为氢、C.sub.1-C.sub.4烷基、C.sub.1-C.sub.4卤代烷基、C.sub.1-C.sub.4烷氧基、羟基或--O-阳离子基团，R.sub.6为氢或C.sub.1-C.sub.4烷基，m为0至3的值，n为0或1，p为0至3的值，q为0或1，但R.sub.1和R.sub.3结合在一起也可以是未取代或取代的C.sub.1-C.sub.3烷基链，且n、p和q中至少一个符号的值不为0。这些化合物具有有用的除草特性。
• Diaryl ethers
  申请人：Hoffmann-La Roche Inc.

  公开号：US04792616A1

  公开（公告）日：1988-12-20

  Novel diaryl ethers of the formula ##STR1## wherein A is CR.sup.3 or N and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, n and R.sup.6 are as defined hereinafter, processes for their preparation, herbicidal compositions which contain these compounds as the active ingredient as well as the use of these compounds or compositions for the control of weeds is disclosed.

  公开了式子##STR1##中A为CR.sup.3或N，R.sup.1、R.sup.2、R.sup.3、R.sup.4、R.sup.5、n和R.sup.6如下所定义的新型二芳醚，以及它们的制备方法、含有这些化合物作为活性成分的除草剂组合物，以及利用这些化合物或组合物控制杂草的用途。
• Phenoxy- and pyridyloxy-phenoxyalkyl phosphinates and related sulfur
  申请人：Zoecon Corporation

  公开号：US04456464A1

  公开（公告）日：1984-06-26

  Novel phenoxyphenoxyalkyl-, phenoxyphenylthioalkyl- or phenoxyphenylsulfonylalkyl-substituted phosphinates and phosphonates, related compounds, synthesis thereof, intermediates therefor, and the use of said novel compounds for the control of weeds.

  新型苯氧苯氧烷基、苯氧苯基硫烷基或苯氧苯基磺酰基烷基取代的膦酸酯和膦酸盐，相关化合物，其合成，中间体以及利用这些新型化合物控制杂草。