3-(Diethylthiocarbamoylthio)-propionsaeure | 7629-43-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-(Diethylthiocarbamoylthio)-propionsaeure
• 英文别名: 3-(diethylcarbamothioylthio)propanoic acid；3-diethylthiocarbamoylsulfanyl-propionic acid；3-Diaethylthiocarbamoylmercapto-propionsaeure；β-(N,N-Diethyl-thiocarbamoylthio)-propionsaeure；3-(Diethylcarbamothioylsulfanyl)propanoic acid
• CAS: 7629-43-8
• 化学式: C₈H₁₅NO₂S₂
• 分子量: 221.345
• InChiKey: RPGCIKCIZAEEPV-UHFFFAOYSA-N

物化性质

• 熔点：
  91.5 °C
• 沸点：
  345.4±44.0 °C(Predicted)
• 密度：
  1.220±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  97.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-(Diethylthiocarbamoylthio)-propionsaeure 在 盐酸 、 sodium nitrite 作用下， 以 溶剂黄146 为溶剂， 反应 1.0h， 以65%的产率得到3-(Diethylcarbamoylthio)-propionsaeure
  参考文献：
  名称：

  1,3-噻嗪的研究，第 33 部分 1) 硫代氨基甲酸酯的氧化，第 7 部分 2)。亚硝酸和硝酸氧化脱硫二硫代氨基甲酸乙酯

  摘要：

  二硫代氨基甲酸酯，特别是 2-thioxo-tetrahydro-4H-1,3-thiazin-4-ones 1，被亚硝酸转化为硫醇氨基甲酸酯，尤其是 5,6-dihydro-2H-1,3-thiazine-2和硝酸. 4 (3H)-dione 2 转移。随着浓度。此外，苯基取代基在硝酸中硝化。

  DOI：

  10.1002/ardp.19863190608
• 作为产物：
  描述：

  酯-105 在 盐酸 作用下， 生成 3-(Diethylthiocarbamoylthio)-propionsaeure
  参考文献：
  名称：

  Seyden-Penne, Annales de Chimie (Cachan, France), 1958, vol. <13>3, p. 599,631

  摘要：

  DOI：

文献信息

• Synthesis of a new series of dithiocarbamate-linked peptidomimetics and their application in Ugi reactions
  作者：Azim Ziyaei Halimehjani、Mohammad Amin Ranjbari、Hamed Pasha Zanussi

  DOI：10.1039/c3ra44552f

  日期：——

  Novel peptidomimetics containing dithiocarbamate groups were synthesized via the Ugi reaction. Also, dithiocarbamates of natural amino acids were prepared and were used successfully in Ugi reactions to prepare novel peptidomimetics bearing amino acid and dithiocarbamate groups in a single structure. In addition the prepared dithiocarbamates based on amino acids are converted to the corresponding amides

  通过Ugi反应合成了含有二硫代氨基甲酸酯基团的新型拟肽。此外，还制备了天然氨基酸的二硫代氨基甲酸酯，并将其成功用于Ugi反应中，以制备具有单一结构的氨基酸和二硫代氨基甲酸酯基团的新型拟肽。另外，将基于氨基酸制备的二硫代氨基甲酸酯转化为相应的酰胺。
• A novel Y-shaped photoiniferter used for the construction of polydimethylsiloxane surfaces with antibacterial and antifouling properties
  作者：Wei Sun、Jingrui Liu、Qing Hao、Kunyan Lu、Zhaoqiang Wu、Hong Chen

  DOI：10.1039/d1tb01968f

  日期：——

  Dual-functional polydimethylsiloxane (PDMS) surfaces with antibacterial and antifouling properties were conveniently developed via a novel Y-shaped photoiniferter (Y-iniferter).

  通过一种新型的Y形光引发剂（Y-iniferter），方便地开发出具有抗菌和抗污染性能的双功能聚二甲基硅氧烷（PDMS）表面。
• ELECTROPHOTOGRAPHIC PHOTORECEPTOR
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0581956A1

  公开（公告）日：1994-02-09

  An electrophotographic photoreceptor improved in electrostatic characteristics and image pickup and particularly excellent in the reproduction of highly precise images by the use of a liquid developer and in the image pickup according to the scanning exposure system using low-output laser beams. The photoreceptor contains a binder resin comprising at least one resin (A) containing at least 30 wt% of a polymer component of general formula (I) and 0.5 to 15 wt% of a specified polar polymer component and having a weight average molecular weight of 1x10³ to 2x10⁴ and at least one resin (B) comprising an A-B block copolymer composed of block A containing a specified polar polymer component and block B containing a polymer component of general formula (I) and having a weight-average molecular weight of 3x10⁴ to 1x10⁶. In formula (I) a¹ and a² represent each hydrogen, halogen, cyano, hydrocarbyl, or COOR⁴ optionally bonded via hydrocarbyl (wherein R⁴ represents hydrocarbyl); and R³ represents hydrocarbyl.

  一种电子照相感光元件，在静电特性和图像拾取方面均有改进，尤其是在通过使用液体显影剂复制高精度图像和根据使用低输出激光束的扫描曝光系统进行图像拾取方面表现出色。感光元件含有粘合剂树脂，粘合剂树脂包括至少一种树脂 (A)，该树脂含有至少 30 wt% 的通式 (I) 的聚合物成分和 0.5 至 15 wt% 的指定极性聚合物组分，且其重量平均分子量为 1x10³ 至 2x10⁴；以及至少一种树脂 (B)，该树脂包含由含有指定极性聚合物组分的嵌段 A 和含有通式 (I) 聚合物组分的嵌段 B 组成的 A-B 嵌段共聚物，且其重量平均分子量为 3x10⁴ 至 1x10⁶。在式 (I) 中，a¹ 和 a² 分别代表氢、卤素、氰基、烃基或通过烃基任选键合的 COOR⁴（其中 R⁴ 代表烃基）；R³ 代表烃基。
• Aspherical-polymer fine particles and production method thereof, and method for producing lithographic printing plate, ink composition and electrophoretic particle composition
  申请人：Fuji Photo Film Co., Ltd.

  公开号：EP1728805A1

  公开（公告）日：2006-12-06

  Aspherical-polymer fine particles are resin particles synthesized by polymerizing radically radical polymerizable monomers in a non-aqueous solvent in the presence of a resin for dispersal stability, wherein the aspherical-polymer fine particles have a sphericity of 0.95 or less.

  非球面聚合物微粒是通过在非水溶剂中聚合可自由基聚合的单体而合成的树脂微粒，其中树脂具有分散稳定性，而非球面聚合物微粒的球度为 0.95 或更小。
• Fluorescent polymer fine particle
  申请人：Fujifilm Corporation

  公开号：EP1783168A2

  公开（公告）日：2007-05-09

  The invention provides a fluorescent polymer fine particle having at least; a polymer particle having a core-shell configuration having a hydrophobic core and a hydrophilic shell; and a fluorescent lanthanoid dye that is integrated with the polymer particle and has a fluorescent lanthanoid cation, wherein a hydrophilic polymer which forms the hydrophilic shell has a polymerizable unit and at least one hydrophilic unit selected from the group consisting of a hydrophilic (meth)acrylamide unit and a hydrophilic vinyl amine unit. The invention further provides a method for forming the fluorescent polymer fine particle having at least dispersing and polymerizing a hydrophobic radical polymerizable monomer in an aqueous solvent in the presence of a radical generator and the presence of a components for forming a hydrophilic polymer which forms the hydrophilic shell; and introducing the fluorescent lanthanoid dye with the polymer particle.

  本发明提供了一种荧光聚合物微粒，该微粒至少具有；具有芯壳构型的聚合物微粒，该聚合物微粒具有疏水芯和亲水壳；以及与聚合物微粒结合并具有荧光镧系阳离子的荧光镧系染料，其中形成亲水壳的亲水聚合物具有可聚合单元和至少一个亲水单元，该亲水单元选自由亲水(甲基)丙烯酰胺单元和亲水乙烯基胺单元组成的组。本发明进一步提供了一种形成荧光聚合物微粒的方法，该方法至少在水性溶剂中，在自由基发生器和形成亲水聚合物的组分存在的情况下，分散和聚合疏水自由基可聚合单体，形成亲水外壳；并将荧光镧系染料引入聚合物微粒。