1,4-bis((8’-bromooctyl)oxy)benzene | 102702-38-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,4-bis((8’-bromooctyl)oxy)benzene
• 英文别名: 1,4-bis-(8-bromo-octyloxy)-benzene；1,4-Bis-(8-brom-octyloxy)-benzol；Bis-O-(8-brom-octyl)-hydrochinon；1,4-Bis(8-bromooctoxy)benzene
• CAS: 102702-38-5
• 化学式: C₂₂H₃₆Br₂O₂
• 分子量: 492.335
• InChiKey: YDDOSKLZPLJUBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  26
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  吡啶 、 1,4-bis((8’-bromooctyl)oxy)benzene 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Multiresponsive Supramolecular Gel Based on Pillararene-Containing Polymers

  摘要：

  A multiresponsive supramolecular gel was constructed based on a bis(pyridinium) dication guest and a copolymer with pillararenes as the pendant groups, which was synthesized by free radical copolymerization of methacrylatefunctionalized pillararenes and methyl methacrylate. The mechanism of gel formation was explored by the intensive study. Upon addition of competitive host or guest molecules, pillararene-based gel could be transferred into sol due to the competition of host guest complexation. Surprisingly, the ordered stacking of pillararenes was indispensable to- obtain the supramolecular gel, which endowed the system with response to temperature change.

  DOI：

  10.1021/acs.macromol.6b00270
• 作为产物：
  描述：

  1,8-二溴辛烷 、 对苯二酚 在 potassium carbonate 作用下， 以 乙腈 为溶剂， 反应 25.0h， 以81%的产率得到1,4-bis((8’-bromooctyl)oxy)benzene
  参考文献：
  名称：

  Silica bound co-pillar[4+1]arene as a novel supramolecular stationary phase

  摘要：

  第一次合成了一种新型的共柱[4+1]芳烃，使用微波辐射，并将其用作色谱固定相。

  DOI：

  10.1039/c9cc09656f

文献信息

• Multistimuli responsive supramolecular polymer networks via host-guest complexation of pillararene-containing polymers and sulfonium salts
  作者：Feihong Lu、Yi Chen、Boqiao Fu、Shigui Chen、Lu Wang

  DOI：10.1016/j.cclet.2022.03.103

  日期：2022.12

  supramolecular polymer network has been constructed based on the host-guest interactions between the copolymer poly-P[5]A with pendent pillararene units and bis(sulfonium) diction guest G2. The formation mechanism of the supramolecular polymer network has been explored by the intensive study. With the addition of the competitive molecules and heating, the supramolecular polymer network could be dissociated

  基于具有悬垂柱芳烃单元的共聚物poly-P[5]A与双(锍)双键客体G2之间的主客体相互作用，构建了一种刺激响应的超分子聚合物网络。通过深入研究探索了超分子聚合物网络的形成机制。随着竞争分子的加入和加热，超分子聚合物网络可以解离并导致核磁共振光谱和粘度特性的明显变化。
• Luettringhaus et al., Justus Liebigs Annalen der Chemie, 1958, vol. 613, p. 185,194
  作者：Luettringhaus et al.

  DOI：——

  日期：——
• Many-Membered Ring Compounds by Direct Synthesis from Two ι,ι'-Bifunctional Molecules
  作者：Roger Adams、L. N. Whitehill

  DOI：10.1021/ja01853a013

  日期：1941.8
• US7411019B1
  申请人：——

  公开号：US7411019B1

  公开（公告）日：2008-08-12