N-vinyl lauramide | 122908-50-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: N-vinyl lauramide
• 英文别名: N-ethenyldodecanamide
• CAS: 122908-50-3
• 化学式: C₁₄H₂₇NO
• 分子量: 225.374
• InChiKey: UNVMOPYJBABOAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-vinyl lauramide 、 苯硫酚 在 tris(bipyridine)ruthenium(II) dichloride hexahydrate 作用下， 以 乙腈 为溶剂， 反应 18.0h， 以75%的产率得到
  参考文献：
  名称：

  Visible light photoredox-catalyzed hydrothiolation of enamides and enecarbamates

  摘要：

  An efficient visible light photoredox-catalyzed, Markovnikov selective, hydrothiolation reaction of enamides and enecarbamates is presented. This protocol is mild and operationally simple. This process provides access to N,S-acetal products from available thiols and a variety of enamides and enecarbamates. (C) 2020 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2020.152201

文献信息

• RUBBER COMPOSITION AND PNEUMATIC TIRE MADE BY USING THE SAME
  申请人：Bridgestone Corporation

  公开号：EP0857752A2

  公开（公告）日：1998-08-12

  The present invention provides a rubber composition comprising natural rubber and/or diene synthetic rubbers, silica in an amount of 10 to 85 parts by weight per 100 parts by weight of the rubber, a specific silane coupling agent, i.e., a bis(alkoxysilylalkyl) polysulfide having a polysulfide structure in which the distribution of sulfur is specified, in an amount of 1 to 20% by weight of the amount of silica, and a specific silica dispersion improver in an amount of 1 to 15% by weight of the amount of silica, and provides a pneumatic tire manufactured by using the rubber composition. The pneumatic tire has excellent low heat buildup property and abrasion resistance.

  本发明提供了一种橡胶组合物，该组合物包含天然橡胶和/或二烯烃合成橡胶、白炭黑（以每 100 份橡胶的重量计，白炭黑的用量为 10 至 85 份）、特定硅烷偶联剂（即具有多硫化物结构的双(烷氧基硅烷基)多硫化物，其中硫的分布按重量计为 1 至 20%）、双（烷氧基硅烷基）多硫化物，其具有指定硫分布的多硫化物结构，用量为白炭黑用量的 1 至 20%（按重量计），以及特定的白炭黑分散改进剂，用量为白炭黑用量的 1 至 15%（按重量计），并提供使用该橡胶组合物制造的充气轮胎。该充气轮胎具有优异的低热积聚性能和耐磨性。
• BLOCK COPOLYMER AND SURFACE TREATMENT AGENT USING SAME
  申请人：Tosoh Corporation

  公开号：EP3495400A1

  公开（公告）日：2019-06-12

  The present invention addresses the problem of providing a block copolymer which is useful as a surface treatment agent for cell culture substrates, said surface treatment agent enabling cell separation in a short period of time. The above-mentioned problem is solved by a block copolymer that comprises the following blocks (A), (B) and (C). (A) a temperature-responsive polymer block that has a lower critical solution temperature (LCST) within the range of from 0°C to 50°C with respect to water (B) a hydrophilic polymer block that does not have an LCST within the range of from 0°C to 50°C, while having an HLB value (as determined by a Griffin method) within the range of from 9 (inclusive) to 20 (exclusive) (C) a hydrophobic polymer block that does not have an LCST within the range of from 0°C to 50°C, while having an HLB value (as determined by a Griffin method) within the range of from 0 (inclusive) to 9 (exclusive)

  本发明要解决的问题是提供一种嵌段共聚物，它可用作细胞培养基质的表面处理剂，所述表面处理剂可在短时间内实现细胞分离。解决上述问题的是一种嵌段共聚物，它由以下嵌段（A）、（B）和（C）组成。(A) 具有温度响应性的聚合物嵌段，其相对于水的较低临界溶液温度（LCST）在 0°C 至 50°C 范围内 (B) 亲水性聚合物嵌段，其相对于水的较低临界溶液温度（LCST）不在 0°C 至 50°C 范围内、(C) 疏水性聚合物嵌段，其低临界溶液温度（LCST）不在 0℃至 50℃之 间，同时其 HLB 值（由格里芬方法确定）在 0（含）至 9（不含）之 间。
• Multi-component particles comprising inorganic nanoparticles distributed in an organic matrix and processes for making and using same
  申请人：SICPA HOLDING SA

  公开号：US10428186B2

  公开（公告）日：2019-10-01

  Multi-component particles comprising inorganic nanoparticles distributed in an organic matrix and processes for making and using same. A flowing aerosol is generated that includes droplets of a precursor medium dispersed in a gas phase. The precursor medium contains a liquid vehicle and at least one precursor. At least a portion of the liquid vehicle is removed from the droplets of precursor medium under conditions effective to convert the precursor to the nanoparticles or the matrix and form the multi-component particles.

  由分布在有机基质中的无机纳米粒子组成的多组分微粒，以及制造和使用该微粒的工艺。生成的流动气溶胶包括分散在气相中的前驱体介质液滴。前驱体介质包含液体载体和至少一种前驱体。在将前驱体转化为纳米颗粒或基质并形成多组分颗粒的有效条件下，从前驱体介质液滴中去除至少一部分液态载体。
• Block copolymer and surface treatment agent using same
  申请人：TOSOH CORPORATION

  公开号：US11046803B2

  公开（公告）日：2021-06-29

  The present invention addresses the problem of providing a block copolymer which is useful as a surface treatment agent for cell culture substrates, said surface treatment agent enabling cell separation in a short period of time. The above-mentioned problem is solved by a block copolymer that includes the following blocks (A), (B) and (C): (A) a temperature-responsive polymer block that has a lower critical solution temperature (LCST) within the range of from 0° C. to 50° C. with respect to water (B) a hydrophilic polymer block that does not have an LCST within the range of from 0° C. to 50° C., while having an HLB value within the range of from 9 (inclusive) to 20 (exclusive) (C) a hydrophobic polymer block that does not have an LCST within the range of from 0° C. to 50° C., while having an HLB value within the range of from 0 (inclusive) to 9 (exclusive).

  本发明要解决的问题是提供一种嵌段共聚物，它可用作细胞培养基底的表面处理剂，所述表面处理剂可在短时间内实现细胞分离。解决上述问题的嵌段共聚物包括以下嵌段 (A)、(B) 和 (C)：(A) 具有温度响应性的聚合物嵌段，其相对于水的较低临界溶液温度 (LCST) 在 0°C 至 50°C 范围内 (B) 亲水性聚合物嵌段，其相对于水的较低临界溶液温度 (LCST) 不在 0°C 至 50°C 范围内、(C) 疏水性聚合物嵌段，其 LCST 不在 0° C 至 50° C 范围内，HLB 值在 0（含）至 9（不含）范围内。
• Responsive microgel and methods related thereto
  申请人：——

  公开号：US20030152623A1

  公开（公告）日：2003-08-14

  A responsive microgel is provided which responds volumetrically and reversibly to a change in one or more aqueous conditions selected from the group consisting of (temperature, pH, and ionic conditions) comprised of an ionizable network of covalently cross-linked homopolymeric ionizable monomers wherein the ionizable network is covalently attached to an amphiphilic copolymer to form a plurality of ‘dangling chains’ and wherein the ‘dangling chains’ of amphiphilic copolymer form immobile micelle-like aggregates in aqueous solution. A responsive microgel is further provided that comprises at least one therapeutic entity and delivers a substantially linear and sustained release of the therapeutic entity under physiological conditions.

  本发明提供了一种响应型微凝胶，该微凝胶可对选自由温度、pH 值和离子条件组成的组中的一种或多种水性条件的变化作出体积上和可逆的响应、和离子条件）组成的共价交联均聚可离子化单体的可离子化网络，其中可离子化网络与两性共聚物共价连接，形成多条 "悬链"，两性共聚物的 "悬链 "在水溶液中形成不动的胶束状聚集体。还提供了一种响应性微凝胶，它包含至少一种治疗实体，并能在生理条件下提供治疗实体的线性和持续释放。