Benzenesulfonylimino-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-oxidoazanium | 164855-67-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzenesulfonylimino-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-oxidoazanium
• CAS: 164855-67-8
• 化学式: C₁₂H₁₅N₃O₇S
• 分子量: 345.333
• InChiKey: ZYBHXWLPBVQGQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  148
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  Benzenesulfonylimino-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-oxidoazanium 在 溴 、 sodium carbonate 、 乙酰氯 作用下， 以 甲醇 、 水 为溶剂， 反应 0.5h， 生成
  参考文献：
  名称：

  (?-Nitroalkyl)-ONN-azoxysulfones and some of their transformations

  摘要：

  A regioselective method for the synthesis of [(alpha-nitroalkyl)-ONN-azoxy]alkyl- and -arylsulfones by oxidative condensation of pseudonitroles with aliphatic and aromatic sulfamides under the action of dibromoisocyanurate (DBI) was proposed. The behavior of the azoxysulfones obtained toward acids and bases as well as futher transformations of the products of acid hydrolysis into salts and halo-derivatives of nitroalkylazoxysulfones were investigated.

  DOI：

  10.1007/bf00698245
• 作为产物：
  描述：

  苯磺酰胺 、 1,3-二噁烷,2,2-二甲基-5-硝基-5-亚硝基- 在 降糖灵 作用下， 以 二氯甲烷 为溶剂， 以100%的产率得到Benzenesulfonylimino-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-oxidoazanium
  参考文献：
  名称：

  (?-Nitroalkyl)-ONN-azoxysulfones and some of their transformations

  摘要：

  A regioselective method for the synthesis of [(alpha-nitroalkyl)-ONN-azoxy]alkyl- and -arylsulfones by oxidative condensation of pseudonitroles with aliphatic and aromatic sulfamides under the action of dibromoisocyanurate (DBI) was proposed. The behavior of the azoxysulfones obtained toward acids and bases as well as futher transformations of the products of acid hydrolysis into salts and halo-derivatives of nitroalkylazoxysulfones were investigated.

  DOI：

  10.1007/bf00698245

文献信息

• (?-Nitroalkyl)-ONN-azoxysulfones and some of their transformations
  作者：O. A. Luk'yanov、Yu. B. Salamonov、A. G. Bass

  DOI：10.1007/bf00698245

  日期：1994.7

  A regioselective method for the synthesis of [(alpha-nitroalkyl)-ONN-azoxy]alkyl- and -arylsulfones by oxidative condensation of pseudonitroles with aliphatic and aromatic sulfamides under the action of dibromoisocyanurate (DBI) was proposed. The behavior of the azoxysulfones obtained toward acids and bases as well as futher transformations of the products of acid hydrolysis into salts and halo-derivatives of nitroalkylazoxysulfones were investigated.