1,2-bis(2-hexynyl)-3,4,5,6-tetrapropylbenzene | 254747-38-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis(2-hexynyl)-3,4,5,6-tetrapropylbenzene
• 英文别名: 1,2-di(2-hexynyl)-3,4,5,6-tetrapropylbenzene；1,2-di-2-hexynyl-3,4,5,6-tetrapropylbenzene；1,2-bis(hex-2-ynyl)-3,4,5,6-tetrapropylbenzene
• CAS: 254747-38-1
• 化学式: C₃₀H₄₆
• 分子量: 406.695
• InChiKey: BRWZVXGZDFMGEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.3
• 重原子数：
  30
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2-bis(2-hexynyl)-3,4,5,6-tetrapropylbenzene 在 dibutylbis(cyclopentadienyl)zirconium lithium aluminium tetrahydride 、 正丁基锂 、 三溴化磷 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 2.0h， 生成 2,3-bis(2-hexynyl)-9,10-dihydro-1,4,5,6,7,8-hexapropylanthracene
  参考文献：
  名称：

  同系化合成高度烷基取代的并四苯和并五苯衍生物的简单方法

  摘要：

  DOI：

  10.1021/ja003130g
• 作为产物：
  描述：

  1,2-bis(hydroxymethyl)-3,4,5,6-tetrapropylbenzene 在 正丁基锂 、 三溴化磷 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 2.0h， 生成 1,2-bis(2-hexynyl)-3,4,5,6-tetrapropylbenzene
  参考文献：
  名称：

  同系化合成高度烷基取代的并四苯和并五苯衍生物的简单方法

  摘要：

  DOI：

  10.1021/ja003130g

文献信息

• Functional thin film
  申请人：Takahashi Tamotsu

  公开号：US20050240061A1

  公开（公告）日：2005-10-27

  The present invention provides organic electroluminescent elements selected from polyacene derivatives represented by general formula (I) below: [wherein, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , A 1 and A 2 , which are the same or different, each represents hydrogen atom, a hydrocarbon group, etc., and n denotes an integer of not less than 1]. The organic electroluminescent elements of the present invention can provide materials for organic electroluminescent elements and organic electroluminescent elements, which are excellent in stability, durability, luminance and luminance efficiency.

  本发明提供了选择自下述一般式（I）所代表的聚芳烃衍生物的有机电致发光元件：[其中，R1、R2、R3、R4、R5、R6、R7、R8、R9、R10、A1和A2，它们相同或不同，分别代表氢原子、烃基等，n表示不小于1的整数]。本发明的有机电致发光元件可以提供用于有机电致发光元件和有机电致发光元件的材料，这些元件在稳定性、耐久性、亮度和发光效率方面都表现出优异的特性。
• Unusual Conformational Isomer of 9,10-Dihydro-1,2,3,4,5,6,7,8-octapropylanthracene in Solid State
  作者：Masanori Kitamura、Guohua Gao、Kiyohiko Nakajima、Tamotsu Takahashi

  DOI：10.1246/cl.2002.1076

  日期：2002.11

  The unusual conformational isomer 1b(2) of 9,10-dihydro-1,2,3,4,5,6,7,8-octapropylanthracene with three continuous propyl groups up was selectively prepared.

  选择性地制备出了带有三个连续丙基的 9,10- 二氢-1,2,3,4,5,6,7,8-辛基蒽的不寻常构象异构体 1b(2)。
• Polyacene derivatives and production thereof
  申请人：——

  公开号：US20030116755A1

  公开（公告）日：2003-06-26

  The present invention relates to polyacene derivatives represented by general formula (I) below: 1 (wherein R 1 to R 10 , etc. each represents hydrogen atom, hydrocarbon group, or an alkoxy group; A 1 and A 2 are hydrogen atom, a halogen atom, a hydrocarbon group, an alkoxy group, cyano group, etc.; n is an integer of not less than 1; R 6 and R 7 may be linked to each other to form a ring); and a process for preparing the polyacene derivatives from polyhydro compounds as well as electrically conductive materials comprising the polyacene derivatives. According to the process for preparing the polyacene derivatives of the present invention, optional substituents can be introduced into any carbon atoms of the polyacene, and the number of aromatic rings can be increased.

  本发明涉及由下列通式(I)所表示的聚芴衍生物：1（其中R1至R10等分别表示氢原子、烃基或烷氧基；A1和A2表示氢原子、卤素原子、烃基、烷氧基、氰基等；n是不小于1的整数；R6和R7可以连接在一起形成环）以及从聚氢化合物制备聚芴衍生物的方法，以及包含聚芴衍生物的电导材料。根据本发明制备聚芴衍生物的方法，可以在聚芴的任何碳原子上引入可选的取代基，并且可以增加芳香环的数量。
• Zirconium-Mediated Coupling Reaction for Synthesis of Substituted Thiophene-Fused Acenes
  作者：Yang Ni、Kiyohiko Nakajima、Ken-ichiro Kanno、Tamotsu Takahashi

  DOI：10.1021/ol900903w

  日期：2009.8.20

  A novel zirconium-mediated synthesis of substituted thiophene-fused acenes is described. A variety of substituents, such as alkyl, aryl, silyl, iodo, and alkynyl groups, could be introduced to the acene skeleton by this method. Moreover, the double coupling with tetraiodothiophene gave the corresponding dianthrathiophene.
• Preparation and characterization of 1,1′-diphosphaferrocenes with linearly fused six-membered carbocycles
  作者：Masamichi Ogasawara、Takeshi Sakamoto、Kiyohiko Nakajima、Tamotsu Takahashi

  DOI：10.1016/j.jorganchem.2006.08.073

  日期：2007.1

  Zirconacyclopentadiene-mediated homologation method was applied to preparation of a couple of 1,1'-diphosphaferrocene derivatives with linearly fused six-membered carbocycles. The solid-state structure of bis(hexapropyldihydro-iso-naphthophospholyl)iron(II) complex (1) was studied by X-ray single-crystal structure determination. (c) 2006 Elsevier B.V. All rights reserved.