1,2-bis(hydroxymethyl)-3,4,5,6-tetrapropylbenzene | 323584-08-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis(hydroxymethyl)-3,4,5,6-tetrapropylbenzene
• 英文别名: [2-(hydroxymethyl)-3,4,5,6-tetrapropylphenyl]methanol
• CAS: 323584-08-3
• 化学式: C₂₀H₃₄O₂
• 分子量: 306.489
• InChiKey: CGRPIPFKXTYWKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  22
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-bis(hydroxymethyl)-3,4,5,6-tetrapropylbenzene 在 正丁基锂 、 三溴化磷 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 2.0h， 生成 1,2-bis(2-hexynyl)-3,4,5,6-tetrapropylbenzene
  参考文献：
  名称：

  同系化合成高度烷基取代的并四苯和并五苯衍生物的简单方法

  摘要：

  DOI：

  10.1021/ja003130g
• 作为产物：
  描述：

  dimethyl 3,4,5,6-tetrapropylbenzene-1,2-dicarboxylate 在 lithium aluminium tetrahydride 、 硫酸 、 水 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以91%的产率得到1,2-bis(hydroxymethyl)-3,4,5,6-tetrapropylbenzene
  参考文献：
  名称：

  Functional thin film

  摘要：

  本发明提供了选择自下述一般式（I）所代表的聚芳烃衍生物的有机电致发光元件：[其中，R1、R2、R3、R4、R5、R6、R7、R8、R9、R10、A1和A2，它们相同或不同，分别代表氢原子、烃基等，n表示不小于1的整数]。本发明的有机电致发光元件可以提供用于有机电致发光元件和有机电致发光元件的材料，这些元件在稳定性、耐久性、亮度和发光效率方面都表现出优异的特性。

  公开号：

  US20050240061A1

文献信息

• Polyacene derivatives and production thereof
  申请人：——

  公开号：US20030116755A1

  公开（公告）日：2003-06-26

  The present invention relates to polyacene derivatives represented by general formula (I) below: 1 (wherein R 1 to R 10 , etc. each represents hydrogen atom, hydrocarbon group, or an alkoxy group; A 1 and A 2 are hydrogen atom, a halogen atom, a hydrocarbon group, an alkoxy group, cyano group, etc.; n is an integer of not less than 1; R 6 and R 7 may be linked to each other to form a ring); and a process for preparing the polyacene derivatives from polyhydro compounds as well as electrically conductive materials comprising the polyacene derivatives. According to the process for preparing the polyacene derivatives of the present invention, optional substituents can be introduced into any carbon atoms of the polyacene, and the number of aromatic rings can be increased.

  本发明涉及以下通式（I）所代表的聚芳烃衍生物：1（其中R1至R10等分别代表氢原子、烃基或烷氧基；A1和A2分别代表氢原子、卤素原子、烃基、烷氧基、氰基等；n为不小于1的整数；R6和R7可以连接在一起形成环）；以及从聚羟基化合物制备聚芳烃衍生物的方法，以及包括所述聚芳烃衍生物的电导材料。根据本发明的制备聚芳烃衍生物的方法，可以在聚芳烃的任何碳原子上引入可选取代基团，并且可以增加芳香环的数量。
• Functional thin film
  申请人：Takahashi Tamotsu

  公开号：US20050240061A1

  公开（公告）日：2005-10-27

  The present invention provides organic electroluminescent elements selected from polyacene derivatives represented by general formula (I) below: [wherein, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , A 1 and A 2 , which are the same or different, each represents hydrogen atom, a hydrocarbon group, etc., and n denotes an integer of not less than 1]. The organic electroluminescent elements of the present invention can provide materials for organic electroluminescent elements and organic electroluminescent elements, which are excellent in stability, durability, luminance and luminance efficiency.

  本发明提供了选择自下述一般式（I）所代表的聚芳烃衍生物的有机电致发光元件：[其中，R1、R2、R3、R4、R5、R6、R7、R8、R9、R10、A1和A2，它们相同或不同，分别代表氢原子、烃基等，n表示不小于1的整数]。本发明的有机电致发光元件可以提供用于有机电致发光元件和有机电致发光元件的材料，这些元件在稳定性、耐久性、亮度和发光效率方面都表现出优异的特性。
• POLYACENE DERIVATIVES AND PRODUCTION THEREOF
  申请人：JAPAN SCIENCE AND TECHNOLOGY CORPORATION

  公开号：EP1262469A1

  公开（公告）日：2002-12-04

  The present invention relates to polyacene derivatives represented by general formula (I) below: (wherein R1 to R10, etc. each represents hydrogen atom, hydrocarbon group, or an alkoxy group; A1 and A2 are hydrogen atom, a halogen atom, a hydrocarbon group, an alkoxy group, cyano group, etc.; n is an integer of not less than 1; R6 and R7 may be linked to each other to form a ring); and a process for preparing the polyacene derivatives from polyhydro compounds as well as electrically conductive materials comprising the polyacene derivatives. According to the process for preparing the polyacene derivatives of the present invention, optional substituents can be introduced into any carbon atoms of the polyacene, and the number of aromatic rings can be increased.

  本发明涉及如下通式(I)所代表的聚乙炔衍生物： (其中R1至R10等各自代表氢原子、烃基或烷氧基；A1和A2为氢原子、卤素原子、烃基、烷氧基、氰基等；n为不小于1的整数；R6和R7可相互连接形成环）；以及从多氢化合物制备该聚乙炔衍生物的工艺和包含该聚乙炔衍生物的导电材料。根据本发明制备聚乙炔衍生物的工艺，可在聚乙炔的任意碳原子上引入任选取代基，并可增加芳香环的数量。
• FUNCTIONAL THIN FILM
  申请人：Japan Science and Technology Agency

  公开号：EP1493796A1

  公开（公告）日：2005-01-05

  The present invention provides organic electroluminescent elements selected from polyacene derivatives represented by general formula (I) below: [wherein, R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, A1 and A2, which are the same or different, each represents hydrogen atom, a hydrocarbon group, etc., and n denotes an integer of not less than 1]. The organic electroluminescent elements of the present invention can provide materials for organic electroluminescent elements and organic electroluminescent elements, which are excellent in stability, durability, luminance and luminance efficiency.

  本发明提供的有机电致发光元件选自以下通式 (I) 所代表的聚乙炔衍生物： [其中，R1、R2、R3、R4、R5、R6、R7、R8、R9、R10、A1和A2相同或不同，各自代表氢原子、烃基等，n表示不小于1的整数]。本发明的有机电致发光元件可以提供稳定性、耐久性、亮度和发光效率都非常优异的有机电致发光元件材料和有机电致发光元件。
• Effect of Substituents at 1,4-Positions of Polycyclic Aromatic Compounds and Preparation of 2,3-Difunctionalized Pentacenes and Naphthacenes
  作者：Tamotsu Takahashi、Shi Li、Lishan Zhou、Zhiyi Song、Fengyu Bao、Ken-ichiro Kanno

  DOI：10.3987/com-07-s(u)28

  日期：——