trans-3,8-dimethyl-trans-bicyclo[4.4.0]decane | 5216-67-1

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: trans-3,8-dimethyl-trans-bicyclo[4.4.0]decane
• 英文别名: cis-3,cis-8-Dimethyl-trans-bicyclo<4.4.0>decan；cis-3,cis-8-Dimethyl-trans-bicyclo[4.4.0]decan；cis,trans,trans-Bicyclo[4.4.0]decane, 3,8-dimethyl；(2R,4aS,6S,8aR)-2,6-dimethyl-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalene
• CAS: 5216-67-1
• 化学式: C₁₂H₂₂
• 分子量: 166.307
• InChiKey: XNOHNIPVHGINQP-BKUVIOGVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  环己烷 在 bis(acetylacetonato)palladium(II) 、 三乙基铝 作用下， 以 四氯化碳 为溶剂， 反应 3.0h， 以49%的产率得到trans-3,8-dimethyl-trans-bicyclo[4.4.0]decane
  参考文献：
  名称：

  摘要：

  A catalytic system comprising an organoaluminum compound, polychloromethane, and a transition metal complex transforms cyclohexane into dimethyldecalins, cyclooctane into dimethyl- and ethylcyclohexane, and endo-tricyclo[5.2.1.0(2.6)]decane into its exo-isomer under mild conditions.

  DOI：

  10.1023/a:1014047915995

文献信息

• Transformations of Cyclohexane under the Action of in situ Generated Aluminum Halides
  作者：R. A. Sadykov、M. G. Samokhina、P. N. Petrov、E. A. Paramonov、U. M. Dzhemilev

  DOI：10.1023/b:rjac.0000044161.71250.30

  日期：2004.7

  Transformations of inert cyclohexane into dimethyldecalins under mild conditions in the presence of a simple catalytic system consisting of aluminum metal and halomethanes were studied.
• ——
  作者：R. A. Sadykov、M. G. Samokhina、U. M. Dzhemilev

  DOI：10.1023/a:1014047915995

  日期：——

  A catalytic system comprising an organoaluminum compound, polychloromethane, and a transition metal complex transforms cyclohexane into dimethyldecalins, cyclooctane into dimethyl- and ethylcyclohexane, and endo-tricyclo[5.2.1.0(2.6)]decane into its exo-isomer under mild conditions.