2-tetrahydropyranyl 6-bromohexanoate | 134509-33-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-tetrahydropyranyl 6-bromohexanoate
• 英文别名: Oxan-2-YL 6-bromohexanoate
• CAS: 134509-33-4
• 化学式: C₁₁H₁₉BrO₃
• 分子量: 279.174
• InChiKey: OKUULHCPDNUVEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-tetrahydropyranyl 6-bromohexanoate 在 氨 、 氢气 作用下， 生成 6-(4-Phenylazo-phenoxy)-hexanoic acid amide
  参考文献：
  名称：

  Intercalation and Photochemical Behavior of Azobenzene Derivatives with Layered Polymer Crystals as the Organic Host

  摘要：

  通过将含有氨基的偶氮苯衍生物插层到层状聚合物晶体聚（粘多酸）中，制备了一种光功能有机固体。有机插层和光异构化行为取决于客体的偶氮苯和氨基之间的间隔物结构。

  DOI：

  10.1246/cl.2003.712
• 作为产物：
  描述：

  3,4-二氢-2H-吡喃 、 6-溴己酸 生成 2-tetrahydropyranyl 6-bromohexanoate
  参考文献：
  名称：

  Intercalation and Photochemical Behavior of Azobenzene Derivatives with Layered Polymer Crystals as the Organic Host

  摘要：

  通过将含有氨基的偶氮苯衍生物插层到层状聚合物晶体聚（粘多酸）中，制备了一种光功能有机固体。有机插层和光异构化行为取决于客体的偶氮苯和氨基之间的间隔物结构。

  DOI：

  10.1246/cl.2003.712

文献信息

• Photorecording element and liquid crystal cell comprising the same
  申请人：Agency of Industrial Science & Technology

  公开号：US04963448A1

  公开（公告）日：1990-10-16

  A photorecording element is disclosed which consists of a transparent substrate, a molecular layer of an organic compound with an ability to change structure reversibly by virtue of light and disposed in direct contact with the transparent substrate, and a layer of liquid crystals disposed in direct contact with the molecular layer. A liquid crystal cell comprising the photorecording element is also disclosed. A modification having fine deformations on the surface of the transparent substrate and a modification having a dichroic dye contained in the layer of liquid crystals are embraced by the present invention.

  本发明公开了一种光记录元件，包括透明基板、一层有机化合物分子层，该层具有通过光可逆转地改变结构的能力，并直接与透明基板接触，以及一层液晶层，直接与分子层接触。本发明还公开了一种包括该光记录元件的液晶电池。本发明还包括在透明基板表面具有微小变形的改性和在液晶层中包含二色性染料的改性。
• Self-Assembly of Amphoteric Azopyridine Carboxylic Acids:  Organized Structures and Macroscopic Organized Morphology Influenced by Heat, pH Change, and Light
  作者：Ken'ichi Aoki、Masaru Nakagawa、Kunihiro Ichimura

  DOI：10.1021/ja001790f

  日期：2000.11.1

  In this paper, we describe the synthesis of novel amphoteric azopyridine carboxylic acids (2b, 3a, 3b, 4a, and 4b), having both a carboxyl group as a hydrogen donor and a pyridyl group as an acceptor at each molecular terminus, and their self-organization, which is markedly affected by external stimuli including heat, pH changes, and light. The amphoteric compounds form intermolecular hydrogen bonds between pyridyl and carboxyl groups in a head-to-tail manner in the solid state to give linear pseudopolymer structures, as supported by FT-IR analysis. Heating and cooling across their melting points induced thermoreversible supramolecular depolymerization to and polymerization from small molecular components of monomers and the corresponding carboxylic acid dimers. In alkaline aqueous media, these amphoteric compounds, dissolved as carboxylate anions, were gradually neutralized by atmospheric carbon dioxide, leading to their deposition as novel fibrous materials from 3b and 4b, substituted with a propyl group at the phenyl ring, and as leaflet crystals from 3a and 4a bearing no substituent. FT-IR and X-ray diffraction measurements supported the conclusion that the formation of fibrous materials from 3b and 4b arises from their intermolecular hydrogen bonding in a head-to-tail manner as well as the suppressive effect of propyl substitution on the pi-pi stacking of the molecules. UV irradiation of alkaline solutions of 4b resulted in the modification of the morphology of fibrous materials, probably because the photoisomerized Z-isomer of 4b affected the nucleation process in the fibrous formation. These results suggest that morphological properties of these macroscopic self-assemblages are tunable by appropriate choices of environmental stimuli such as heat, pH, and light.
• US4963448A
  申请人：——

  公开号：US4963448A

  公开（公告）日：1990-10-16
• Intercalation and Photochemical Behavior of Azobenzene Derivatives with Layered Polymer Crystals as the Organic Host
  作者：Shinya Oshita、Akikazu Matsumoto

  DOI：10.1246/cl.2003.712

  日期：2003.8

  A photofunctional organic solid was fabricated by the intercalation of azobenzene derivatives containing an amino group into poly(muconic acid) as the layered polymer crystals. The organic intercalation and photoisomerization behaviors depended on the structure of the spacer between the azobenzene and amino groups of the guest.

  通过将含有氨基的偶氮苯衍生物插层到层状聚合物晶体聚（粘多酸）中，制备了一种光功能有机固体。有机插层和光异构化行为取决于客体的偶氮苯和氨基之间的间隔物结构。