(+/-)-6-[4'-(1-methylheptyloxy)biphenyl-4-yloxy]hexylamine | 703404-72-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (+/-)-6-[4'-(1-methylheptyloxy)biphenyl-4-yloxy]hexylamine
• 英文别名: 6-[4-(4-Octan-2-yloxyphenyl)phenoxy]hexan-1-amine；6-[4-(4-octan-2-yloxyphenyl)phenoxy]hexan-1-amine
• CAS: 703404-72-2
• 化学式: C₂₆H₃₉NO₂
• 分子量: 397.601
• InChiKey: JEHDCGRGLXSXIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  29
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  44.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  仲辛醇 在 吡啶 、 氢氧化钾 、 一水合肼 、 potassium iodide 作用下， 以 甲醇 、 乙醇 为溶剂， 反应 172.0h， 生成 (+/-)-6-[4'-(1-methylheptyloxy)biphenyl-4-yloxy]hexylamine
  参考文献：
  名称：

  Amphotropic LC Polymers and Their Multilayer Buildup

  摘要：

  Cationic and anionic LC ionomers, which possess both thermotropic and lyotropic phases, are suitable materials to fabricate multilayers with an internal structure. The LC ionomers were synthesized using a reactive precursor polymer and used for the multilayer buildup by solution-dipping and spin-coating methods based on the electrostatic attraction between polycations and polyanions. Multilayers prepared by the spin-coating method were thicker and showed a smoother surface than the ones prepared by the solution-dipping method. The multilayers prepared by the solution-dipping method showed, on the other hand, a better internal order with respect to layering and orientation of the mesogens, as a result of the liquid crystalline phase. The LC ionomers and multilayers thereof were fully characterized by NMR, UV, IR, DSC (differential scanning calorimetry), XRR (X-ray reflectometry), SPR (surface plasmon resonance), AFM (atomic force microscopy), and polarizing microscopy analyses.

  DOI：

  10.1021/ma051131t

文献信息

• Amphotropic LC Polymers and Their Multilayer Buildup
  作者：Kyungsun Choi、Ralf Mruk、Alain Moussa、Alain M. Jonas、Rudolf Zentel

  DOI：10.1021/ma051131t

  日期：2005.11.1

  Cationic and anionic LC ionomers, which possess both thermotropic and lyotropic phases, are suitable materials to fabricate multilayers with an internal structure. The LC ionomers were synthesized using a reactive precursor polymer and used for the multilayer buildup by solution-dipping and spin-coating methods based on the electrostatic attraction between polycations and polyanions. Multilayers prepared by the spin-coating method were thicker and showed a smoother surface than the ones prepared by the solution-dipping method. The multilayers prepared by the solution-dipping method showed, on the other hand, a better internal order with respect to layering and orientation of the mesogens, as a result of the liquid crystalline phase. The LC ionomers and multilayers thereof were fully characterized by NMR, UV, IR, DSC (differential scanning calorimetry), XRR (X-ray reflectometry), SPR (surface plasmon resonance), AFM (atomic force microscopy), and polarizing microscopy analyses.