cis-1,4-dihydro-1,4-diarsinine-2,3,5,6-tetracarboxylic acid dianhydride

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: cis-1,4-dihydro-1,4-diarsinine-2,3,5,6-tetracarboxylic acid dianhydride
• 英文别名: 2,8-Dimethyl-5,11-dioxa-2,8-diarsatricyclo[7.3.0.03,7]dodeca-1(9),3(7)-diene-4,6,10,12-tetrone；2,8-dimethyl-5,11-dioxa-2,8-diarsatricyclo[7.3.0.03,7]dodeca-1(9),3(7)-diene-4,6,10,12-tetrone
• 化学式: C₁₀H₆As₂O₆
• 分子量: 371.997
• InChiKey: XLJXWUAWWVXGSY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.83
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  86.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  乙烷,三氯氟- 、 cis-1,4-dihydro-1,4-diarsinine-2,3,5,6-tetracarboxylic acid dianhydride 反应 10.0h， 以42%的产率得到3-(4-甲基苯胺基)-1-(4-甲基苯基)吡咯-2,5-二酮
  参考文献：
  名称：

  Arylaminomaleimides as a New Class of Aggregation-induced Emission-active Molecules Obtained from Organoarsenic Compounds

  摘要：

  将1,4-二氢-1,4-二砷酸四羧酸二酸酐与过量的苯胺和甲苯胺加热，分别得到3-苯基氨基美克霉素和3-对甲苯氨基-N-对甲苯美克霉素，它们显示出聚集诱导发光（AIE）特性。这些氨基美克霉素衍生物不仅是结构简单的AIE活性分子，而且在不引入额外功能单元的情况下，还表现出pH响应特性。

  DOI：

  10.1246/cl.2012.1445
• 作为产物：
  描述：

  cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(t-butoxycarbonyl)-1,4-diarsinine 在 甲酸 作用下， 反应 24.0h， 生成 cis-1,4-dihydro-1,4-diarsinine-2,3,5,6-tetracarboxylic acid dianhydride 、 cis-1,4-dihydro-1,4-diarsinine-2,3,5,6-tetracarboxylic acid dianhydride
  参考文献：
  名称：

  1,4-二氢胂四羧酸二亚胺在非酸性条件下从顺式到反式的立体异构化

  摘要：

  Stereoisomerization of cis-1,4-dihydro-1,4-dimethyl-1,4-diarsininetetracarboxylic acid diimides, which were prepared from cis-1,4-dihydro-1,4-diarsininetetracarboxylic acid dianhydride with n-dodecylamine or aniline, to trans-isomers in CDCl3 proceeded at room temperature and quantitatively by repeated concentration and dissolution process in various solvents such as CHCl3, toluene, and ethyl acetate. Two stereoisomers were isolated respectively as single crystals, of which structures were determined by X-ray crystallography.

  DOI：

  10.3987/com-17-13699

文献信息

• Arylaminomaleimides as a New Class of Aggregation-induced Emission-active Molecules Obtained from Organoarsenic Compounds
  作者：Takuji Kato、Kensuke Naka

  DOI：10.1246/cl.2012.1445

  日期：2012.11.5

  Heating 1,4-dihydro-1,4-diarsininetetracarboxylic acid dianhydride with excess amounts of aniline and toluidine provided 3-anilino-N-phenylmaleimide and 3-p-toluidino-N-p-tolylmaleimide, respectively, which showed aggregation-induced emission (AIE) properties. Not only are the present aminomaleimide derivatives simple-structured AIE-active molecules, but they also exhibit pH responsive properties without introducing additional functional units.

  将1,4-二氢-1,4-二砷酸四羧酸二酸酐与过量的苯胺和甲苯胺加热，分别得到3-苯基氨基美克霉素和3-对甲苯氨基-N-对甲苯美克霉素，它们显示出聚集诱导发光（AIE）特性。这些氨基美克霉素衍生物不仅是结构简单的AIE活性分子，而且在不引入额外功能单元的情况下，还表现出pH响应特性。
• Stereoisomerization of 1,4-Dihydroarsininetetracarboxylic Acid Diimides under Non-Acidic Condition from cis- to trans-Forms
  作者：Kensuke Naka、Takuji Kato、Koushi Abe、Makoto Ishidoshiro、Shintaro Nishiyama、Susumu Tanaka、Hiroaki Imoto、Seiji Watase、Kimihiro Matsukawa、Kazuyoshi Tanaka

  DOI：10.3987/com-17-13699

  日期：——

  Stereoisomerization of cis-1,4-dihydro-1,4-dimethyl-1,4-diarsininetetracarboxylic acid diimides, which were prepared from cis-1,4-dihydro-1,4-diarsininetetracarboxylic acid dianhydride with n-dodecylamine or aniline, to trans-isomers in CDCl3 proceeded at room temperature and quantitatively by repeated concentration and dissolution process in various solvents such as CHCl3, toluene, and ethyl acetate. Two stereoisomers were isolated respectively as single crystals, of which structures were determined by X-ray crystallography.