Valeryl-DBA | 110203-21-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯氮卓类
• 英文名称: Valeryl-DBA
• 英文别名: 1-Benzo[b][1]benzazepin-11-ylpentan-1-one；1-benzo[b][1]benzazepin-11-ylpentan-1-one
• CAS: 110203-21-9
• 化学式: C₁₉H₁₉NO
• 分子量: 277.366
• InChiKey: IQBULMRYJSJSJX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  亚氨基芪 、 戊酰氯 以 1,2-二氯乙烷 为溶剂， 生成 Valeryl-DBA
  参考文献：
  名称：

  Triplet energy transfer of the intramolecular system having benzophenone and dibenz[b,f]azepine at the chain ends: chain length dependence

  摘要：

  Intramolecular triplet-triplet energy transfer in a series of polymethylene chains having a benzophenone (BP) group as an energy donor and a dibenz[b,f]azepine (DBA) group as an energy acceptor (BP-O(CH2)nCO-DBA) has been studied by phosphorescence measurement and nanosecond laser photolysis. In a rigid solution and PMMA matrix, the quantum yield of triplet-triplet energy transfer is close to unity for the chain lengths shorter than n = 5. On the basis of the through-space mechanism of energy transfer, phosphorescence decay curves were analyzed by Dexter's equation in which the distribution of donor-acceptor distance was calculated by the conformational energy analysis. The results of the simulation were in fairly good agreement with the experimentally observed decay curves. The rate constant of triplet-triplet energy transfer is strongly dependent on the chain length, i.e., about one-tenth decrease per every methylene unit, and the rate is much smaller than that of singlet-singlet energy transfer.

  DOI：

  10.1021/j100162a009

文献信息

• Triplet energy transfer of the intramolecular system having benzophenone and dibenz[b,f]azepine at the chain ends: chain length dependence
  作者：Hideaki Katayama、Shogo Maruyama、Shinzaburo Ito、Yoshinobu Tsujii、Akira Tsuchida、Masahide Yamamoto

  DOI：10.1021/j100162a009

  日期：1991.5

  Intramolecular triplet-triplet energy transfer in a series of polymethylene chains having a benzophenone (BP) group as an energy donor and a dibenz[b,f]azepine (DBA) group as an energy acceptor (BP-O(CH2)nCO-DBA) has been studied by phosphorescence measurement and nanosecond laser photolysis. In a rigid solution and PMMA matrix, the quantum yield of triplet-triplet energy transfer is close to unity for the chain lengths shorter than n = 5. On the basis of the through-space mechanism of energy transfer, phosphorescence decay curves were analyzed by Dexter's equation in which the distribution of donor-acceptor distance was calculated by the conformational energy analysis. The results of the simulation were in fairly good agreement with the experimentally observed decay curves. The rate constant of triplet-triplet energy transfer is strongly dependent on the chain length, i.e., about one-tenth decrease per every methylene unit, and the rate is much smaller than that of singlet-singlet energy transfer.