dodecyl dichloroacetate | 83005-01-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: dodecyl dichloroacetate
• 英文别名: dodecyl 2,2-dichloroacetate
• CAS: 83005-01-0
• 化学式: C₁₄H₂₆Cl₂O₂
• 分子量: 297.265
• InChiKey: XOWWGPRKFWEEDR-UHFFFAOYSA-N

物化性质

• 沸点：
  341.3±22.0 °C(Predicted)
• 密度：
  1.038±0.06 g/cm3(Predicted)
• 保留指数：
  1884.8

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  dodecyl dichloroacetate 、 足球烯 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 甲苯 为溶剂， 反应 8.0h， 以54%的产率得到61-(dodecyloxycarbonyl)-61-chloro-1,2-methano-[60]fullerene
  参考文献：
  名称：

  Lipophilic fullerenes

  摘要：

  By reactions of dodecyl and arachidic esters of methylmalonic and dichloroacetic acids with fullerene C-60 under the conditions of Bingel-Hirsch reaction the corresponding monosubstituted methanofullerenes well soluble in organic solvents were obtained and characterized. A possible version of properties investigation of these highly lipophilic fullerenes is suggested.

  DOI：

  10.1134/s1070428015080011
• 作为产物：
  描述：

  二氯乙酰氯 、 十二烷醇 在 吡啶 作用下， 以86%的产率得到dodecyl dichloroacetate
  参考文献：
  名称：

  Lipophilic fullerenes

  摘要：

  By reactions of dodecyl and arachidic esters of methylmalonic and dichloroacetic acids with fullerene C-60 under the conditions of Bingel-Hirsch reaction the corresponding monosubstituted methanofullerenes well soluble in organic solvents were obtained and characterized. A possible version of properties investigation of these highly lipophilic fullerenes is suggested.

  DOI：

  10.1134/s1070428015080011

文献信息

• Lipophilic fullerenes
  作者：S. A. Torosyan、V. V. Mikheev、Yu. N. Biglova、M. S. Miftakhov

  DOI：10.1134/s1070428015080011

  日期：2015.8

  By reactions of dodecyl and arachidic esters of methylmalonic and dichloroacetic acids with fullerene C-60 under the conditions of Bingel-Hirsch reaction the corresponding monosubstituted methanofullerenes well soluble in organic solvents were obtained and characterized. A possible version of properties investigation of these highly lipophilic fullerenes is suggested.

表征谱图