tetrabutylammonium decanoate | 34283-64-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: tetrabutylammonium decanoate
• 英文别名: tetrabutylammonium caprate；decanoate;tetrabutylazanium
• CAS: 34283-64-2
• 化学式: C₁₀H₁₉O₂*C₁₆H₃₆N
• 分子量: 413.728
• InChiKey: XXVRKIMVRXELHH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.88
• 重原子数：
  29
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.96
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [3-chloro-4-(2-methyl-benzoyl)-phenyl]-(4-fluoro-2-methyl-phenyl)-carbamic acid 1-chloro-ethyl ester 、 tetrabutylammonium decanoate 在 propionic acid 1-[[3-chloro-4-(2-methyl-benzoyl)-phenyl]-(4-fluoro-2-methyl-phenyl)-carbamoyloxy]-ethyl ester 作用下， 生成 decanoic acid 1-[[3-chloro-4-(2-methyl-benzoyl)-phenyl]-(4-fluoro-2-methyl-phenyl)-carbamoyloxy]-ethyl ester
  参考文献：
  名称：

  Novel aminobenzophenone compounds

  摘要：

  本发明提供了一种新的化合物，其符合公式I的化合物，所述化合物在治疗炎症性疾病等方面具有有用性。

  公开号：

  US20060058380A1
• 作为产物：
  描述：

  正癸酸 、 四丁基溴化铵 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 6.0h， 生成 tetrabutylammonium decanoate
  参考文献：
  名称：

  Fatty acid-derived ionic liquids as renewable lubricant additives: Effect of chain length and unsaturation

  摘要：

  Fatty acid-derived ionic liquids (FAILs) are synthesized and then demonstrated as the environmentally-friendly additive to mineral lube base oil for enhancement of lubrication properties. Unlike most of the conventional ionic liquids, FAILS exhibited good miscibility with non-polar mineral lube base oil. The quaternary structure of tetrabutylammonium (TBA) cation, diffused positive charge on the cationic center due to +I effect of alkyl chains, and the alkyl chain of fatty acid anion collectively facilitates the miscibility of FAILS in the mineral lube base oil. Experimental results revealed that 1% FAILs could significantly reduce the friction (16-27%) and wear (9-15%) of lube base oil. The viscosity of these ionic liquids is found to be governed by alkyl chain-length and unsaturation of fatty acid anions, and it exhibited a linear correlation with the coefficient of friction. The elemental mapping of worn surfaces on aluminium disc suggested the formation of ionic liquids-derived tribochemical film, which is accounted for protection of tribo-interfaces to reduce the wear and friction. The FAILs being halogen-free, environment-friendly, having an excellent affinity towards engineering surfaces, and good miscibility with non-polar hydrocarbon lubricants, promised the immense potential for tribological applications. (C) 2019 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molliq.2019.112322

文献信息

• 一种亲水性季铵型生物相容离子液体的制备 方法及应用
  申请人：浙江大学

  公开号：CN108863816B

  公开（公告）日：2021-05-18

  本发明公开了一种亲水性季铵型生物相容离子液体的合成方法及其在生物转化过程中的应用。离子液体的特征在于由四丁基铵阳离子和长链脂肪酸根阴离子构成，其合成过程通过简单的酸碱中和反应即可完成，操作简便，收率高。所得的离子液体具有较弱的极性和极强的氢键碱性，因而对甾醇表现出优异的溶解性能，具有良好的生物相容性，对微生物细胞膜完整性几乎没有影响，且其特殊的两亲特性有助于作为共溶剂，用于分枝杆菌催化的植物甾醇侧链降解过程，促进底物和产物溶解，提高过程转化效率。
• Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C₂N₂O₂−Ligated Palladium(IV) Complexes
  作者：Joy M. Racowski、Allison R. Dick、Melanie S. Sanford

  DOI：10.1021/ja9014474

  日期：2009.8.12

  This paper describes the synthesis of a series of Pd(IV) complexes of general structure (N~C)(2)Pd(IV)(O(2)CR)(2) (N~C = a rigid cyclometalated ligand; O(2)CR = carboxylate) by reaction of (N~C)(2)Pd(II) with PhI(O(2)CR)(2). The majority of these complexes undergo clean C-O bond-forming reductive elimination, and the mechanism of this process has been investigated. A variety of experiments, including

  本文描述了一系列具有一般结构 (N~C)(2)Pd(IV)(O(2)CR)(2) 的 Pd(IV) 配合物的合成（N~C = 刚性环金属化配体；O (2)CR = 羧酸盐) 通过 (N~C)(2)Pd(II) 与 PhI(O(2)CR)(2) 的反应。这些配合物中的大多数都经历了清洁的 CO 键形成还原消除，并且已经研究了该过程的机制。各种实验，包括哈米特图、艾林分析、交叉研究以及溶剂和添加剂影响的研究，表明形成 CO 键的还原消除是通过初始羧酸盐解离然后从 5 配位阳离子 Pd( IV) 中间体。
• Hydrates of Organic Compounds. VIII. The Effect of Carboxylate Anions on the Formation of Clathrate Hydrates of Tetrabutylammonium Carboxylates
  作者：Haruo Nakayama、Shigeru Torigata

  DOI：10.1246/bcsj.57.171

  日期：1984.1

  clathrate-like hydrates. The results can be summarized as follows: (1) for 14 carboxylates the formation of a clathrate-like hydrate is newly confirmed; (2) judging from melting points and hydration numbers, the hydrates can be classified into three groups: I, II, and III; (3) the group I hydrates, formed by the carboxylates with R=H, CH3, C2H5, n-C3H7, i-C3H7, and t-C4H9, have hydration numbers around

  检查了四丁基羧酸铵 (n-C4H9)4 NOOCR（R=Hn-C10H21，包括被甲基或乙基取代的各种烷基）与水的二元混合物的固液相图，以确认形成笼状水合物。结果可概括如下： (1) 14 种羧酸盐形成了笼形水合物；(2)从熔点和水合数判断，水合物可分为I、II、III三类；(3) 由 R=H、CH3、C2H5、n-C3H7、i-C3H7 和 t-C4H9 的羧酸盐形成的 I 组水合物的水合数约为 30，是本研究中最稳定的水合物实验，除了 2-甲基丙酸酯和 2,2-二甲基丙酸酯水合物；(4) II组水合物，水合数约为 39，由 R=n-C4H9、s-C4H9、i-C4H9 和所有 C5H11 的盐形成，并且相对不稳定（mp=5–11 °C）；(5) III 组水合物，...
• COMPOSITION FOR POROUS FILM FORMATION, POROUS FILM, PROCESS FOR PRODUCING THE SAME, INTERLAYER INSULATION FILM AND SEMICONDUCTOR DEVICE
  申请人：MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.

  公开号：EP1568744A1

  公开（公告）日：2005-08-31

  A composition for film formation from which a porous film excelling in dielectric characteristics, adherence, coating film uniformity and mechanical strength and realizing reduced moisture absorption can be prepared; a porous film and a process for producing the same; and a highly reliable semiconductor device of high performance wherein the porous film is incorporated. In particular, a composition for porous film formation, obtained by adding to a siloxane polymer at least one quaternary ammonium salt represented by the general formula: [(R<1>)4N]<+>[R<2>X]<-> (1), or Hk[(R<1>)4N]m<+>Y (2) wherein X represents CO2, OSO3 or SO3; Y represents SO4, SO3, CO3, O2C-CO2, NO3 or NO2; k is 0 or 1; each of m and n is 1 or 2; when n=1, k=0 and m=1; and when n=2, either k=0 and m=2, or k=1 and m=1.

  一种可制备介电特性、附着力、涂膜均匀性和机械强度优异的多孔膜并实现降低吸湿性的成膜用组合物；一种多孔膜及其生产工艺；以及一种含有该多孔膜的高性能高可靠性半导体器件。特别是一种用于形成多孔薄膜的组合物，它是通过向硅氧烷聚合物中添加至少一种由通式表示的季铵盐而获得的：[(R)4N][RX](1)，或 Hk[(R)4N]mY (2)，其中 X 代表 CO2、OSO3 或 SO3；Y 代表 SO4、SO3、CO3、O2C-CO2、NO3 或 NO2；k 为 0 或 1；m 和 n 各为 1 或 2；当 n=1 时，k=0，m=1；当 n=2 时，或者 k=0，m=2，或者 k=1，m=1。
• Silicon-containing film-forming composition, silicon-containing film, silicon-containing film-bearing substrate, and patterning method
  申请人：Shinetsu Chemical Co., Ltd.

  公开号：EP1845132A2

  公开（公告）日：2007-10-17

  A silicon-containing film is formed from a heat curable composition comprising (A) a silicon-containing compound obtained by effecting hydrolytic condensation of a hydrolyzable silicon compound in the presence of an acid catalyst, and substantially removing the acid catalyst from the reaction mixture, (B) a hydroxide or organic acid salt of lithium, sodium, potassium, rubidium or cesium, or a sulfonium, iodonium or ammonium compound, (C) an organic acid, and (D) an organic solvent. The silicon-containing film allows an overlying photoresist film to be patterned effectively. The composition is effective in minimizing the occurrence of pattern defects after lithography and is shelf stable.

  含硅薄膜由一种热固化组合物形成，该组合物包括：(A) 一种含硅化合物，该化合物是通过在酸催化剂存在下使一种可水解的硅化合物发生水解缩合，并从反应混合物中基本除去酸催化剂而获得；(B) 锂、钠、钾、铷或铯的氢氧化物或有机酸盐，或一种锍、碘或铵化合物；(C) 一种有机酸；以及 (D) 一种有机溶剂。含硅薄膜可以有效地将上覆的光刻胶薄膜图案化。该组合物能有效地减少光刻后图案缺陷的出现，并具有货架稳定性。