(N,N,N’,N’-tetrakis(diphenylphosphinomethyl)phenyl-4,4’-diamine) | 1316861-49-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (N,N,N’,N’-tetrakis(diphenylphosphinomethyl)phenyl-4,4’-diamine)
• 英文别名: N,N,N',N'-tetrakis((diphenylphosphino)methyl)biphenyl-4,4'-diamine；Pbbaa；4-[4-[bis(diphenylphosphanylmethyl)amino]phenyl]-N,N-bis(diphenylphosphanylmethyl)aniline
• CAS: 1316861-49-0
• 化学式: C₆₄H₅₆N₂P₄
• 分子量: 977.057
• InChiKey: BDIXILXIDWIOHD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.5
• 重原子数：
  70
• 可旋转键数：
  19
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 (N,N,N’,N’-tetrakis(diphenylphosphinomethyl)phenyl-4,4’-diamine) 以 乙腈 为溶剂， 以21%的产率得到[(N,N,N',N'-tetrakis((diphenylphosphino)methyl)biphenyl-4,4'-diamine)(AuCl)4]
  参考文献：
  名称：

  Gold(I) Chloride Complexes of Polyphosphine Ligands with Electron-Rich Arene Spacer: Gold–Arene Interactions

  摘要：

  The reactions of Au(tht)Cl (tht = tetrahydrothiophene) with the electron-rich-arene-spacer-containing polyphosphine ligands N,N'-bis((diphenylphosphino)methyl)benzene-1,4-diamine (Dpba), N,N'-bis((diphenylphosphino)methyl)naphthalene-1,5-diamine (Dpna), N,N,N',N'-tetralcis((diphenylphosphino)methyl)benzene-1,4-diamine (Pbaa), N,N,N',N'-tetrakis-((diphenylphosphino)methyl)naphthalene-1,5-diamine (Pnaa), and N,N,N',N'-tetralcis((diphenylphosphino)methyl)biphenyl-4,4'-diamine (Pbbaa) lead to [Dpba(AuCl)2] (1), [Dpna(AuCl)(2)] (2), [Pnaa(AuCl)(4)] (3), [Pbbaa(AuCl)(4) (4). and [Pbaa(AuCl)(4)] (5), which are characterized by H-1 and P-31 NMR, IR, elemental analysis, and X-ray crystal structure analysis. These complexes exhibit weak Au arene interactions with the electron-rich arene spacer, while the Au arene interactions are modified by a combination of electronic and steric effects from the ligands. Different from monomeric complexes 1, 2, 3, and 4, complex 5 in the solid state exhibits a centrosymmetric trimeric unit that is constructed by intermolecular Au center dot center dot center dot Au interactions between the central molecule and the two symmetry-related terminal molecules and in which the conformation of the central molecule is different from that of the two symmetric terminal molecules. On the basis of the Kochi's geometric criteria and the crystal structural parameters relating to Au-arene interactions, the Au center dot center dot center dot C-arene contacts in 3 and 4 feature nearly eta(2)-arene interactions, while the Au center dot center dot center dot C-arene contacts in 5 can be described as eta(1)-arene interactions, and the Au center dot center dot center dot C-arene contacts in 1 and 2, are very weak due to intermolecular N-H center dot center dot center dot Cl interactions.

  DOI：

  10.1021/om201276w
• 作为产物：
  描述：

  聚合甲醛 、 二苯基膦 、 联苯胺 以 甲苯 为溶剂， 反应 12.0h， 以79%的产率得到(N,N,N’,N’-tetrakis(diphenylphosphinomethyl)phenyl-4,4’-diamine)
  参考文献：
  名称：

  新型银 (I)-P4 配位聚合物强烈吸附刚果红以产生具有增强光电流响应的复合材料

  摘要：

  四膦 (P4) 配体 dppbpda 与 Ag(I) 氧基化物的反应产生式 [(dppbpda)Ag 4 (Ox) 4 ] n (Ox=Bz ( 1 ), Sal ( 2 ), LA ( 3 )，Bz=苯甲酸盐，Sal=水杨酸盐，LA=乳酸盐)。1 – 3的固态结构由一维 (1D) 链组成，这些链由四核μ - η 2、η 2 - 连接的 Ag 4 (Ox) 4簇核和 dppbpda 桥接配体构成。化合物1 – 3以两个不同的步骤吸收刚果红，最大吸收量为 1438 ( 1 )、1417 ( 2 ) 和 1656 ( 3 ) mg/g，与 CP 中阴离子的大小成反比。这些 CP 在半导体区域 (Eg) 具有 3.05–3.15 eV 的带隙，并且在 CR 的逐步吸附过程中，所有三个都显示出增强的双峰光电流响应，最大光电流密度为 227 ( 1 )、163 ( 2 ) 和 386 ( 3 ) μA

  DOI：

  10.1002/ejic.202100228

文献信息

• Synthesis, structural characterization and luminescent properties of a series of Cu(i) complexes based on polyphosphine ligands
  作者：Ruobing Hou、Ting-Hong Huang、Xiu-Jian Wang、Xuan-Feng Jiang、Qing-Ling Ni、Liu-Cheng Gui、You-Jun Fan、Yi-Liang Tan

  DOI：10.1039/c1dt10358j

  日期：——

  A series of Cu(I) complexes with a [Cu(NN)(PP)]+ moiety, [Cu(phen)(pba)](BF4) (1a), [Cu2(phen)2(pbaa)](BF4)2 (2a), [Cu2(phen)2(pnaa)](BF4)2 (3a), [Cu2(phen)2(pbbaa)](BF4)2 (4a), [Cu(dmp)(pba)](BF4) (1b), [Cu2(dmp)2(pbaa)](BF4)2 (2b), [Cu2(dmp)2(pnaa)](BF4)2 (3b) and [Cu2(dmp)2(pbbaa)](BF4)2 (4b) (phen = 1,10-phenanthroline, dmp = 2,9-dimethyl-1,10-phenanthroline, pba = N,N-bis((diphenylphosphino)methyl)benzenamine

  一系列具有[Cu（NN）（PP）] +部分，[Cu（phen）（pba）]（BF 4）（1a），[Cu 2（phen）2（pbaa）]的Cu（I）配合物（BF 4）2（2a），[Cu 2（phen）2（pnaa）]（BF 4）2（3a），[Cu 2（phen）2（pbbaa）]（BF 4）2（4a），[ Cu（dmp）（pba）]（BF 4）（1b），[Cu 2（dmp）2（pbaa）]（BF 4）2（2b），[Cu 2（dmp）2（pnaa）]（BF 4）2（3b）和[Cu 2（dmp）2（pbbaa）]（BF 4）2（4b）（phen =1,10-菲咯啉，dmp = 2,9-二甲基-1,10-菲咯啉，pba = N，N-双（（二苯基膦基）甲基）苯胺，pbaa = N，N，N '，N'-四（（二苯基膦基）甲基）苯-1,4-二胺，pnaa = N，N，N '，N'-四（（二苯基膦基）甲基）萘-1
• New Silver(I)‐P4 Coordination Polymers Strongly Adsorb Congo Red to Yield Composites with Enhanced Photocurrent Responses
  作者：Min Zhang、Meng‐Yao Feng、Jia‐Jun Yan、Hai‐Yan Li、David James Young、Hong‐Xi Li、Zhi‐Gang Ren

  DOI：10.1002/ejic.202100228

  日期：2021.6.21

  tetraphosphine (P4) ligand dppbpda with Ag(I) oxylates yielded new coordination polymers (CPs) of formula [(dppbpda)Ag4(Ox)4]n (Ox=Bz (1), Sal (2), LA (3), Bz=benzoate, Sal=salicylate, LA=lactate). The solid-state structures of 1–3 consist of one dimensional (1D) chains constructed from tetranuclear μ-η2,η2- connected Ag4(Ox)4 cluster cores and dppbpda bridging ligands. Compounds 1–3 absorbed Congo Red in two

  四膦 (P4) 配体 dppbpda 与 Ag(I) 氧基化物的反应产生式 [(dppbpda)Ag 4 (Ox) 4 ] n (Ox=Bz ( 1 ), Sal ( 2 ), LA ( 3 )，Bz=苯甲酸盐，Sal=水杨酸盐，LA=乳酸盐)。1 – 3的固态结构由一维 (1D) 链组成，这些链由四核μ - η 2、η 2 - 连接的 Ag 4 (Ox) 4簇核和 dppbpda 桥接配体构成。化合物1 – 3以两个不同的步骤吸收刚果红，最大吸收量为 1438 ( 1 )、1417 ( 2 ) 和 1656 ( 3 ) mg/g，与 CP 中阴离子的大小成反比。这些 CP 在半导体区域 (Eg) 具有 3.05–3.15 eV 的带隙，并且在 CR 的逐步吸附过程中，所有三个都显示出增强的双峰光电流响应，最大光电流密度为 227 ( 1 )、163 ( 2 ) 和 386 ( 3 ) μA
• Gold(I) Chloride Complexes of Polyphosphine Ligands with Electron-Rich Arene Spacer: Gold–Arene Interactions
  作者：Qing-Ling Ni、Xuan-Feng Jiang、Ting-Hong Huang、Xiu-Jian Wang、Liu-Cheng Gui、Kun-Guo Yang

  DOI：10.1021/om201276w

  日期：2012.3.26

  The reactions of Au(tht)Cl (tht = tetrahydrothiophene) with the electron-rich-arene-spacer-containing polyphosphine ligands N,N'-bis((diphenylphosphino)methyl)benzene-1,4-diamine (Dpba), N,N'-bis((diphenylphosphino)methyl)naphthalene-1,5-diamine (Dpna), N,N,N',N'-tetralcis((diphenylphosphino)methyl)benzene-1,4-diamine (Pbaa), N,N,N',N'-tetrakis-((diphenylphosphino)methyl)naphthalene-1,5-diamine (Pnaa), and N,N,N',N'-tetralcis((diphenylphosphino)methyl)biphenyl-4,4'-diamine (Pbbaa) lead to [Dpba(AuCl)2] (1), [Dpna(AuCl)(2)] (2), [Pnaa(AuCl)(4)] (3), [Pbbaa(AuCl)(4) (4). and [Pbaa(AuCl)(4)] (5), which are characterized by H-1 and P-31 NMR, IR, elemental analysis, and X-ray crystal structure analysis. These complexes exhibit weak Au arene interactions with the electron-rich arene spacer, while the Au arene interactions are modified by a combination of electronic and steric effects from the ligands. Different from monomeric complexes 1, 2, 3, and 4, complex 5 in the solid state exhibits a centrosymmetric trimeric unit that is constructed by intermolecular Au center dot center dot center dot Au interactions between the central molecule and the two symmetry-related terminal molecules and in which the conformation of the central molecule is different from that of the two symmetric terminal molecules. On the basis of the Kochi's geometric criteria and the crystal structural parameters relating to Au-arene interactions, the Au center dot center dot center dot C-arene contacts in 3 and 4 feature nearly eta(2)-arene interactions, while the Au center dot center dot center dot C-arene contacts in 5 can be described as eta(1)-arene interactions, and the Au center dot center dot center dot C-arene contacts in 1 and 2, are very weak due to intermolecular N-H center dot center dot center dot Cl interactions.