2,2,4,4-tetrachloro-9,9,10,10,11,11-hexafluoro-7,13-dioxa-1,3,5-triaza-2λ⁵,4λ⁵,6λ⁵-triphospha-spiro[5.7]trideca-1,3,5-triene | 57703-61-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环化合物
• 英文名称: 2,2,4,4-tetrachloro-9,9,10,10,11,11-hexafluoro-7,13-dioxa-1,3,5-triaza-2λ⁵,4λ⁵,6λ⁵-triphospha-spiro[5.7]trideca-1,3,5-triene
• 英文别名: 2,2,4,4-Tetrachloro-9,9,10,10,11,11-hexafluoro-7,13-dioxa-3,5-diaza-1-azanida-2lambda5,4lambda5-diphospha-6-phosphoniaspiro[5.7]trideca-2,4-diene；2,2,4,4-tetrachloro-9,9,10,10,11,11-hexafluoro-7,13-dioxa-3,5-diaza-1-azanida-2λ5,4λ5-diphospha-6-phosphoniaspiro[5.7]trideca-2,4-diene
• CAS: 57703-61-4
• 化学式: C₅H₄Cl₄F₆N₃O₂P₃
• 分子量: 486.829
• InChiKey: UNZGAGDKEFFYPX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  44.2
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  2,2,4,4-tetrachloro-9,9,10,10,11,11-hexafluoro-7,13-dioxa-1,3,5-triaza-2λ⁵,4λ⁵,6λ⁵-triphospha-spiro[5.7]trideca-1,3,5-triene 在 sodium hydride 、 三乙胺 作用下， 以 四氢呋喃 、 mineral oil 为溶剂， 反应 48.0h， 生成
  参考文献：
  名称：

  The synthesis and thermal properties of fluorodioxy-substituted N,N-spiro bridged cyclotriphosphazenes

  摘要：

  Fluorodioxy substituted mono-spiro (1a,b), di-spiro (2a,b) and mono-ansa (3a-c) cyclotriphosphazene derivatives were reacted with n-butylamine to obtain fluorodioxy cyclotriphosphazenes bearing a P-NH group. Then, the fluorodioxy cyclotriphosphazene derivatives containing one NH moiety (4a,b; 5a,5b and 6a-c) which can give a deprotonation reaction were treated with sodium hydride giving rise to new types of bis-cyclophosphazenes bridged with a four-membered cyclophosphazane ring in a spiro arrangement (7, 8, 9a,b and 10a-c). The deprotonation reactions of substituted cyclotriphosphazenes were investigated for the first time and rigid and stable spiro- and ansa-derivatives of N,N-spiro bridged biscyclotriphosphazenes were obtained. Additionally, the thermal stabilities of all new compounds were investigated and found that the thermal stability increases with the formation of N,N-spiro bridge. (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2017.01.014
• 作为产物：
  描述：

  2,2,3,3,4,4-六氟环-1,5-戊二醇 在 六氯环三磷腈 、 三乙胺 作用下， 以 二乙二醇二甲醚 为溶剂， 生成 2,2,4,4-tetrachloro-9,9,10,10,11,11-hexafluoro-7,13-dioxa-1,3,5-triaza-2λ⁵,4λ⁵,6λ⁵-triphospha-spiro[5.7]trideca-1,3,5-triene
  参考文献：
  名称：

  Sharov,V.N. et al., Journal of general chemistry of the USSR, 1975, vol. 45, p. 1919 - 1923

  摘要：

  DOI：

文献信息

• The synthesis and thermal properties of fluorodioxy-substituted N,N-spiro bridged cyclotriphosphazenes
  作者：Ceylan Mutlu Balcı、Serap Beşli

  DOI：10.1016/j.poly.2017.01.014

  日期：2017.4

  Fluorodioxy substituted mono-spiro (1a,b), di-spiro (2a,b) and mono-ansa (3a-c) cyclotriphosphazene derivatives were reacted with n-butylamine to obtain fluorodioxy cyclotriphosphazenes bearing a P-NH group. Then, the fluorodioxy cyclotriphosphazene derivatives containing one NH moiety (4a,b; 5a,5b and 6a-c) which can give a deprotonation reaction were treated with sodium hydride giving rise to new types of bis-cyclophosphazenes bridged with a four-membered cyclophosphazane ring in a spiro arrangement (7, 8, 9a,b and 10a-c). The deprotonation reactions of substituted cyclotriphosphazenes were investigated for the first time and rigid and stable spiro- and ansa-derivatives of N,N-spiro bridged biscyclotriphosphazenes were obtained. Additionally, the thermal stabilities of all new compounds were investigated and found that the thermal stability increases with the formation of N,N-spiro bridge. (C) 2017 Elsevier Ltd. All rights reserved.
• Sharov,V.N. et al., Journal of general chemistry of the USSR, 1975, vol. 45, p. 1919 - 1923
  作者：Sharov,V.N. et al.

  DOI：——

  日期：——