In a rod sealing system, which comprises a buffer ring, a rod seal, and a dust seal, provided successively in this order from a fluid hydraulic side toward the outside in an annular clearance between two members in reciprocating motion, the buffer ring is made up of a thermoplastic polyurethane molding product obtained by subjecting a thermoplastic polyurethane molding product prepared by reaction of (A) a high molecular weight polycarbonatediol having a number average molecular weight Mn of 500-6,000, (B) an aromatic diisocyanate, and (C) a low molecular weight diol as a chain elongation agent in an NCO/OH ratio of 0.95-1.20,to heat treatment under conditions that a glass transition point (Tg) of hard phases becomes 170 °C or higher, preferably 170- 230 °C , and an endothermic peak area (ΔH) at Tg becomes 5J/g or more, by differential scanning calorimetry. The buffer ring made up of the thermoplastic polyurethane molding product has a distinguished heat resistance capable of withstanding the service environmental temperature, particularly maximum 120°C, compression set characteristics, follow-up to eccentricity, etc.
在一种杆密封系统中,包括一个缓冲环、一个杆密封件和一个防尘密封件,在两个往复运动部件之间的环形间隙中从流体液压侧向外依次设置、缓冲环由热塑性聚
氨酯模塑产品构成,该热塑性聚
氨酯模塑产品由以下物质反应制备而成:(A) 平均分子量 Mn 为 500-6,000 的高分子量聚
碳酸酯,(B) 芳香族二
异氰酸酯,和 (C) 作为链延伸剂的低分子量二元醇,其 NCO/OH 比为 0.95-1.20,通过差示扫描量热法,在硬相的
玻璃化转变点(Tg)变为 170℃或更高,最好是 170-230 ℃,Tg 处的内热峰面积(ΔH)变为 5J/g 或更高的条件下进行热处理。由热塑性聚
氨酯模塑产品制成的缓冲环具有出色的耐热性,能够承受使用环境温度,尤其是最高 120°C,并具有压缩永久变形特性和偏心后续特性等。