silver hexanoate | 32461-90-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: silver hexanoate
• 英文别名: silver(I) hexanoate；Silberhexanoat；silver;hexanoate
• CAS: 32461-90-8
• 化学式: Ag*C₆H₁₁O₂
• 分子量: 223.02
• InChiKey: LLISFGHXLYQOBX-UHFFFAOYSA-M

物化性质

• 沸点：
  200-205 °C

计算性质

• 辛醇/水分配系数(LogP)：
  0.31
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  silver hexanoate 在 亚硝酰氯 作用下， 生成 Caproylnitrit
  参考文献：
  名称：

  Pritzkow,W.; Nitzer,H., Journal fur praktische Chemie (Leipzig 1954), 1964, vol. 25, p. 69 - 78

  摘要：

  DOI：
• 作为产物：
  描述：

  己酸 在 氨 、 silver nitrate 作用下， 以 水 为溶剂， 以71%的产率得到silver hexanoate
  参考文献：
  名称：

  [EN] PALLADIUM NANOWIRES AND METHODS OF PREPARATION
  [FR] NANOFILS DE PALLADIUM ET LEURS PROCÉDÉS DE PRÉPARATION

  摘要：

  公开号：

  WO2012109389A3
• 作为试剂：
  描述：

  碘甲基4-硝基苯基碳酸酯 、 己酸 在 silver hexanoate 碳酸氢钠 、 水 、 Sodium sulfate-III 作用下， 以 苯 为溶剂， 反应 2.0h， 以to furnish hexanoyloxymethyl p-nitrophenyl carbonate as a light yellow liquid (0.28 g)的产率得到hexanoyloxymethyl 4-nitrophenyl carbonate
  参考文献：
  名称：

  Process for preparing novel N-(acyloxy-alkoxy)carbonyl derivatives

  摘要：

  本发明涉及一种新的一步法制备新型N-（酰氧烷氧基）羰基衍生物，其可用作具有主要或次要胺基的药物的生物可逆前药基团。

  公开号：

  US04916230A1

文献信息

• Novel developing agents for (photo) thermographic systems
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0681210A1

  公开（公告）日：1995-11-08

  A thermographic element comprising in a non-aqueous binder medium a silver salt oxidising agent in reactive association with a compound comprising a plurality of redox colour releasing moieties such that oxidation of each redox colour releasing moiety causes release from said compound of a thermally diffusible dye. The compounds many of which are new incorporate two or more developer moieties into a single molecule to minimise the diffusibility of the compound. Following oxidation, either directly by the silver salt or by means of a cross-oxidising agent, each oxidised developer moiety releases a thermally diffusible dye. The compounds are of sufficient size and molecular weight to slow or prevent diffusion in imaging systems and yet possess several active developer moieties per molecule which is advantageous over known ballasted dye releasers which comprise bulky molecules with only a single developer moiety.

  一种热成像元素，包括在非水性粘合剂介质中，一种银盐氧化剂与含有多个氧化还原色释放基团的化合物反应地结合，使得每个氧化还原色释放基团的氧化引起所述化合物中的热扩散染料的释放。这些化合物中的许多是新的，将两个或更多的显影剂基团结合到一个分子中，以减少化合物的扩散性。在氧化后，通过银盐直接氧化或通过交叉氧化剂，每个氧化的显影剂基团释放出一个热扩散染料。这些化合物足够大且具有足够的分子量，以在成像系统中减慢或阻止扩散，但每个分子中具有多个活性显影剂基团，这比已知的只包含单个显影剂基团的笨重分子的配重染料释放剂更具优势。
• Hydrates of Organic Compounds. VIII. The Effect of Carboxylate Anions on the Formation of Clathrate Hydrates of Tetrabutylammonium Carboxylates
  作者：Haruo Nakayama、Shigeru Torigata

  DOI：10.1246/bcsj.57.171

  日期：1984.1

  clathrate-like hydrates. The results can be summarized as follows: (1) for 14 carboxylates the formation of a clathrate-like hydrate is newly confirmed; (2) judging from melting points and hydration numbers, the hydrates can be classified into three groups: I, II, and III; (3) the group I hydrates, formed by the carboxylates with R=H, CH3, C2H5, n-C3H7, i-C3H7, and t-C4H9, have hydration numbers around

  检查了四丁基羧酸铵 (n-C4H9)4 NOOCR（R=Hn-C10H21，包括被甲基或乙基取代的各种烷基）与水的二元混合物的固液相图，以确认形成笼状水合物。结果可概括如下： (1) 14 种羧酸盐形成了笼形水合物；(2)从熔点和水合数判断，水合物可分为I、II、III三类；(3) 由 R=H、CH3、C2H5、n-C3H7、i-C3H7 和 t-C4H9 的羧酸盐形成的 I 组水合物的水合数约为 30，是本研究中最稳定的水合物实验，除了 2-甲基丙酸酯和 2,2-二甲基丙酸酯水合物；(4) II组水合物，水合数约为 39，由 R=n-C4H9、s-C4H9、i-C4H9 和所有 C5H11 的盐形成，并且相对不稳定（mp=5–11 °C）；(5) III 组水合物，...
• Organic tellurium compounds—VIII
  作者：M. Moura Campos、E.L. Suranyi、H. de Andrade、N. Petragnani

  DOI：10.1016/s0040-4020(01)98497-2

  日期：1964.1

  di-p-tolyltelluride with ferric, cupric and mercuric chloride, performed in glacial acetic acid, effects the reduction of the metallic salts giving rise to di-p-tolyltellurium dichloride. In toluene solution only the ferric chloride was reduced and the anhydride of di-p-tolyltellurium hydroxychloride formed, due to the hydrolysis of the tellurium dichloride. The reaction of the mentioned telluride and benzoyl

  在冰醋酸中进行二对甲苯基脲与三价铁，氯化铜和氯化汞的反应，使金属盐还原，从而生成二氯化二对甲苯基碲。在甲苯溶液中，由于二氯化碲的水解，仅还原了氯化铁，形成了二对甲苯基羟氯的酸酐。所述碲化物和苯甲酰氯的反应产生二氯化物和二苯甲酸酯的混合物。讨论了该反应的机理。
• Monoaminophenazine leuco dyes and photothermographic materials containing same
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0671393A1

  公开（公告）日：1995-09-13

  Photothermographic elements incorporating leuco forms of phenazinium dyes to provide a developed colour image. The dye has a nucleaus of the general formula: in which;    X represents    Y is H or any substituent other than amino or amido,    R¹, R², R⁴ and R¹⁰ are independently selected from H, alkyl, aryl, alkylsulfonyl, arysulfonyl, alkylcarbonyl, arylcarbonyl, or    R¹ and R² together represent the necessary atoms to complete a cyclic structure or one or more of R¹, R² and R⁴ represent the necessary atoms to complete a cyclic structure fused to the nucleus having skeletal atoms selected from C, N, 0 and S, and    R¹¹ represents any group which will not prevent oxidative cleavage of the X-N bond,    with the proviso that when R¹ is C₂H₅    R² is not C₂H₄NHSO₂CH₃.

  光热成像元件采用苯并二氮杂染料的白态形式，以提供发展后的彩色图像。该染料具有一般式的核：其中; X代表; Y为H或任何不是氨基或酰胺基的取代基，R¹，R²，R⁴和R¹⁰独立地选自H，烷基，芳基，烷基磺酰基，芳基磺酰基，烷基羰基，芳基羰基，或R¹和R²一起代表必要的原子以完成环状结构，或者R¹，R²和R⁴中的一个或多个代表必要的原子以完成与骨架原子（选自C，N，0和S）融合的环状结构，R¹¹代表任何不会防止X-N键的氧化裂解的基团，但当R¹为C₂H₅时，R²不为C₂H₄NHSO₂CH₃。
• Organic silver complex compound used in paste for conductive pattern forming
  申请人：Yoon Sung-Ho

  公开号：US20100021704A1

  公开（公告）日：2010-01-28

  Disclosed is an organic silver complex compound in which an organic ligand, containing an amine group (—NH 2 ) and a hydroxyl group (—OH), is bonded with aliphatic silver (Ag) carboxylate at an equivalent ratio of 2:1 to form a complex. Also disclosed is a conductive paste comprising: a silver source selected from the group consisting of silver oxide powder, silver powder and silver flake; and organic silver complex compound in which an organic ligand, containing an amine group and a hydroxyl group, is bonded with an organic silver compound to form a complex. The organic silver complex compound has high solubility in a solvent and is present in the liquid state at room temperature. Thus, an extra solvent is not used in a conductive pattern-forming paste containing the complex compound or is used in a small amount, such that the content of silver in the conductive pattern-forming paste can be increased. Also, the conductive pattern-forming paste containing the complex compound has high viscosity, and thus shows excellent stability without adding a dispersant and, at the same time, is easily industrially applied.

  本发明揭示了一种有机银配合物化合物，其中含有氨基（—NH2）和羟基（—OH）的有机配体与脂肪族银（Ag）羧酸盐以2:1的当量比结合形成配合物。还揭示了一种导电浆料，包括：从银氧化物粉末、银粉末和银箔中选择的银源；以及含有氨基和羟基的有机配体与有机银化合物结合形成配合物的有机银配合物化合物。有机银配合物化合物在溶剂中具有高溶解度，并在室温下呈液态。因此，在含有配合物的导电图案形成浆料中不需要额外的溶剂，或者只使用少量溶剂，从而可以增加导电图案形成浆料中银的含量。此外，含有配合物的导电图案形成浆料具有高粘度，因此在不添加分散剂的情况下表现出优异的稳定性，并且易于工业应用。