3,3,5,5-Tetramethyl-hexane-1,4-diol | 136175-37-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3,3,5,5-Tetramethyl-hexane-1,4-diol
• 英文别名: 3,3,5,5-Tetramethylhexane-1,4-diol
• CAS: 136175-37-6
• 化学式: C₁₀H₂₂O₂
• 分子量: 174.283
• InChiKey: KIRPPLBXHMVUAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,3-环氧-3-甲基丁烷 、 特戊醛 在 4,4'-di-tert-butylbiphenylide 、 三乙基铝 作用下， 生成 异戊醇 、 3,3,5,5-Tetramethyl-hexane-1,4-diol
  参考文献：
  名称：

  Regiochemical control in the reductive cleavage of 2-alkylated oxetanes by use of trialkylaluminums. Tertiary organolithiums with .gamma.-oxy functionality

  摘要：

  Whereas 2,2-dialkylated oxetanes are cleaved by lithium 4,4'-di-tert-butylbiphenylide to provide the primary organolithium-tertiary oxyanions, the same reaction in the presence of trialkylaluminums gives exclusively the 3-lithio-3,3-disubstituted propoxides, which are trapped by carbonyl compounds in moderate yields.

  DOI：

  10.1021/jo00020a011

文献信息

• 1,2-Dioxetane derivative fused to pyran ring and use thereof
  申请人：Tosoh Corporation

  公开号：EP1038876A2

  公开（公告）日：2000-09-27

  A 1,2-dioxetane derivative represented by the general formula: wherein R1, R2, R3, R4, R5, R6 and R7 each independently represents hydrogen atom, an alkyl group, or an aryl group, or one or more than one pair of R2 and R3, R4 and R5, and R6 and R7 can together form a cyclic alkyl group. The compound is easily handled because the compound itself is very stable, and it is capable of emitting light with a very high efficiency.

  由通式代表的 1，2-二氧杂环丁烷衍生物： 其中 R1、R2、R3、R4、R5、R6 和 R7 各自独立地代表氢原子、烷基或芳基，或者一对或多对 R2 和 R3、R4 和 R5 以及 R6 和 R7 可共同形成环状烷基。这种化合物很容易处理，因为化合物本身非常稳定，而且能够以极高的效率发光。
• US6228653B1
  申请人：——

  公开号：US6228653B1

  公开（公告）日：2001-05-08
• Regiochemical control in the reductive cleavage of 2-alkylated oxetanes by use of trialkylaluminums. Tertiary organolithiums with .gamma.-oxy functionality
  作者：Boguslaw Mudryk、Theodore Cohen

  DOI：10.1021/jo00020a011

  日期：1991.9

  Whereas 2,2-dialkylated oxetanes are cleaved by lithium 4,4'-di-tert-butylbiphenylide to provide the primary organolithium-tertiary oxyanions, the same reaction in the presence of trialkylaluminums gives exclusively the 3-lithio-3,3-disubstituted propoxides, which are trapped by carbonyl compounds in moderate yields.