10-[(2,2,5-trimethyl-1,3-dioxan-5-yl)carbonyloxy]decyl acrylate | 659725-31-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 10-[(2,2,5-trimethyl-1,3-dioxan-5-yl)carbonyloxy]decyl acrylate
• 英文别名: 10-Prop-2-enoyloxydecyl 2,2,5-trimethyl-1,3-dioxane-5-carboxylate
• CAS: 659725-31-2
• 化学式: C₂₁H₃₆O₆
• 分子量: 384.513
• InChiKey: ZNBKRWMUVDTQIU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  27
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  10-[(2,2,5-trimethyl-1,3-dioxan-5-yl)carbonyloxy]decyl acrylate 在 DOWEX 5-W-X₂ resin 作用下， 以 甲醇 为溶剂， 以97%的产率得到Acrylic acid 10-(3-hydroxy-2-hydroxymethyl-2-methyl-propionyloxy)-decyl ester
  参考文献：
  名称：

  Dendronized Aliphatic Polymers by a Combination of ATRP and Divergent Growth

  摘要：

  Dendronized, hybrid dendritic-linear polymers were synthesized by either the "graft-onto" route or by atom transfer radical polymerization (ATRP) of macromonomers. In both ways, the main chain was composed of acrylate repeating units and the dendrons were based on the aliphatic ester skeleton obtained from 2,2-bis(methylol)propionic acid (bis-MPA). ATRP of macromonomers was not a viable route for monomers with side chains larger than second-generation dendrons, which is why a combination of the two approaches was required to obtain polymers with larger side chains. The "graft-onto" route was conducted by reacting hydroxyl groups on the main chain with the acetonide-protected 2,2-bis(hydroxymethyl)propionic anhydride. The acetonide protecting group was easily removed by treating a solution of the polymer with an acidic ion-exchange resin. Dendronized polymers with 1-3 generation dendron side groups were synthesized with a maximum molecular weight of ca. 86 kDa. The products were analyzed by H-1 and C-13 NMR, SEC, and MALDI-TOF.

  DOI：

  10.1021/ma0347464
• 作为产物：
  描述：

  1,10-癸二醇 在 吡啶 、 4-二甲氨基吡啶 、 TEA 作用下， 以 二氯甲烷 为溶剂， 生成 10-[(2,2,5-trimethyl-1,3-dioxan-5-yl)carbonyloxy]decyl acrylate
  参考文献：
  名称：

  Dendronized Aliphatic Polymers by a Combination of ATRP and Divergent Growth

  摘要：

  Dendronized, hybrid dendritic-linear polymers were synthesized by either the "graft-onto" route or by atom transfer radical polymerization (ATRP) of macromonomers. In both ways, the main chain was composed of acrylate repeating units and the dendrons were based on the aliphatic ester skeleton obtained from 2,2-bis(methylol)propionic acid (bis-MPA). ATRP of macromonomers was not a viable route for monomers with side chains larger than second-generation dendrons, which is why a combination of the two approaches was required to obtain polymers with larger side chains. The "graft-onto" route was conducted by reacting hydroxyl groups on the main chain with the acetonide-protected 2,2-bis(hydroxymethyl)propionic anhydride. The acetonide protecting group was easily removed by treating a solution of the polymer with an acidic ion-exchange resin. Dendronized polymers with 1-3 generation dendron side groups were synthesized with a maximum molecular weight of ca. 86 kDa. The products were analyzed by H-1 and C-13 NMR, SEC, and MALDI-TOF.

  DOI：

  10.1021/ma0347464

文献信息

• Ink composition, inkjet recording method, printed material, method for producing planographic printing plate, and planographic printing plate
  申请人：Fujifilm Corporation

  公开号：EP1803784A2

  公开（公告）日：2007-07-04

  The invention provides an ink composition having at least (A) a polymerization initiator, (B) an ester or amide of (meth)acrylic acid having a 1,3-dioxolane ring skeleton or a 1,3-dioxane ring skeleton or (B') an ester or amide of (meth)acrylic acid having a 1,3-diketone structure, and (C) a colorant. The invention further provides an inkjet recording method and a method for producing a planographic printing plate, each of which includes at least (I) ejecting the ink composition onto a hydrophilic support and (II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support. The invention furthermore provides a planographic printing plate formed by the method for producing a planographic printing plate.

  本发明提供了一种墨水组合物，它至少具有(A)聚合引发剂，(B)具有 1，3-二氧戊环骨架或 1，3-二氧六环骨架的(甲基)丙烯酸酯或酰胺，或(B')具有 1，3-二酮结构的(甲基)丙烯酸酯或酰胺，以及(C)着色剂。本发明进一步提供了一种喷墨记录方法和一种平面印刷板的制作方法，其中每种方法都至少包括：(I) 将墨水组合物喷射到亲水性支撑物上；(II) 用活性辐射照射喷射出的墨水组合物，使墨水组合物固化，从而在亲水性支撑物上形成疏水性图像区域。此外，本发明还提供了一种由该方法形成的平版印刷板。
• [EN] PHOTOSENSITIVE RESIN COMPOSITION, SPACER, PROTECTIVE FILM AND LIQUID CRYSTAL DISPLAY DEVICE<br/>[FR] COMPOSITION DE RÉSINE PHOTOSENSIBLE, ESPACEUR, FILM DE PROTECTION ET DISPOSITIF D'AFFICHAGE À CRISTAUX LIQUIDES<br/>[ZH] 感光性树脂组成物、间隙体、保护膜以及液晶显示元件
  申请人：CHI MEI CORP

  公开号：WO2016058546A1

  公开（公告）日：2016-04-21

  一种感光性树脂组成物，其包括碱可溶性树脂（A）、含乙烯性不饱和基的化合物（B）、光起始剂（C）以及溶剂（D）。含乙烯性不饱和基的化合物（B）包括具有式（II）结构的含乙烯性不饱和基的第一化合物（B-1）。所述光起始剂（C）包括由式（1）表示的光起始剂（C-1）。
• INK COMPOSITION, INKJET RECORDING METHOD, PRINTED MATERIAL, METHOD FOR PRODUCING PLANOGRAPHIC PRINTING PLATE, AND PLANOGRAPHIC PRINTING PLATE
  申请人：Nakamura Ippei

  公开号：US20100298494A1

  公开（公告）日：2010-11-25

  The invention provides an ink composition having at least (A) a polymerization initiator, (B) an ester or amide of (meth)acrylic acid having a 1,3-dioxolane ring skeleton or a 1,3-dioxane ring skeleton or (B′) an ester or amide of (meth)acrylic acid having a 1,3-diketone structure, and (C) a colorant. The invention further provides an inkjet recording method and a method for producing a planographic printing plate, each of which includes at least (I) ejecting the ink composition onto a hydrophilic support and (II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support. The invention furthermore provides a planographic printing plate formed by the method for producing a planographic printing plate.
• US7794918B2
  申请人：——

  公开号：US7794918B2

  公开（公告）日：2010-09-14
• US8211623B2
  申请人：——

  公开号：US8211623B2

  公开（公告）日：2012-07-03