(Diphenylarsino)ethen | 61193-58-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (Diphenylarsino)ethen
• 英文别名: diphenylvinylarsine；vinyl-diphenyl-arsine；Diphenylvinylarsen；Ethenyl(diphenyl)arsane
• CAS: 61193-58-6
• 化学式: C₁₄H₁₃As
• 分子量: 256.179
• InChiKey: TUQPTXHRZVCABH-UHFFFAOYSA-N

物化性质

• 沸点：
  300.7±15.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.02
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (Diphenylarsino)ethen 在 双氧水 作用下， 以 丙酮 为溶剂， 以22%的产率得到Diphenylvinylarsane oxide
  参考文献：
  名称：

  Kauffmann, Thomas; Ahlers, Holger; Echsler, Klaus-Josef, Chemische Berichte, 1985, vol. 118, # 11, p. 4496 - 4506

  摘要：

  DOI：
• 作为产物：
  描述：

  二苯胂化氯 、 乙烯基氯化镁 以75%的产率得到(Diphenylarsino)ethen
  参考文献：
  名称：

  Kauffmann, Thomas; Ahlers, Holger; Echsler, Klaus-Josef, Chemische Berichte, 1985, vol. 118, # 11, p. 4496 - 4506

  摘要：

  DOI：

文献信息

• Asymmetric synthesis of a chiral diarsine ligand via a cycloaddition reaction between 3,4-dimethyl-1-phenylarsole and diphenylvinylarsine
  作者：Weiwei Yao、Mengtao Ma、Weifan Wang、Jianming Cheng、Li Xu、Sumod A. Pullarkat、Pak-Hing Leung

  DOI：10.1016/j.tetasy.2014.06.005

  日期：2014.8
• Kauffmann,T. et al., Angewandte Chemie, 1977, vol. 89, p. 760 - 761
  作者：Kauffmann,T. et al.

  DOI：——

  日期：——
• Asymmetric Synthesis of a (P-Chiral) As−P Bidentate Ligand <i>via</i> an Organopalladium Complex Promoted Asymmetric Diels−Alder Reaction between Ph₂AsCHCH₂ and 1-Phenyl-3,4-dimethylphosphole
  作者：Beng-Hwee Aw、Pak-Hing Leung、Andrew J. P. White、David J. Williams

  DOI：10.1021/om9600351

  日期：1996.8.20

  Convenient access to the enantiomerically pure rigid bidentate ligand (-)-[5-(diphenylarsino)-2,3 -dimethyl-7-phenyl-7(S)-phosphabicyclo[2.2.1]hept-2-ene is established via an asymmetric [4 + 2] cycloaddition between diphenylvinylarsine and 1-phenyl-3,4-dimethylphosphole using the chiral organopalladium(II) complex containing ortho-metalated dimethyl[1-(2-naphthyl)ethyl]amine as the reaction promoter. The absolute configurations of the four newly generated stereocenters have been assigned by single-crystal X-ray analysis.
• Synthesis and Characterization of [(η⁶-arene)RuCl₂(R₂AsCHCH₂)] and Tethered Arsinopropylarene−Ruthenium(II) Complexes
  作者：John H. Nelson、Kesete Y. Ghebreyessus、Vernon C. Cook、Alison J. Edwards、Wolfram Wielandt、S. Bruce Wild、Anthony C. Willis

  DOI：10.1021/om011092j

  日期：2002.4.1

  The complexes [eta(6)-arene)RuCl2(R2AsCH=CH2)] [arene = MeC6H5, R = Ph (1a), R = Cy (1b); p-MeC6H4Me, R = Ph (2a), R = Cy (2b); o-MeC6H4Me, R = Ph (3a), R = Cy (3b); 1,3,5-Me3C6H3, R = Ph (4a); p-MeC6H4CHMe2, R = Ph (5a), R = Cy (5b); 1,2,4,5-Me4C6H2, R = Ph (6a), R = Cy (6b); C6Me6, R = Ph (7a)] have been synthesized by reacting [eta(6)-arene)-RuCl2](2) with the respective vinyl arsine. The compounds [eta(6)-MeC6H5)RuCl2(Ph2AsCH=CH2)] (1a) and [eta(6)-1,3,5-Me3C6H3)RuCl2(Ph2AsCH=CH2)] (4a) undergo KOBut-promoted intramolecular hydroalkylation in boiling acetonitrile to produce tethered arsinopropylareneruthenium(II) complexes 1c and 4c, respectively. The complexes have been characterized by H-1 and C-13H-1} NMR spectroscopy, elemental analyses, cyclic voltammetry, and in several cases by X-ray crystallography.
• KAUFFMANN, TH.;AHLERS, H.;ECHSLER, K. -J.;SCHULZ, H.;TILHARD, H. -J., CHEM. BER., 1985, 118, N 11, 4496-4506
  作者：KAUFFMANN, TH.、AHLERS, H.、ECHSLER, K. -J.、SCHULZ, H.、TILHARD, H. -J.

  DOI：——

  日期：——