tetradecyl phenylphosphonic acid | 122584-05-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetradecyl phenylphosphonic acid
• 英文别名: Phenyl(tetradecoxy)phosphinic acid
• CAS: 122584-05-8
• 化学式: C₂₀H₃₅O₃P
• 分子量: 354.47
• InChiKey: YFQZGSHPXAYPFG-UHFFFAOYSA-N

物化性质

• 沸点：
  462.3±28.0 °C(Predicted)
• 密度：
  1.01±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  24
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  十四醇 在 palladium on activated charcoal 吡啶 、 氢气 作用下， 以 溶剂黄146 、 苯 为溶剂， 反应 25.0h， 生成 tetradecyl phenylphosphonic acid
  参考文献：
  名称：

  An Improved Access to Phosphonic Acids and Their Mono-and Diesters

  摘要：

  磷二氯化物的反应与苄醇和脂肪醇混合物提供了相应的二苄基膦酸盐、二烷基膦酸盐和烷基苄基膦酸盐混合物，该混合物通过柱色谱法容易分离得到纯成分。二苄基膦酸盐通过催化氢化裂解得到膦酸，而烷基苄基膦酸盐在相同条件下裂解得到烷基氢膦酸盐（单酯）。

  DOI：

  10.1055/s-1988-27752

文献信息

• Alkyl phenylphosphonic acid extractants and processes for their manufacture
  申请人：——

  公开号：US20010029810A1

  公开（公告）日：2001-10-18

  The present invention provides a novel process for the removal and recovery of radionuclides from waste waters and process streams. The process of the present invention utilizes a combination of a supported liquid membrane (SLM) and a strip dispersion to improve extraction of the target species while increasing membrane stability and reducing processing costs. Additionally, the invention provides a family of new extractants, alkyl phenylphosphonic acids, for the removal and recovery of radionuclides and/or metals, including the use of the new extractants in the process. The new extractant selectively removes radionuclides and metals from the feed stream to provide a concentrated strip solution of the target species.

  本发明提供了一种从废水和工艺流中去除和回收放射性核素的新型工艺。本发明的工艺利用支撑液体膜（SLM）和带状分散体的组合来改善目标物质的萃取，同时提高膜的稳定性并降低处理成本。此外，本发明还提供了一系列新型萃取剂--烷基苯基膦酸，用于去除和回收放射性核素和/或金属，包括在工艺中使用新型萃取剂。新萃取剂可选择性地从进料流中去除放射性核素和金属，从而提供目标物质的浓缩带状溶液。
• US6328782B1
  申请人：——

  公开号：US6328782B1

  公开（公告）日：2001-12-11
• US6696589B2
  申请人：——

  公开号：US6696589B2

  公开（公告）日：2004-02-24
• [EN] COMBINED SUPPORTED LIQUID MEMBRANE/STRIP DISPERSION PROCESSES AND EXTRACTANTS<br/>[FR] PROCEDES COMBINANT UNE DISPERSION D'EPURATION ET DES MEMBRANES LIQUIDES SUR SUPPORT, ET AGENTS D'EXTRACTION
  申请人：COMMODORE SEPARATION TECHNOLOG

  公开号：WO2001056933A2

  公开（公告）日：2001-08-09

  The present invention provides a novel process for the removal and recovery of target species, such as metals, radionuclides, penicillins, and organic acids, from waste waters and process streams. The process of the present invention utilizes a combination of a supported liquid membrane (SLM) and a strip dispersion to improve extraction of the target species while increasing membrane stability and reducing processing costs. The present invention also provides an SLM, embedded in a microporous support material with an interfacial polymerized layer or layers. Additionally, the present invention provides novel classes of extractants and methods of manufacture for the extractants. The new classes of extractants include alkyl phenylphosphonic acids and dialkyl phosphoric acids. The method for manufacturing the dialkyl phosphoric acid extractants includes mixing phosphorus pentasulfide with an alcohol, followed by hydrolysis of the intermediate reactants with a mineral acid.
• An Improved Access to Phosphonic Acids and Their Mono-and Diesters
  作者：Françoise Plénat、Sanusi Ibrahim、Henri-Jean Cristau

  DOI：10.1055/s-1988-27752

  日期：——

  The reaction of phosphonic dichlorides with a mixture of benzyl alcohol and an aliphatic alcohol affords a mixture of the corresponding dibenzyl phosphonate, dialkyl phosphonate, and alkyl benzyl phosphonate which is easily separated by column chromatography to give the pure components. Cleavage of the dibenzyl phosphonate by catalytic hydrogenation affords the phosphonic acid whereas cleavage of the alkyl benzyl phosphonate under the same conditions affords the alkyl hydrogen phosphonate (monoester).

  磷二氯化物的反应与苄醇和脂肪醇混合物提供了相应的二苄基膦酸盐、二烷基膦酸盐和烷基苄基膦酸盐混合物，该混合物通过柱色谱法容易分离得到纯成分。二苄基膦酸盐通过催化氢化裂解得到膦酸，而烷基苄基膦酸盐在相同条件下裂解得到烷基氢膦酸盐（单酯）。