1,5-dimorpholino-pentane | 5625-91-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: 1,5-dimorpholino-pentane
• 英文别名: 1,5-Dimorpholino-pentan；4-(5-Morpholin-4-ylpentyl)morpholine
• CAS: 5625-91-2
• 化学式: C₁₃H₂₆N₂O₂
• 分子量: 242.362
• InChiKey: XZZMJRSDPRIVGX-UHFFFAOYSA-N

物化性质

• 沸点：
  347.2±37.0 °C(Predicted)
• 密度：
  1.008±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,5-dimorpholino-pentane 在 氢氟酸 作用下， 以26%的产率得到perfluorodimorpholinopentane
  参考文献：
  名称：

  On the electrochemical fluorination of derivatives of morpholine and piperidine

  摘要：

  Electrochemical fluorination (ECF) of alpha,omega-dimorpholino- and dipiperidino-alkanes of different chain length (n = 1-6) and of morpholinocyclohexene gave the perfluoro derivatives in yields up to 45%. By ring contractions, fragmentations and rearrangements several side products were obtained. Conclusions on the mechanism of ECF, based on a sterical model, were drawn.

  DOI：

  10.1016/s0022-1139(00)80306-1
• 作为产物：
  描述：

  4-(2-氯乙基)吗啉 在 乙醇 、 镍 、 sodium amide 、 甲苯 作用下， 生成 1,5-dimorpholino-pentane
  参考文献：
  名称：

  Hypotensive Agents. I. Acetylenic Diamines

  摘要：

  DOI：

  10.1021/ja01550a049

文献信息

• ORGANO-1-OXA-4-AZONIUM CYCLOHEXANE COMPOUNDS
  申请人：UOP LLC

  公开号：US20160159760A1

  公开（公告）日：2016-06-09

  Novel 1-oxa-4-azonium cyclohexane salts are described. These compounds can be used as structure directing agents, and they overcome many of the typical problems associated with OSDA synthesis and subsequent zeolite synthesis. Methods for synthesis of the 1-oxa-4-azonium cyclohexane salts from a variety of starting materials are also described. A substituted hydrocarbon is added to water to form a mixture, and a 1-oxa-4-azacyclohexane derivative is then added. The reaction mixture stirred until a solution containing the 1-oxa-4-azonium cyclohexane salt is obtained.

  描述了新型的1-oxa-4-azonium环己烷盐。这些化合物可用作结构导向剂，并且克服了与OSDA合成和随后的沸石合成相关许多典型问题。还描述了从各种起始材料合成1-oxa-4-azonium环己烷盐的方法。 将取代的烃加入水中形成混合物，然后加入1-oxa-4-azacyclohexane衍生物。搅拌反应混合物，直到获得含有1-oxa-4-azonium环己烷盐的溶液。
• alpha, omega-Amino Alcohols. I. N-Phenyl-N′-(ω-hydroxyalkyl)-piperazines from α,ω-Chlorohydrins. Derivatives of Piperazine. XVII
  作者：George W. Anderson、C. B. Pollard

  DOI：10.1021/ja01267a062

  日期：1939.12
• SALTS OF CARBOXYLIC ACID HERBICIDES
  申请人：MONSANTO TECHNOLOGY LLC

  公开号：US20140309114A1

  公开（公告）日：2014-10-16

  Amine salts of certain herbicides that in free acid form include at least one carboxylic acid moiety are described. Herbicide salts comprising the cation of various imidazole, piperazine, piperidine, and morpholine compounds are provided. The herbicide amine salts described are suitable for formulation into herbicidal application mixtures and/or stable concentration compositions that exhibit acceptable volatility characteristics upon application.