4-(diisopropyloxymethylsilyl)styrene | 105785-18-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(diisopropyloxymethylsilyl)styrene
• 英文别名: 4-(methyldiisopropyloxysilyl)styrene；(4-ethenylphenyl)-methyl-di(propan-2-yloxy)silane
• CAS: 105785-18-0
• 化学式: C₁₅H₂₄O₂Si
• 分子量: 264.44
• InChiKey: ZLRLHTVXSARHDM-UHFFFAOYSA-N

物化性质

• 沸点：
  303.5±21.0 °C(Predicted)
• 密度：
  0.93±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.46
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(diisopropyloxymethylsilyl)styrene 在 palladium diacetate 、 对甲苯磺酸 、 三乙胺 、 三(邻甲基苯基)磷 作用下， 以 甲苯 为溶剂， 反应 28.0h， 生成 4,4'-bis(dimethoxymethylsilyl)stilbene
  参考文献：
  名称：

  Rigid rod molecules containing two Si(OMe)3 or SiMe(OMe)2 groups for hybrid materials synthesis

  摘要：

  The synthesis of new bis(trimethoxysilyl) and bis(dimethoxymethylsilyl)arene compounds containing rigid organic groups such as stilbenyl, diphenylacetylene or diphenylbut-1,3-diyne is reported. The Heck type reaction constituted a convenient route to these compounds. since this coupling reaction appeared compatible with the presence of Si(OR)(3) groups. (C) 2001 Elsevier Science B.V. All nights reserved.

  DOI：

  10.1016/s0022-328x(01)00668-4
• 作为产物：
  描述：

  对溴苯乙烯 、 Chlor-diisopropyloxy-methyl-silan 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以56%的产率得到4-(diisopropyloxymethylsilyl)styrene
  参考文献：
  名称：

  Rigid rod molecules containing two Si(OMe)3 or SiMe(OMe)2 groups for hybrid materials synthesis

  摘要：

  The synthesis of new bis(trimethoxysilyl) and bis(dimethoxymethylsilyl)arene compounds containing rigid organic groups such as stilbenyl, diphenylacetylene or diphenylbut-1,3-diyne is reported. The Heck type reaction constituted a convenient route to these compounds. since this coupling reaction appeared compatible with the presence of Si(OR)(3) groups. (C) 2001 Elsevier Science B.V. All nights reserved.

  DOI：

  10.1016/s0022-328x(01)00668-4

文献信息

• Curable silicone resin composition and reactive silicon compounds
  申请人：——

  公开号：US20030130389A1

  公开（公告）日：2003-07-10

  A curable silicone resin composition comprises (A) an uncured silicone resin having units of the formula (R*) a (R) b SiO (4−a−b)/2 , where each R* is a functional group capable of reacting with Si—OH and/or Si-alkoxy groups and each R is a nonfunctional monovalent hydrocarbon group, a+b is from 1.0 to 3.0 and each molecule of uncured silicone resin contains an average of at least two groups R*, and (B) a silanol or hydrolysable compound of the formula (I) where R′ represents a hydroxyl group or a hydrolysable group; each R″ represents hydrogen, a monovalent hydrocarbon which optionally is substituted, or a group within the above definition of R′; and Ar is a substantially nonflexible linkage including at least one para-arylene moiety, so that the groups (R′) 2 R″Si— are spatially separated.

  一种可治愈的硅树脂组合物包括(A)未固化的硅树脂，其具有式(R*)a(R)bSiO(4−a−b)/2的单元，其中每个R*是能够与Si—OH和/或Si-烷氧基反应的功能性基团，每个R是非功能性单价碳氢基团，a+b为1.0至3.0，每个未固化的硅树脂分子含有平均至少两个R*基团；以及(B)式(I)的硅醇或可水解化合物，其中R'代表羟基或可水解基团；每个R"代表氢、一价碳氢基团（可选地被取代）或上述R'定义内的基团；Ar是包括至少一个对位芳基单元的实质上非柔性连接，以使得(R')2R"Si—基团在空间上分离。
• CURABLE SILICONE RESIN COMPOSITION AND REACTIVE SILICON COMPOUNDS
  申请人：DOW CORNING CORPORATION

  公开号：EP1276807B1

  公开（公告）日：2005-10-12
• Rigid rod molecules containing two Si(OMe)3 or SiMe(OMe)2 groups for hybrid materials synthesis
  作者：Geneviève Cerveau、Sabrina Chappellet、Robert J.P. Corriu*、Bertrand Dabiens

  DOI：10.1016/s0022-328x(01)00668-4

  日期：2001.4

  The synthesis of new bis(trimethoxysilyl) and bis(dimethoxymethylsilyl)arene compounds containing rigid organic groups such as stilbenyl, diphenylacetylene or diphenylbut-1,3-diyne is reported. The Heck type reaction constituted a convenient route to these compounds. since this coupling reaction appeared compatible with the presence of Si(OR)(3) groups. (C) 2001 Elsevier Science B.V. All nights reserved.