bis(2-hydroxy-3-(methacryloyloxy)propyl)-2,2-dimethyl-4-methylenepentanedioate | 1392192-30-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: bis(2-hydroxy-3-(methacryloyloxy)propyl)-2,2-dimethyl-4-methylenepentanedioate
• 英文别名: Bis[2-hydroxy-3-(2-methylprop-2-enoyloxy)propyl] 2,2-dimethyl-4-methylidenepentanedioate；bis[2-hydroxy-3-(2-methylprop-2-enoyloxy)propyl] 2,2-dimethyl-4-methylidenepentanedioate
• CAS: 1392192-30-1
• 化学式: C₂₂H₃₂O₁₀
• 分子量: 456.49
• InChiKey: HHXMBBPGMGATLU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  32
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  146
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  bis(2-hydroxy-3-(methacryloyloxy)propyl)-2,2-dimethyl-4-methylenepentanedioate 在 四磷十氧化物 、 2,6-二叔丁基-4-甲基苯酚 、 tin(II) octanoate 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 1.25h， 生成 AFM-caprolactonyl phosphate
  参考文献：
  名称：

  DENTAL COMPOSITIONS COMPRISING ADDITION-FRAGMENTATION AGENTS

  摘要：

  揭示了一种可治愈的牙科组合物，包括一种加成-断裂剂和一种可治愈的牙科树脂。

  公开号：

  US20160008234A1
• 作为产物：
  描述：

  dimethyl 2,2-dimethyl-4-methylenepentanoate 在 水 、 三苯基锑 、 potassium hydroxide 作用下， 反应 46.0h， 生成 bis(2-hydroxy-3-(methacryloyloxy)propyl)-2,2-dimethyl-4-methylenepentanedioate
  参考文献：
  名称：

  DENTAL COMPOSITIONS COMPRISING ADDITION-FRAGMENTATION AGENTS

  摘要：

  揭示了一种可治愈的牙科组合物，包括一种加成-断裂剂和一种可治愈的牙科树脂。

  公开号：

  US20160008234A1

文献信息

• [EN] ADDITION-FRAGMENTATION AGENT WITH PENDENT AMINE GROUPS<br/>[FR] AGENT D'ADDITION-FRAGMENTATION À GROUPES AMINE PENDANTS
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2020075007A1

  公开（公告）日：2020-04-16

  Provided is an addition-fragmentation agent of the formula (I) where Ramine comprises a tertiary amine group; R2 linking group of valence a+2; Z is an ethylenically unsaturated polymerizable group; and subscript a is 0 or 1.

  提供的是公式（I）的加成-分裂剂，其中Ramine包括一个三级胺基团；R2是价为a+2的连接基团；Z是一个乙烯基不饱和可聚合基团；下标a为0或1。
• Polymer Materials With Unsaturated Transfer Reagents
  申请人：Ivoclar Vivadent AG

  公开号：US20200087241A1

  公开（公告）日：2020-03-19

  Radically polymerizable composition which contains at least one vinyl ether according to general formula I: in which the variables have the following meanings: A is H, CN, a cycloaliphatic, linear or branched aliphatic C 1 -C 30 hydrocarbon residue, an aromatic C 6 -C 30 hydrocarbon residue or a combination thereof; X is —COO—, —CON(R 3 )— or is dispensed with; B is H, CN, a cycloaliphatic, linear or branched aliphatic C 1 -C 30 hydrocarbon residue, an aromatic C 6 -C 30 hydrocarbon residue or a combination thereof; Y is —COO—, —CON(R 3 )— or is dispensed with; R 1-3 in each case independently of one another are hydrogen, a cycloaliphatic, linear or branched aliphatic C 1 -C 10 hydrocarbon residue or an aromatic C 6 -C 10 hydrocarbon residue; m is an integer from 1 to 6; n is an integer from 1 to 6; p is an integer from 1 to 6; wherein m and p cannot be greater than 1 at the same time and wherein if m=1, p=n, and if p=1, m=n.

  包含至少一种根据通式I的乙烯醚的根本聚合组合物：其中变量具有以下含义：A为H、CN、环脂肪、线性或支链脂肪C1-C30烃残基、芳香族C6-C30烃残基或它们的组合；X为—COO—、—CON(R3)—或省略；B为H、CN、环脂肪、线性或支链脂肪C1-C30烃残基、芳香族C6-C30烃残基或它们的组合；Y为—COO—、—CON(R3)—或省略；R1-3分别独立地为氢、环脂肪、线性或支链脂肪C1-C10烃残基或芳香族C6-C10烃残基；m为1到6的整数；n为1到6的整数；p为1到6的整数；其中m和p不能同时大于1，如果m=1，则p=n，如果p=1，则m=n。
• [EN] ADDITION-FRAGMENTATION AGENTS<br/>[FR] AGENTS D'ADDITION-FRAGMENTATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2012112304A1

  公开（公告）日：2012-08-23

  Addition-fragmentation agents of the formula are disclosed formula (I): wherein R1, R2 and R3 are each independently Z-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R1, R2 and R3 is Zm-Q-, Q is a linking group have a valence of m +1; Z is an ethylenically unsaturated polymerizable group, m is 1 to 6; each X1 is independently -O- or -NR4-, where R4 is H or C1-C4 alkyl, and n is 0 or 1.

  公开了化学式为（I）的加成-解离剂，其中R1、R2和R3分别独立地是Z-Q-、(杂)烷基或(杂)芳基，但至少其中一个是Zm-Q-，Q是具有价态为m+1的连接基团；Z是乙烯基不饱和可聚合基团，m为1至6；每个X1独立地是-O-或-NR4-，其中R4是H或C1-C4烷基，n为0或1。
• DENTAL COMPOSITIONS COMPRISING ETHYLENICALLY UNSATURATED ADDITION-FRAGMENTATION AGENT
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20150238389A1

  公开（公告）日：2015-08-27

  Dental compositions are described comprising an addition-fragmentation agent of the formula: wherein R 1 , R 2 and R 3 are each independently Z m -Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R 1 , R 2 and R 3 is Z m -Q-; Q is a linking group have a valence of m+1; Z is an ethylenically unsaturated polymerizable group; m is 1 to 6; each X 1 is independently —O— or —NR 4 —, where R 4 is H or C 1 -C 4 alkyl; and n is 0 or 1. Also described are dental articles prepared from a dental composition comprising an addition-fragmentation agent and methods of treating a tooth surface.

  本文描述了一种牙科组合物，其中包括一个式子为的加成-断裂剂：其中R1、R2和R3各自独立地是Zm-Q-、(杂)烷基或(杂)芳基，但至少其中一个是Zm-Q-；Q是具有价为m+1的连接基；Z是乙烯基不饱和可聚合基团；m为1至6；每个X1分别是—O—或—NR4—，其中R4是H或C1-C4烷基；n为0或1。还描述了从含有加成-断裂剂的牙科组合物制备的牙科制品和治疗牙齿表面的方法。
• ADDITION-FRAGMENTATION OLIGOMERS HAVING HIGH REFRACTIVE INDEX GROUPS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20160346170A1

  公开（公告）日：2016-12-01

  Addition-fragmentation oligomers of the general formula Z—B y -A-(B-A) x -B-A-B y —Z, where the A monomers units are derived from a diester or diacid, the B monomer units are derived from a difunctional monomer having functional groups co-reactive with the acid or ester groups of the A monomer, x+y is zero to 60, Z comprises an ethylenically unsaturated, polymerizable group, A monomers comprise a 1-methylene-3,3-dimethylpropyl group, and at least one B monomer unit comprises a high refractive index group.

  一般公式为Z-By-A-(B-A)x-B-A-By-Z的加成-断裂寡聚体，其中A单体单元来源于二酯或二酸，B单体单元来源于具有与A单体的酸或酯基反应的官能团的双官能单体，x+y为0至60，Z包括一个具有乙烯基不饱和度、可聚合的基团，A单体包括1-亚甲基-3,3-二甲基丙基基团，并且至少一个B单体单元包括高折射率基团。