2,5-dimethyl-3,4-diphenylcyclopenta-2,4-dione dimer | 13360-84-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 2,5-dimethyl-3,4-diphenylcyclopenta-2,4-dione dimer
• 英文别名: 2,5-dimethyl-3,4-diphenylcyclopentadienone dimer；2,4,7,7a-tetramethyl-3,3a,5,6-tetraphenyl-3a,4,7,7a-tetrahydro-4,7-methano-indene-1,8-dione；2,5-dimethyl-3,4-diphenyl-cyclopentadienone dimer；2,4,7,7a-Tetramethyl-3,3a,5,6-tetraphenyl-3a,4,7,7a-tetrahydro-4,7-methano-inden-1,8-dion；1.8-Dioxo-2.4.7.7a-tetramethyl-3.3a.5.6-tetraphenyl-3a.4.7.7a-tetrahydro-4.7-methano-inden；2.4.7.7a-Tetramethyl-3.3a.5.6-tetraphenyl-4.7-carbonyl-3a.4.7.7a-tetrahydro-indenon-(1)；1,2,4,7-Tetramethyl-5,6,8,9-tetraphenyltricyclo[5.2.1.02,6]deca-4,8-diene-3,10-dione
• CAS: 13360-84-4
• 化学式: C₃₈H₃₂O₂
• 分子量: 520.671
• InChiKey: NBMUMLNUVRPNNO-UHFFFAOYSA-N

物化性质

• 熔点：
  190 °C (decomp)
• 沸点：
  200-204 °C(Press: 3 Torr)
• 密度：
  1.220±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  40
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,5-dimethyl-3,4-diphenylcyclopenta-2,4-dione dimer 在 三氯化铝 、 苯 作用下， 生成 2,5-dimethyl-3,4-diphenyl-cyclopentanone
  参考文献：
  名称：

  The Thermal Decomposition of Certain Polyarylated Carbinols

  摘要：

  DOI：

  10.1021/ja01247a031
• 作为产物：
  描述：

  4-hydroxy-2,5-dimethyl-3,4-diphenylcyclopent-2-enone 在 硫酸 、 乙酸酐 作用下， 以 溶剂黄146 为溶剂， 反应 3.0h， 以33.5 g的产率得到2,5-dimethyl-3,4-diphenylcyclopenta-2,4-dione dimer
  参考文献：
  名称：

  Synthesis, Reactivity, and Electronic Properties of 6,6-Dicyanofulvenes

  摘要：

  A series of 6,6-dicyanofulvene derivatives are synthesized starting from masked, dimeric, or monomeric cyclopentadienones. The reactivities of 6,6-dicyanofulvenes relative to their parent cyclopentadienones are discussed. 6,6-Dicyanofulvenes are capable of undergoing two consecutive, reversible, one-electron reductions and are presented as potential n-type small molecules.

  DOI：

  10.1021/ol102384k

文献信息

• [EN] CARBON MONOXIDE RELEASING NORBORNENONE COMPOUNDS<br/>[FR] COMPOSÉS DE NORBORNÉNONE LIBÉRANT DU MONOXYDE DE CARBONE
  申请人：SAMMUT IVAN ANDREW

  公开号：WO2017095237A1

  公开（公告）日：2017-06-08

  The present invention provides organic compounds which are capable of releasing carbon monoxide under physiological conditions or pH trigger, and to the use of such compounds for conditioning a cell, tissue or organ, for example, to protect against ischaemic injury during a transplant event.

  本发明提供了在生理条件或pH触发下能够释放一氧化碳的有机化合物，以及将这种化合物用于调节细胞、组织或器官，例如，在移植事件中保护免受缺血性损伤的使用方法。
• Cyclopentadienone complexes of molybdenum: synthesis of carbonyl, acetonitrile, phosphine and phosphido-bridged derivatives
  作者：Harry Adams、Neil A. Bailey、Paul D. Hempstead、Michael J. Morris、Sarah Riley、Roy L. Beddoes、Elizabeth S. Cook

  DOI：10.1039/dt9930000091

  日期：——

  Reaction of [Mo(CO)6] with 2 equivalents of tetraphenylcyclopentadienone (tetracyclone) in refluxing toluene gives [Mo(CO)2(η4-C4Ph4CO)2]1a in ca. 95% yield. With 1 equivalent of tetracyclone in boiling heptane, [Mo(CO)3(σ:η4-C4Ph4CO)}2]2 is produced as well as 1a. This dimeric complex has been crystallographically characterised [triclinic, space group P(no. 2), a= 8.980(3), b= 11.332(4), c= 13.526(5)Å;

  的反应[沫（CO）6 ]，在回流甲苯2个当量四苯基环戊二烯酮（tetracyclone）的给出[沫（CO）2（η 4 -C 4博士4 CO）2 ]图1A中大约 产率95％。与1个当量的tetracyclone在沸腾庚烷，[沫（CO）3（σ：η 4 -C 4博士4 CO）} 2 ] 2产生以及1A。该二聚体复合物在晶体学上已经得到了表征[三斜晶系，空间群P（2号），a = 8.980（3），b= 11.332（4），c = 13.526（5）Å；α＝ 77.55（3），β＝ 71.94（3），γ＝ 81.02（3）°，Z＝ 2个单体单元。每钼是在扭曲八面体的环境中，由η协调4 -二烯配体，三个羰基配体，以及其他相关的中心对称的tetracyclone的酮羰基。另一个方便的途径进入tetracyclone钼配合物是由[沫（CO）提供的化学3（NCMe）（η 4 -C 4博士4 CO）] 5，
• Peruvian Black Pottery Production and Metalworking: A Middle Sicán CraftWorkshop at Huaca Sialupe
  作者：Izumi Shimada、Ursel Wagner

  DOI：10.1557/mrs2001.15

  日期：2001.1

  The technical sophistication and virtuosity of prehispanic Andean ceramics are so often praised in the literature that it may appear that there is a large body of supportive, empirical findings. To the contrary, in-depth technical and more comprehensive technological studies have been rare. To achieve a comprehensive understanding of the many facets and stages of the technology and organization of craft production requires a correspondingly comprehensive, sustained effort—one built on interdisciplinary collaboration and longterm regional study of environmental, historical, social, and technological factors.

  安第斯史前陶器的技术复杂性和精湛技艺在文献中经常受到赞扬，以至于似乎有大量支持性的经验性发现。相反，深入的技术和更全面的技术研究却很少。要全面了解工艺生产的许多方面和阶段的技术和组织，需要相应全面、持续的努力，建立在跨学科合作和长期区域研究的环境、历史、社会和技术因素基础之上。
• Carbon monoxide releasing norbornenone compounds
  申请人：OTAGO INNOVATION LIMITED

  公开号：US11072584B2

  公开（公告）日：2021-07-27

  The present invention provides organic compounds which are capable of releasing carbon monoxide under physiological conditions or pH trigger, and to the use of such compounds for conditioning a cell, tissue or organ, for example, to protect against ischaemic injury during a transplant event.

  本发明提供了在生理条件下或 pH 触发下能够释放一氧化碳的有机化合物，并提供了使用此类化合物调节细胞、组织或器官的方法，例如在移植过程中防止缺血性损伤。
• Sen Gupta; Bhattacharyya, Journal of the Indian Chemical Society, 1956, vol. 33, p. 29,31
  作者：Sen Gupta、Bhattacharyya

  DOI：——

  日期：——