copper(II) decanoate | 10139-56-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: copper(II) decanoate
• 英文别名: copper(II) n-caprate；copper caprate；decanoic acid ; copper (II)-caprinate；Decansaeure; Kupfer(II)-caprinat；Kupfercaprat；copper;decanoate
• CAS: 10139-56-7；12121-66-3；28567-33-1；64508-49-2
• 化学式: 2C₁₀H₁₉O₂*Cu
• 分子量: 406.065
• InChiKey: SOZPIVMISATACJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.87
• 重原子数：
  13.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  40.13
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  copper(II) decanoate 、 C.I.酸性橙108 以 丙酮 为溶剂， 生成 copper;2-aminoethanol;decanoate
  参考文献：
  名称：

  Complexes of copper(II) carboxylates with 2-aminoethanol - syntheses, characterization and fungicidal activity; crystal structure of Cu(O2CC8H17)2(NH2C2H4OH)2

  摘要：

  Complexes of copper(II) octanoate, nonanoate and decanoate with 2-aminoethanol (ethanolamine) have been synthesized and characterized. The crystal structure of Cu(O2CC8H17)(2)(NH2C2H4OH)(2) consists of mononuclear units with pairs of amino nitrogen atoms and deprotonated nonanoato oxygen atoms forming a square coordination plane around the central copper. The hydroxyl oxygen atoms from the 2-aminoethanol ligands are positioned axially with respect to the coordination plane. Results of screening for fungicidal activity against the wood-rotting fungus Trametes versicolor (L. ex Fr.) Pilat show that the complexes totally inhibit fungal growth at a concentration of 1.0 x 10(-3) mol/l but only partially at a concentration of 5.0 x 10 mol/l. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00332-x
• 作为产物：
  描述：

  sodium decanoate 、 copper(II) nitrate 以 甲醇 、 水 为溶剂， 生成 copper(II) decanoate
  参考文献：
  名称：

  Mirnaya; Sudovtsova; Yaremchuk, Russian Journal of Inorganic Chemistry, 2004, vol. 49, # 9, p. 1440 - 1443

  摘要：

  DOI：
• 作为试剂：
  描述：

  (2Z)-9,18-dioxatetracyclo[17.3.1.14,8.011,16]tetracosa-1(23),2,4(24),5,7,11,13,15,19,21-decaene 在 碘 、 copper(II) decanoate 作用下， 以 乙醚 为溶剂， 反应 24.0h， 以58%的产率得到
  参考文献：
  名称：

  4,5-O-Substituted phenanthrenes from cyclophanes. The total synthesis of cannithrene II

  摘要：

  DOI：

  10.1021/jo00213a008

文献信息

• A comparison of thermal characteristics of Cu(II) carboxylates and their complexes with pyridine
  作者：S. Petriček、M. Petrič

  DOI：10.1016/s0040-6031(97)00077-4

  日期：1997.10

  2 ( R CO 2 ) 4 and Cu 2 ( R CO 2 ) 4 py 2 ( R = CH 3 (CH 2 ) n −2 ; n = 7, 8, 9, 10, 12) were done to compare their thermal behavior and establish the influence of pyridine in complexes on phase transition from solid state to liquid crystalline phase. Transitions from a crystalline to a liquid crystalline phase were observed for all Cu 2 ( R CO 2 ) 4 compounds, but only for pyridine complexes of Cu(II)

  摘要 Cu 2 ( R CO 2 ) 4 和Cu 2 ( R CO 2 ) 4 py 2 ( R = CH 3 (CH 2 ) n -2 ; n = 7, 8, 9, 10, 12)的TG和DTA测量进行了比较它们的热行为并确定吡啶在复合物中对从固态到液晶相的相变的影响。对于所有Cu 2 (R CO 2 ) 4 化合物，观察到从结晶相到液晶相的转变，但仅对于壬酸、癸酸和十二酸Cu(II)的吡啶配合物观察到。吡啶配合物的转变温度低于相应的Cu 2 (R CO 2 ) 4 。在刚好高于熔化温度重复加热时，Cu 2 (R CO 2 ) 4 py 2 复合物分解为Cu 2 (R CO 2 ) 4 ，其在较高温度下经历已知的结晶到液晶相转变。
• Complexes of copper(II) carboxylates with ammonia. Crystal structure of Cu(O2CC9H19)2(NH3)2(H2O)
  作者：M. Petrič、I. Leban、P. Šegedin

  DOI：10.1016/0277-5387(96)00135-0

  日期：1996.9

  composition CuX 2 (NH 3 ) 2 (H 2 O) (X = heptanoate, octanoate, nonanoate, decanoate or dodecanoate) were prepared, analysed and characterized by vibrational and electron paramagnetic resonance (EPR) spectroscopy and by magnetic susceptibility measurements. The crystal and molecular structure of diammineaquabis(decanoato)copper(II) was determined by X-ray diffraction. The structure consists of mononuclear

  摘要制备了组成为CuX 2（NH 3）2（H 2 O）（X =庚酸酯，辛酸酯，壬酸酯，癸酸酯或十二烷酸酯）的化合物，并通过振动和电子顺磁共振（EPR）光谱以及磁化率对其进行了分析和表征。测量。通过X射线衍射确定了二氨基四水合（癸）铜（II）的晶体和分子结构。该结构由在中心铜周围具有（4 + 2）配位的单核单元组成。
• The thermal behaviour and spectral properties of some long chain copper(II) carboxylates
  作者：Hugh D. Burrows、Henry A. Ellis

  DOI：10.1016/0040-6031(82)85190-3

  日期：1982.1

  Abstract Results are presented on the temperatures, enthalpies, and entropies of the phase transitions of the even chain length copper(II) carboxylates from decanoate to octadecanoate. The dodecanoate, tetradecanoate and hexadecanoate melt directly from crystal to isotropic liquid. However, with the decanoate and octadecanoate, an intermediate phase is observed between solid and isotropic liquid. Tentative

  摘要 给出了偶数链长羧酸铜 (II) 从癸酸到十八酸的相变的温度、焓和熵的结果。十二酸、十四酸和十六酸直接从晶体熔化成各向同性液体。然而，对于癸酸酯和十八酸酯，在固体和各向同性液体之间观察到中间相。对中间阶段进行了初步分配。报告了固体羧酸铜 (II) 的电子和红外光谱。在这两种情况下，光谱都提供了清晰的证据，证明每个羧酸铜系统的头基区域中至少有两个铜离子。
• Study of the Polymorphism in Copper(II) Decanoate through Its Phase Diagram with Decanoic Acid, and Texture of the Columnar Thermotropic Liquid Crystal Developable Domains in This and Similar Systems
  作者：M. Ramos Riesco、F. J. Martínez-Casado、J. A. Rodríguez Cheda、M. I. Redondo Yélamos、A. Fernández-Martínez、S. López-Andrés

  DOI：10.1021/cg501572s

  日期：2015.1.7

  these systems) of the pure salt into the saturated acid solution. These domains are seen not only in the copper(II) decanoate but also in other members of the series, at high salt concentration in the corresponding acid solution, and allow identification of the hexagonal columnar discotic structure of the mesophase (with the exception of the copper(II) butanoate, where the tetragonal domains with tilted

  通过两种方法发现了癸酸铜（II）的新的第三多晶型物：盐溶液的结晶和正庚烷中多晶型物的特定热处理。从热力学观点来看，这种新的多晶型物是首次稳定的晶体结构，是最稳定的。它具有双层结构，但具有两种不同类型的方向相反的明轮链。该多态性以及系统的温度与组成相图，[（1- x）C 9 H 21 CO 2 H +（x）（C 9 H 21 CO 2）2通过差示扫描量热法，傅立叶变换红外光谱，X射线衍射，成对分布函数和光学显微镜对Cu]进行解析。相图的奇异点是（a）癸酸铜（II）进入酸溶液的类似克拉夫特分子缔合过程，大约在T = 361.5 K和x = 0.022时（形成1：1的盐-酸加合物）化学计量比）; （b）作为不变量（T从癸酸铜（II）晶体相到盘状液晶的固体盐过量= 379.1 K），从而形成了纯盐向饱和酸溶液中的各向同性可显影区域（在这些系统中首次见到）。这些结构域不仅在癸酸铜（II）中可见，在系
• Spectroscopic study of the phase transitions of copper(II) n-alkanoates
  作者：M.I. Redondo、M.V. García、M.J. González-Tejera、J.A.R. Cheda

  DOI：10.1016/0584-8539(94)00128-x

  日期：1995.3

  FTIR spectra of copper nonanoate, decanoate, undecanoate and dodecanoate are recorded every 5 K from room temperature to 390 K. Changes detected in the infrared spectra when heating the sample allow the heat absorptions observed in some of these samples prior to the transition to the mesophase to be explained as due to conformational changes taking place in the alkyl chain next to the carboxylate group. Low frequency infrared and Raman spectra are consistent with a D-4h geometry for the ionic core where the copper ions are located. Moreover, the study of the low frequency region at the temperature of the mesophase permit the detection of rearrangements around the central core in the transition from the crystal to the mesophase.