dimethyl dihydrophthalate | 56387-51-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: dimethyl dihydrophthalate
• 英文别名: dimethyl 1,2-dihydrophthalate；Dimethyl cyclohexa-3,5-diene-1,2-dicarboxylate
• CAS: 56387-51-0
• 化学式: C₁₀H₁₂O₄
• 分子量: 196.203
• InChiKey: DXRDJSMCWTZCPH-UHFFFAOYSA-N

物化性质

• 沸点：
  266.2±40.0 °C(Predicted)
• 密度：
  1.166±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  dimethyl dihydrophthalate 、 五羰基铁 生成 carbon monoxide;dimethyl (1S,2R)-cyclohexa-3,5-diene-1,2-dicarboxylate;iron
  参考文献：
  名称：

  BANDARA, B. M. R.;BIRCH, A. J.;REVERTY, W. D., J. CHEM. SOC. PERKIN TRANS., 1982, N 8, 1755-1762

  摘要：

  DOI：
• 作为产物：
  描述：

  dimethyl 3-chlorocyclohex-4-ene-1,2-dicarboxylate 生成 dimethyl dihydrophthalate
  参考文献：
  名称：

  AVAGYAN, S. P.;MARTIROSYAN, N. G.;VOSKANYAN, EH. S., ARM. XIM. ZH., 41,(1988) N 8, S. 482-486

  摘要：

  DOI：

文献信息

• LIQUID CRYSTAL ELEMENT AND LIQUID CRYSTAL COMPOSITION
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2692828A1

  公开（公告）日：2014-02-05

  A liquid crystal element which comprises: a pair of substrates with electrodes, in which the substrates are arranged so as to face each other and at least one of the substrates is a transparent substrate; and a liquid crystal light adjusting layer which is disposed between the substrates and contains a composite containing a chiral nematic liquid crystal phase and a polymer resin phase, wherein the polymer resin phase contains a polymer compound having a repeating unit represented by the following general formula (1), and dielectric constant anisotropy of the chiral nematic liquid crystal phase is positive:

  一种液晶元件，它包括：一对带电极的基板，其中基板相互面对面排列，至少有一个基板是透明基板；以及一个液晶光调节层，该层位于基板之间，包含手性向列液晶相和聚合物树脂相的复合材料，其中聚合物树脂相包含具有以下通式（1）表示的重复单元的聚合物化合物，手性向列液晶相的介电常数各向异性为正：
• Method for purifying an organic solvent for the purposes of absorption of maleic acid anhydride
  申请人：——

  公开号：US20040127726A1

  公开（公告）日：2004-07-01

  In a process for purifying an organic solvent for the absorption of maleic anhydride from a gaseous mixture, in which the maleic anhydride is separated off from the solvent, a substream is taken from the solvent stream, this substream is distilled and returned to the solvent circuit, the proposed improvement comprises separating off a low-boiling fraction and a high-boiling fraction from the fraction consisting essentially of purified solvent and feeding the fraction consisting essentially of purified solvent back into the solvent stream.

  在一种用于从气态混合物中吸收顺丁烯二酸酐的有机溶剂的提纯工艺中，顺丁烯二酸酐从溶剂中分离出来，从溶剂流中提取一个子流，这个子流经过蒸馏后返回溶剂回路，建议的改进包括从主要由提纯溶剂组成的馏分中分离出一个低沸点馏分和一个高沸点馏分，并将主要由提纯溶剂组成的馏分送回溶剂流。
• Direct Observation of Polaritonic Chemistry by Nuclear Magnetic Resonance Spectroscopy
  作者：Bianca Patrahau、Maciej Piejko、Robert J Mayer、Cyril Antheaume、Thitiporn Sangchai、Giulio Ragazzon、Anjali Jayachandran、Eloïse Devaux、Cyriaque Genet、Joseph Moran、Thomas W. Ebbesen

  DOI：10.1002/anie.202401368

  日期：——

  New Fabry-Perot optical cavities were developed that enable studying Vibrational Strong Coupling (VSC) by Nuclear Magnetic Resonance (NMR) spectroscopy. We demonstrate that the London dispersion-driven conformational equilibrium of a molecular balance is altered when the C−H stretching vibration is strongly coupled to the cavity. Unexpectedly, VSC does not substantially affect molecular electron density

  开发了新的法布里-珀罗光学腔，可以通过核磁共振 (NMR) 光谱研究振动强耦合 (VSC)。我们证明，当 C−H 伸缩振动与空腔强烈耦合时，伦敦色散驱动的分子平衡构象平衡会发生改变。出乎意料的是，VSC 并没有显着影响分子电子密度分布，这对极化子化学中可能发挥作用的机制具有深远的影响。
• Synthesis and NMR spectral properties of phosphines in the 2-phosphabicyclo[2.2.2]oct-5-ene and 2-phosphabicyclo[2.2.2]octa-5,7-diene systems
  作者：Louis D. Quin、Alan N. Hughes、John C. Kisalus、Bela Pete

  DOI：10.1021/jo00243a023

  日期：1988.4
• Quin, Louis D.; Szewczyk, Jerzy; Marsi, Brian G., Phosphorus and Sulfur and the Related Elements, 1987, vol. 30, p. 249 - 252
  作者：Quin, Louis D.、Szewczyk, Jerzy、Marsi, Brian G.、Wu, Xiao-Ping、Kisalus, John C.、Pete, Bela

  DOI：——

  日期：——