S-benzyl O,O-diethyl phosphorodithioate | 13286-37-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: S-benzyl O,O-diethyl phosphorodithioate
• 英文别名: dithiophosphoric acid O,O'-diethyl ester-S-benzyl ester；Dithiophosphorsaeure-O,O'-diaethylester-S-benzylester；Dithiophosphorsaeure-O,O-diethyl-S-benzylester；S-Benzyl-O,O-diethyl-phosphordithioester；O,O-Diaethyl-S-(benzyl)-dithiophosphat；O,O'-Diethyl-S-benzyl-dithiophosphat；benzylsulfanyl-diethoxy-sulfanylidene-λ5-phosphane
• CAS: 13286-37-8
• 化学式: C₁₁H₁₇O₂PS₂
• 分子量: 276.361
• InChiKey: LDYLVLLDIQXZFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  75.8
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2931900090

反应信息

• 作为产物：
  描述：

  chloroamine-T 生成 S-benzyl O,O-diethyl phosphorodithioate
  参考文献：
  名称：

  O，O-二烷基二硫代磷酸对半极性键的还原作用

  摘要：

  发现具有半极性官能团的化合物（通常由X→Y表示），即亚砜，亚硫亚胺，鎓内鎓盐，吡啶N-氧化物和N-亚氨基吡啶甜菜碱，很容易与O，O-二烷基二硫代磷酸反应以提供相应的还原产品，硫化物和吡啶。

  DOI：

  10.1016/0040-4020(72)80012-7

文献信息

• Phosphorothioates—III
  作者：Bernard Miller

  DOI：10.1016/s0040-4020(01)98479-0

  日期：1964.1

  Organometallic reagents attack the SS bonds of phosphorothionyl disulphides (V) to give high yields of the corresponding S-substituted phosphorodithioates. S-alkenyl and S-alkynyl phosphorodithioates, previously unknown, were prepared in this manner. No indication of attack at phosphorus atoms, of reduction of SS bonds, or of benzylic rearrangements of the organo- metallic reagents were observed

  有机金属试剂攻击磷硫酰二硫（V）的SS键，从而获得高产率的相应S取代的二硫代磷酸硫酯。以此方式制备先前未知的S-烯基和S-炔基二硫代磷酸酯。没有观察到对磷原子的攻击，S bondsS键的还原或有机金属试剂的苄基重排的迹象。
• A Convenient Synthesis of Phosphorodithioates and Novel Conversion of Epoxides to Thiiranes
  作者：Babak Kaboudin、Hamid Norouzi

  DOI：10.1055/s-2004-829176

  日期：——

  Alumina-supported ammonium acetate under microwave irradiation was found to be an efficient reagent for the preparation of phosphorodithioates from phosphorus pentasulfide under solvent-free condition. A simple, efficient, and new method has been developed for the synthesis of thiiranes from epoxides through a one-pot reaction of epoxides with the mixture of phosphorus pentasulfide in the presence of ammonium acetate

  微波辐射下氧化铝负载的乙酸铵是一种在无溶剂条件下由五硫化二磷制备二硫代磷酸盐的有效试剂。开发了一种简单、有效和新的方法，通过环氧化物与五硫化二磷的混合物在乙酸铵和酸性氧化铝的存在下，在 EtOH 中回流或无溶剂条件下的一锅反应，从环氧化物合成硫杂丙环烷。在微波照射下。这些方法是合成二硫代磷酸酯和硫杂丙环的简单、快速和高产率的反应。
• Heterocyclic phosphorus compounds
  申请人：SHEA CHEMICAL CORP

  公开号：US02834798A1

  公开（公告）日：1958-05-13
• Chemical fractionation of heavy metals in soils around oil installations, Assam
  作者：P. Kotoky、B. J. Bora、N. K. Baruah、J. Baruah、P. Baruah、G. C. Borah

  DOI：10.3184/095422903782775181

  日期：2003.1

  The chemical fractionation of lead, cobalt, chromium, nickel, zinc, cadmium and copper in soils around Lakwa oil field, Assam, India was studied using a sequential extraction method. It is evident from the study that the residual fraction is the most important phase for the seven heavy metals under study. Among non-residual fractions metals are mostly associated with the Fe-Mn oxides fraction. The association of heavy metals with organic matter was observed in the following order: copper> cadmium> zinc> lead. The concentration of Pb in the carbonate fraction for both the seasons is higher compared with other metals, which may pose environmental problems due to its highly toxic nature. The comparatively low concentration of metals in the exchangeable fraction indicates low bioavailability. Correlations between physicochemical parameters and metal fractions of soil do not show consistent behaviour. The local mean values of metals when compared with the accepted values of normal abundance and geochemical background, indicates two to four fold increases in this area. However, the values are within the range of normal abundance. As well as from natural soil geochemical behaviour, anthropogenic influence might have a close bearing on the association of metals with the soil system in the studied area.
• SHABANA, RASHAD;EL, WASSIMY, MOHAMED, T. M.;GHATTAS, ABD, EL, BADIH, A. G+, CHEM. AND IND., 1986, N 4, 140-141
  作者：SHABANA, RASHAD、EL, WASSIMY, MOHAMED, T. M.、GHATTAS, ABD, EL, BADIH, A. G+

  DOI：——

  日期：——