1-methylphenanthro[9,10-d]imidazole | 50609-89-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1-methylphenanthro[9,10-d]imidazole
• 英文别名: 1-methyl-1H-phenanthro[9,10-d]imidazole；1-Methyl-1H-phenanthro[9,10-d]imidazol；1-Methyl-1H-phenanthro<9,10-d>imidazol；1-Methylphenanthreno[9,10-d]imidazole；3-methylphenanthro[9,10-d]imidazole
• CAS: 50609-89-7
• 化学式: C₁₆H₁₂N₂
• 分子量: 232.285
• InChiKey: YXBLLKVMYBJONF-UHFFFAOYSA-N

物化性质

• 熔点：
  196 °C
• 沸点：
  468.3±28.0 °C(Predicted)
• 密度：
  1.21±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-methylphenanthro[9,10-d]imidazole 、 hydroxylamine O-picryl ether 以 氯仿 、 乙腈 为溶剂， 反应 2.0h， 以84%的产率得到1-amino-3-methylphenanthro[9,10-d]imidazolium picrate
  参考文献：
  名称：

  N-Amino Derivatives of Condensed Imidazole Systems

  摘要：

  DOI：

  10.1023/b:cohc.0000008260.31382.77
• 作为产物：
  描述：

  菲醌 、 甲胺 生成 1-methylphenanthro[9,10-d]imidazole
  参考文献：
  名称：

  Japp; Davidson, Journal of the Chemical Society, 1895, vol. 67, p. 34,45

  摘要：

  DOI：

文献信息

• Microwave-assisted conversion of carbonyl compounds into formylated secondary amines: new contribution to the Leuckart reaction mechanism in N-methylformamide
  作者：Fructuoso Barba、Javier Recio、Belen Batanero

  DOI：10.1016/j.tetlet.2013.01.097

  日期：2013.4

  The reductive amination of several carbonyl compounds (Leuckart reaction) has been performed using N-methylformamide and microwave technology. Under these conditions, a new mechanism is proposed via the initial formation of an imine, followed by reduction to the amine by ‘in situ’ generated formic acid, and further formylation of the amine. Using this methodology, the formyl derivatives of several

  几种羰基化合物的还原胺化（Leuckart反应）已使用N-甲基甲酰胺和微波技术进行了。在这些条件下，提出了一种新的机理，即首先形成亚胺，然后通过“原位”生成的甲酸还原为胺，然后进一步使胺甲酰化。使用这种方法，可以良好地获得极好的收率的几种仲胺的甲酰基衍生物。
• ORGANIC COMPOUND, MIXTURE COMPRISING SAME, COMPOSITE, AND ORGANIC ELECTRONIC COMPONENT
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20180130955A1

  公开（公告）日：2018-05-10

  An organic compound having the following structural formula is provided: wherein Ar 1 to Ar 5 are aromatic or heteroaromatic structural units, X, Y, and Z are bridging groups connecting two or three aromatic rings, and n is an integer between 1 and 4. The organic compound has an increased resonance factor and a reduced Δ(S1−T1), thus facilitating acquisition of thermally-excited delayed fluorescence properties provided with increased light emission efficiency, and implementing high efficiency and extended service life of an OLED component. In addition, a synthesis process for the organic compound is simple and inexpensive. A mixture a formulation and an organic electronic device containing the organic compound are also provided.

  提供具有以下结构式的有机化合物：其中Ar1至Ar5为芳香或杂环芳香结构单元，X、Y和Z为连接两个或三个芳香环的桥接基团，n为1到4之间的整数。该有机化合物具有增强的共振因子和减小的Δ(S1−T1)，从而有助于获得具有增加的光发射效率的热激发延迟荧光特性，并实现OLED元件的高效率和延长使用寿命。此外，该有机化合物的合成工艺简单且廉价。还提供了包含该有机化合物的混合物配方和有机电子器件。
• HIGH POLYMER, MIXTURE CONTAINING SAME, COMPOSITION, ORGANIC ELECTRONIC COMPONENT, AND MONOMER FOR POLYMERIZATION
  申请人：Guangzhou Chinaray Optoelectronic Materials Ltd.

  公开号：EP3547384A1

  公开（公告）日：2019-10-02

  A high polymer, a mixture containing the same, a composition, an organic electronic component, and a monomer for polymerization. The high polymer comprises a repeat unit E1 and a repeat unit E2. An E1 group on a side chain of the repeat unit E1 and an E2 group on a side chain of the repeat unit E2 have features for forming Exciplexes, min((LUMO(E1)-HOMO(E2), LUMO(E2)-HOMO(E1)) ≤ min(E T(E1),ET(E2))+0. leV being satisfied, and accordingly a high polymer suitable for printing technologies is provided, thereby reducing manufacturing costs of OLEDs.

  一种高聚物、一种含有高聚物的混合物、一种组合物、一种有机电子元件和一种用于聚合的单体。高聚物包括一个重复单元 E1 和一个重复单元 E2。重复单元 E1 侧链上的 E1 基团和重复单元 E2 侧链上的 E2 基团具有形成Exciplexes的特征，min((LUMO(E1)-HOMO(E2), LUMO(E2)-HOMO(E1)) ≤ min(E T(E1),ET(E2))+0. leV 满足要求，因此提供了一种适用于印刷技术的高聚物，从而降低了有机发光二极管的制造成本。
• Polymers containing furanyl crosslinkable groups and uses thereof
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US11289654B2

  公开（公告）日：2022-03-29

  The present disclosure provides a polymer represented by the following general formula (I): wherein x and y each represent a repeating unit, and both x and y are positive integers; formula and formula are each independently selected from the group consisting of an aryl containing 5-40 ring atoms and a heteroaryl containing 5-40 ring atoms; formula is a linking group, and formula is selected from the group consisting of alkyl, alkoxy, amino, alkenyl, alkynyl, aralkyl, and heteroalkyl; and R2, R3 and R4 are each independently selected from the group consisting of H, D, F, CN, alkyl, fluoroalkyl, aryl, heteroaryl, amino, Si, germyl, alkoxy, aryloxy, fluoroalkoxy, siloxane, siloxy, deuterated alkyl, deuterated fluoroalkyl, deuterated aryl, deuterated heteroaryl, deuterated amino, deuterated silyl, deuterated germyl, deuterated alkoxy, deuterated aryloxy, deuterated fluoroalkoxy, deuterated siloxane, and deuterated siloxy.

  本公开提供了一种由以下通式 (I) 表示的聚合物： 其中 x 和 y 各代表一个重复单元，且 x 和 y 均为正整数； 式中 和公式 各自独立地选自含 5-40 个环原子的芳基和含 5-40 个环原子的杂芳基组成的 组；式中 是连接基团，式 选自由烷基、烷氧基、氨基、烯基、炔基、芳基和杂烷基组成的组； R2、R3 和 R4 各自独立地选自由 H、D、F、CN、烷基、氟烷基、芳基、杂芳基、氨基、 Si、芽基、烷氧基、芳氧基、氟烷氧基、硅氧烷、硅氧基、氚代烷基、氚代氟烷基、氚代芳基、氚代芳基和杂烷基组成的组、氚代氟烷基、氚代芳基、氚代杂芳基、氚代氨基、氚代硅烷基、氚代胚芽 基、氚代烷氧基、氚代芳氧基、氚代氟烷氧基、氚代硅氧烷和氚代硅氧基。
• Boron-containing organic compound and applications thereof, organic mixture, and organic electronic device
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US11239428B2

  公开（公告）日：2022-02-01

  An organic compound containing boron and uses thereof, an organic mixture, and an organic electronic device, the structure of said organic compound containing boron being as shown in formula (1). The substituents in formula (I) have the same definitions as in the description.

  一种含硼的有机化合物及其用途、一种有机混合物和一种有机电子器件，所述含硼有机化合物的结构如式（1）所示。式（I）中的取代基与描述中的定义相同。