O-4-pyridyl N-allylcarbamate | 1309041-66-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: O-4-pyridyl N-allylcarbamate
• 英文别名: pyridin-4-yl N-prop-2-enylcarbamate
• CAS: 1309041-66-4
• 化学式: C₉H₁₀N₂O₂
• 分子量: 178.191
• InChiKey: XUZQOQSLZCUDJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  51.2
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-羟基吡啶 、 3-异氰酸丙烯 在 三乙胺 作用下， 以 丙酮 为溶剂， 以50%的产率得到O-4-pyridyl N-allylcarbamate
  参考文献：
  名称：

  Synthetic Access to New Carbamate and Thiocarbamate Derivatives from Pyridinecarbaldehyde Oximes and Hydroxypyridines

  摘要：

  [image omitted] The synthesis of pyridine carbamate and thiocarbamate derivates is described. A series of oxime carbamate and thiocarbamate derivatives were synthesized by the addition of 2-, 3-, and 4-pyridinecarbaldehyde oximes to isocyanates and isothiocyanates. Furthermore, carbamate and thiocarbamate derivatives of pyridine were synthesized by the addition of 2-, 3-, and 4-hydroxy pyridine to isocyanates and isothiocyanates. Their structures were confirmed by both analytical and spectral data.

  DOI：

  10.1080/00397911.2010.490627

文献信息

• Synthetic Access to New Carbamate and Thiocarbamate Derivatives from Pyridinecarbaldehyde Oximes and Hydroxypyridines
  作者：Ahmet Kocak、Gulnare Ahmetli、Nuriye Kocak、Sait Malkondu、Aysegul Yaylaci、Sultan Kurbanli

  DOI：10.1080/00397911.2010.490627

  日期：2011.5.3

  [image omitted] The synthesis of pyridine carbamate and thiocarbamate derivates is described. A series of oxime carbamate and thiocarbamate derivatives were synthesized by the addition of 2-, 3-, and 4-pyridinecarbaldehyde oximes to isocyanates and isothiocyanates. Furthermore, carbamate and thiocarbamate derivatives of pyridine were synthesized by the addition of 2-, 3-, and 4-hydroxy pyridine to isocyanates and isothiocyanates. Their structures were confirmed by both analytical and spectral data.